GlycoNAVI: CheGly (Chemical Glycosylation)

promoter

CheGly
2,6-lutidine
36
92
AgBF4
AgClO4
AgOTf
Bi(OTf)3
BuLi
Cu(OTf)2
DAST
DDQ
DMF
DMTST
DTBMP
DTBS(OTf)2
Et3N
I2
IDCP
KOH
MeOTf
NBS
NIS
NaH
Sn(OTf)2
SnCl2
TBAI
TBSOTf
TMSOTf
Tf2O
TfOH
Yb(OTf)3
ZnCl2
n-BuLi
Ag2CO3
Ag2O
Br2
Bu3SnH
CuBr2
FeCl3
Hg(CN)2
HgBr2
HgCl2
Me2S
MeI
PPTS
SiF4
SnCl4
TBDMSOTf
TMSI
TiCl4
TrClO4
Zn(OTf)2
ZnBr2
trichloroacetimidate
AgB(C6F5)4
BiCl3
HB(C6F5)4
InCl3
MoO2Cl2
Ph3PAuNTf2
palladium
e
galactosyltransferase
enzyme
BF3
e- E = 1.8~2.1 V
e- (Bu4NBF4)
silver tresylate [2,2,2-trifluoroethanesulfonate:Tresylate]
polymer bound triarylphosphane-iodine complex and imidazole
(4-CF3Ph)3PAuCl, AgOTf
(C4H8N)3P=O
(CH3)3SiClO4
(CH3)5SiOSO2C4F9
(MeO)2P(=S)-S-Br/AgOTf
(Ph)2SO
(Ph3P)3RhCl-DABCO-TMSOTf
(Ph3P)3RhCl/BuLi/TMSOTf
(Ph3P+)2O-2TfO-
(TMS)3SiH, AIBN
(p-NO2Ph)(Ph)SO, Tf2O
(p-tBuC6H4CO2)2Zn
1,3,5-Trimethoxybenzene,Tf2O, DTBMP
1,3-dithian-2-ylium tetrafluoroborate
1-benzenesulfinylpiperidine-Tf2O
2-fluoro-l-methylpyridinium tosylate
?
AcClO4
Ag2CO3-AgClO4
Ag2O-Py
AgClO4-Lawesson's reagent
AgClO4-LiClO4
AgClO4-Ph3Sn=S
AgClO4-SnCl2-di-tert-butylpyridine
AgF-Ag2CO3
AgOTf, 2,4,6-trimethylPy
AgOTf, p-TsSCl
AgOTf-HMPA(catalyc amount)
AgOTf-K2CO3
AgOTf-PhSCl-DTBMP
AgOTf-SnCl2
AgOTf-TMSOTf
AgOTf-lutidine; TMSOTf
AgOTf; NIS-TfOH
AgPF6
AgPF6-DTBMP
Amberlyst 15
ArS(ArSSAr)+B(C6F5)4-
AuBr3
AuBr3, AgOTf
AuCl3
BSM-TTBP-Tf2O
BSM-Tf2O
BSM-Tf2O (additive: TTBP)
BSP-Tf2O-TTBP
BSP/DTBMP
BSP/Tf2O
BTEAB
BTIB
Ba(ClO4)2
Br2, silver silicate
Br2-Ag2CO3
Br2-AgOTf
Br2/TMSOTf
BrCCl3, HFIP, blue LED(cat)
Bromodimethylsulfonium Bromide(BDSM)-AgOTf
Bu3SnH, AIBN
Bu4N+Br-
Bu4NHSO4
Bu4NOTf
Bu4NOTf, R1SR2
C8F17SO3H (cat)
CBr4, PPh3
CBr4, PPh3, N,N-tetramethylurea(TMU)
CBr4/PPh3/DMF
CCl3CHO
CdCl2
Cellulase
Cp2HfCl2-2AgClO4
Cp2HfCl2-AgClO4
Cp2HfCl2-AgOTf
Cp2HfCl2/AgX (X=OTf, ClO4)
Cp2MCl2-AgClO4 (M=Zr or Hf)
Cp2MCl2-AgX (M=Hf, Zr; X=ClO4, OTf)
