GlycoNAVI: CheGly (Chemical Glycosylation)
CheGly
PROM-1
Promoter TMSOTf
Leaving_Group COC6H4-p-NO2
Title TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE (TRIMETHYLSILYL TRIFLATE) AS AN EXCELLENT GLYCOSIDATION REAGENT FOR ANTHRACYCLINE SYNTHESIS. SIMPLE AND EFFICIENT SYNTHESIS OF OPTICALLY PURE 4-DEMETHOXYDAUNORUBICIN
Citation Chem. Lett. 1984