Cp2ZrCl2-AgBF4
Cp2ZrCl2-AgBF4, Cp2HfCl2-AgOTf
Cp2ZrCl2-AgClO4
Cu(OTf)2-BTF
Cu(OTf)2-CuO
Cu(OTf)2-DMTST
Cu(OTf)2-NIS
Cu(OTf)2/cat-TfOH
CuBr2-Bu4NBr
CuCl-I2
CuCl2
CuCl2/dppf/AgClO4
CuOAc-DBU
CuOTf(C6H6)0.5
DAST-Sn(OTf)2-Bu4NClO4-TEA
DEAD-Ph3P
DMTST, Bu4NBr
DMTST-DTBMP
DPS/Tf2O
DTPBI-TBAI
Et2AlCCBu
Et2AlCN
Et2AlCl2
Et3Al
FeCl3-I2
GaCl3-AgClO4 (cat)
Glycosidase
Glycosynthase
H3PO4
H3PW12O40
H4SiW12O40
HB(C6F5)4 or TfOH
HB(C6F5)4, HClO4, HNTf2 and more
HClO4(cat)
HF
HF-pyridine
HF-pyridine complex
Hf(OTf)4
Hg(CN)2-HgBr2(1.6:0.5 mixture)
Hg(CN)2-HgBr2(1:1 mixture)
Hg(OBz)2
Hg(OTf)2
Ho(OTf)3
I2-DDQ
I2-DTBMP
I2/Et3N
I2/Et3SiH
IBr
IBr-AgOTf
IBr-In(OTf)3
IBr-TfOH
ICl
ICl-AgOTf
ICl-In(OTf)3
ICl-TfOH
IPy2BF4
In
In(OTf)3
InBr3
InCl3-TMSCl
InF3
InI3
Iodonium ion
Iodonium-ion
KH
KHMDS, Ts2O
KOt-Bu, I2
LDA
LPTS(2,6-lutidinium p-toluenesulfonate)-nBu4NI
LPTS-nBu4NI
La(OTf)3-NIS
Lawesson reagent
Li naphthalenide
LiClO4
LiClO4, microwave, 100degree
LiOTf
Lipase
Lipase PS-30 from Pseudomonas cepacia
LnPtMe3BF4, Cu(OTf)2
MPBT-Tf2O
MSB or MST
Me2(MeS)S+OTf- and Bu4N+Br-
Me2AlCCBu
Me2AlCCSiMe3
Me2GaCl, Me2GaOTf
Me2S-Tf2O-TTBP
Me2S2-Tf2O
Me2SiCl2-AgClO4
Me3Al
Me3OBF4
Me3OBF4, 4-Me-DTBP
Me3SiBr, CoBr2, n-Bu4NBr
Me3SiClO4
Me3SiOTf
Me4NBr or AgOTf-collidine, pressure of 15 kbar
MeOCH2CO2H-Yb(OTf)3
MeONa
MeOSO2F-CaF
MeOTf, 2,6-lutidine
MeOTf, Cu(OTf)2, or Yb(OTf)2
MeOTf, DTBP
MeOTf-TrClO4
MeSO3H-CoBr2
MeSOTf
MeSiCl3-AgClO4 (cat)
Methallyltri-n-butylstannane
Mg(ClO4)2
MgO
Microwave, montmorillonite K-10
Montomorillonite K-10
MsOH-CoBr2-R'4NBrX (R'=Et, Bu; X=Br, ClO4)
N-PhS-caprolactam-Tf2O
N-acetylglucosaminyltransferase
N-acetylhexosaminidase from Aspergillus oryzae
N-phenylselenophthalimide(NPSP)
NBS, Bi(OTf)3
NBS-AgOTf
NBS-Bu4NOTf
NBS-In(OTf)3
NBS-Ph2IOTf
NBS-QOTf
NBS-TMSOTf
NBS-TfOH
NHTf2
NIS, HClO4-SiO2
NIS-AgOTf
NIS-Et3SiOTf
NIS-I2-TMSOTf
NIS-IDCT
NIS-In(OTf)3
NIS-LiClO4
NIS-MeOTf
NIS-Sn(OTf)2
NIS-TESOTf
NIS-TMSOTf
NIS-TMSOTf, DMF
NIS-TfOH
NIS-TfOH (cat)
NISac(N-Iodosaccharin)
NOBF4
NaH, DMDO
NaH, decyl trifluoromethanesulfonate
Nafion-H
Nafion-TMS
Ni(4-F-PhCN)4(OTf)2
Ni(COD)2/Zn, (R)-Ph-pyBox
NiCl2-ligand, NiCl2-Ligand(PyBox)
NosCl-AgOTf-Et3N-DMA(N,N-dimethylacetamide)
NsCl-AgOTf-Et3N-DMA(N,N-dimethylacetamide)
PPh3-DEAD
PPh3-DIAD
Palladium
Pd (0)
Pd compound
Pd(CH3CN)4(BF4)2
Pd(ClO4)2
Pd(II)
Pd(MeCN)2Cl2-AgOTf
Pd(OAc)2
Pd(OAc)2-Ag2CO3-PPh3
Pd(OAc)2-P(OPh)3
Pd(OAc)2-PPh3
Pd(Ph3P)2Cl2
Pd(Ph3P)4
Pd(PhCN)2(OTf)2
Pd(PhCN)2Cl2
Pd(PhCN)2Cl2/L, L = 2,4,6-tri-iPrPh-[2-P(tBu)]Ph
Pd2(DBA)3
Pd2(dba)3-PPh3
PdCl2(dppf)-CuCN
Ph-S-O-SO2CF3(benzene sulphenyl triflate; BST)
Ph2SO-Tf2O
Ph2SO-Tf2O-TBP
Ph2Sn=S-Tf2O-CsF
Ph3Bi(OTf)2
Ph3C+ClO4-
Ph3PAuOTf
PhHgOTf
PhIO-AgOTf
PhIO-In(OTf)3
PhIO-Mg(ClO4)2
PhIO-TMSOTf
PhIO-Tf2O
PhIO-TfOH
PhSOTf-DTBMP
PhSeNPhth-Mg(ClO4)2
PhSeNPhth-TMSOTf
PhSeOTf
PhSeOTf, thermal condition
PhSeOTf-TTBP
Phthalic anhydride-DBU-Tf2O
Pr3Al
ReOCl3(SMe2)(Ph3PO)
SO2Cl2-TfOH
SO4/ZrO2
Sat. NaHCO3
SiCl(OTf)3
SiCl2(OTf)2
Sm(OTf)3
SmI2
SmI2?
Sn(OTf)2 (cat)
Sn(OTf)2-DTBP
Sn(OTf)2-LiClO4
Sn(OTf)2-TMU
Sn(OTf)2-collidine
Sn(OTf)2/TMSCl
SnBr4
SnCl2(OTf)2
SnCl2-AgB(C6F5)4
SnCl2-AgB(C6H5)4
SnCl2-AgClO4
SnCl2-AgOTf
SnCl2-SnCl4 (cat)
SnCl2-TrClO4
SnCl3(ClO4)
SnCl3(ClO4) (cat)
SnCl3(OTf)
SnCl4, PhOSnBu3
SnCl4-AgClO4
SnCl4-AgClO4 (cat)
SnCl4-Sn(OTf)2 (cat)
TBAB, K2CO3
TBAI-DIPEA
TBAI-DIPEA, reflux
TBPA
TBPA, (4-BrPh)3NH+SbCl6-
TMS2O-CaSO4-La(OTf)3
TMS2O-CaSO4-Sn(OTf)2
TMS2O-CaSO4-SnCl2
TMS2O-CaSO4-Yb(OTf)3
TMS2O-Sn(OTf)2-LiClO4
TMSB(C6F5)4
TMSBr-Sn(OTf)2-LiClO4
TMSCIO4-(CCl3CO)2O
TMSCl-Sn(OTf)2-LiClO4
TMSCl-Zn(OTf)2
TMSI-(C4H8N)3P=O
TMSI-(Me2N)3P=O
TMSI-(N-Morpholinyl)3P=O
TMSI-(p-MeOPh)3P=O
TMSI-(pyrrolidine)3P=O
TMSI-Ph2P(=O)Me
TMSI-Ph2P(=O)OPh
TMSI-Ph3P=O
TMSI-Ph3P=S
TMSI-n-Bu3P=O
TMSI-n-Bu4NI-(i-Pr)2NEt
TMSOCOCF3-Sn(OTf)2-LiClO4
TMSOTf (cat.)
TMSOTf and more
TMSOTf(cat)-Ph2Sn=S
TMSOTf(cat)-Ph2Sn=S-LiClO4
TMSOTf(cat.), SiF4(cat)
TMSOTf-AgClO4
TMSOTf-CaCl2
TMSOTf-PhSEt
TMSOTf-Sn(OTf)2-LiClO4
TMSOTf-thiophene
TTBP-Tf2O
Tb(OTf)3
Tf2O + Lewis acid
Tf2O, 1-benzenesulfinyl piperidine
Tf2O, DTBMP
Tf2O, TBP
Tf2O, TTBP
Tf2O, TfOH
Tf2O, base
TfOH or HClO4
TfOH/TEP
Ti(OtBu)4, mandelic acid
TiCl2(OTf)2
TiF4
TiF4 or SnF4
Tl(NO3)3
Tm(OTf)3
TrB(C6F5)4
TrB(C6F5)4 (cat)
TrB(C6F5)4+ I2+ DDQ
TrB(C6F5)4, PhthNSEt
TrB(C6F5)4-LiBF4
TrB(C6F5)4-LiClO4
TrB(C6F5)4-LiI
TrB(C6F5)4-LiNO3 (X: ClO4, I, NTf2)
TrB(C6F5)4-LiNTf2
TrB(C6F5)4-LiOTf
TrB(C6F5)4-NIS(or NBS)
TrB(C6F5)4-NaIO4
TrBF4
TrCl-ZnCl2
TrClO4 (cat)-TMSOTf
TrClO4, I2
TrClO4-TMSOTf
TrOTf
TrSbCl6
Trypanosoma cruzi trans-sialidase
TsCl-TEBA
TsCl/Bu4N+Cl-
TsOH or ZnCl2 ?
Vermiculite
Volt (+1.5), n-Bu4NClO4
Yb(NTf2)3
Zn(Ac)2
Zn(CN)2
Zn(acac)2
Zn/ZnCl2
ZnCl2-AgClO4
ZnO
ZrCl4
[1,2-benzenediolato(2-)-O,O']oxotitanium-TMSOTf
[1,2-benzenediolato(2-)-O,O']oxotitanium-Tf2O-Base
[Co(dmgH)2py]2-NaBH4
[Ru(bpy)3]2+, Visible light, amine reductant
[bmim][OTf] (ionic liquid promoter)
rare earth metal salts, with or without ZnCl2 and Ba(ClO4)2
acid or mercury salt
acid promoters
alkyne-Co2(CO)6 complex, TMSOTf
allyltri-n-butylstannane
base catalysis
base promoted, acid catalyzed
benzenesulfinyl morpholine, Tf2O
cadmium zeolite
calf intestinal phosphatase
catalyst: Aliquat336 acceptor: ROH (R=alkyl)
catalyst: Bu4N+Br- acceptor: ROH (R=aryl)
catalyst: Bu4N+HSO4- acceptor: ROH (R=aryl)
catalyst: BuN+Bu3Cl- acceptor: ROH (R=aryl)
catalyst: Et3N+BnBr- acceptor: ROH (R=aryl)
catalyst: Et3N+BnCl- acceptor: ROH (R=aryl)
chiral phosphoric acid
copper(II)
electrolyte, catalytic amount of NaOTf
fucosyltransferase
glucosyltransferase (CGTase)
glycosidase
glycosyltransferase
gold(I)
gold(I) complex
i-Bu3Al
insoluble silver salts
lanthanide(III) triflate
catalyst: Me(CH2)15N+Me3Br- acceptor: ROH (R=aryl)
metal trifluoromethanesulfonates
monomethoxyTrSbCl6
n-Bu2SO/TMSOTf
nBu2S=O/(PhSO2)2O/TTBP
nBu3P=O-Tf2O-iPr2NEt
organocopper
organocuprates
organolithiums
p-NO2PhSCl-AgOTf
p-TolSCl, AgOTf
p-TolSl- AgOTf
p-Ts2O
pTSA/[bmim][BF4] ionic liquid
palladium (0)
palladium(0)
palladium(II) complex
phenylsulfenyl triflate
recyclable solid superacid promoter(SO4/ZrO2 ?)
rhodium(I)
secondary alkyl trifluoromethanesulfonates
secondary amine, Cs2CO3
sialyltransferase
silver zeolite
thermophilic galactosidase
titanium(IV)
tributylstannyllithium
vitamin12a, Zn, NH4Cl
Eox = 0.90V, Ag/AgCl, electrolyte: LiClO4 or Bu4NBF4
Pyridinium Triflate (combined with microwave heating )
N,N-dimethyl-carbamoylmethyldimethylsulphonium chloride
[1,2-benzenediolato(2-)-O,O']oxotitanium-Tf2O-CsF-iPrNEt
AgOTf-DMSO or tetramethylurea or HMPA(catalytic amount)
Bu2SnCl2, Me2SnCl2, Bu3SnCl, Me3SnCl, and Ph3SnCl with AgClO4
selectfluor(1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate))
R3P=O (R=aryl, nBu, cyclohexane, (CH2)15CH3), Tf2O, amine
(2??3)-??-sialyltransferase
9-borabicyclo[3.3.1]nonyl trifluoromethanesulfonate (9-BBN_CF3SO3)
1,4-Dicyanonaphthalene (DCN)/h??
40?|60 ??C
4A?AW MS (Acid-Washed Molecular Sieves)
ACF(carbon? fiber)
Acyl Sulfonamide (?⑫?Q??)
Ag_NHC complex
BF3 _ Et2O-DTBMP
BF3?EEt2O
BF3?EEt2O, TMSOTf
BF3?EEt2O/TMSOTf
BF3?EOEt2, p-TsOH
Bacillus1,3-1,4-??-D-glucan 4-glucanohydrolases
Br_nsted acid (chiral organic cat.)?
Bu2SnCl2?%5C2AgClO4
Bu3SnAll, h??
Bu3SnSnBu3, h??
CeCl3_Nal
Cellulase,? ??-galactosidase
DBBOTf??
DDQ,??long-wavelength UV, (p-OMe)PhB(OH)2
EDCl?EHCl-HOBt (TBTU)
Et2O_ZnCl2
FeCl3, TMSOTf, BF3?EEt2O, LiClO4
HClO4?ESiO2
La(ClO4)3?EnH2O (cat)
La(ClO4)3?EnH2O-Sn(OTf)2
Lewis ??(1,3/1,4)fucosyltranferase
MgBr2?EEt2O
N-(p-methylphenylthio)-??-caprolactam-TMSOTf
N-(phenylthio)-??-caprolactam
N-acetyl-??-hexosaminidase
NIS, HClO4_silica
NIS-BF3?EEt2O
NIS-TfOH?in the presence of DTBMP
NMP(1-methyl-2-pyrrolidinone ),?? 40?|60 ??C
Ph2SO-TTBP-Tf2O?
Ph3PAuOTf, BF3_Et2O and DBU
Ph3PAuOTf?, ?Ph3PAuNTf2
Sn(OTf)2-BF3?EEt2O
TBPA+?E(radical)
TMSI?or (Me3Si)2, I2
TMSOTf_AgClO4
TMSOTf?|AgClO4 or TMSOTf
Trichloroisocyanuric acid (TCCA)_TMSOTf
TsCl,?Bu4N+Cl-
Zn_Cu
[Pt(C2H4)Cl2]2 Zeise?fs dimer
[R4N] [AOT]? (ionic liquid promoter), NIS
[Rh(??)(MeCN)3(triphos)](TfO)3
human-milk (1??34)-??-fucosyltransferase
h??
h??, TPT(triphenyltin?)
imidazole(DMAP)??Bu3SnH, reflux??HF(nBu4NF)
lipid-coated ??-D-galactosidase
pTsOH,? BF3?EEt2O
thermal condition (110?`120??)
thermal condition (140??)
thermal condition (60 or 160??)
thiourea?n
uridine-5?e-diphospho-galactose 4-epimerase
??
??(1??3) galactosyltransferase
??-galactosidase from Aspergillus niger
??-galactosidase from Aspergillus oryzae
??-galactosidase from Penicillium multicolor
??-galactosidase from Talaromyces flavus
??2-3-sialyltransferase (ST3Gal-I)
??2-6-sialyltransferase (ST6GalNAc-I)
??2_3-Sialyltransferase
??-(1??4)-mannosyltransferase
??-Galactosidase
??-Galactosidase from Aspergillus oryzae
??-Mannosyltransferase
??-N-Acetylhexosaminidase from Aspergillus oryzae
??-N-acetylhexosaminidase
??-d-galactosidase
??-d-mannanase from Aspergillus niger
??-galactosidase
??-galactosidase from Bacillus circulans
??-galactosidase from bovine testes
??-glucosidase
??-glucosidase from almond
??-glycosidase from Aspergillus oryzae
??-glycosidase from Thermus thermophilus
??-mannosidase from Aspergillus oryzae
??-mannosidase from Helix pomatia
?⑫?A?R?????g?Q??
??-Galactosidases from Coffea arabica, Aspergillus niger and A. oryzae
??-1,4-galactosyl transferase from bovine colostrum
sucrose synthase and UDP-Glc 4??-epimerase and ??-1,4-galactosyltransferase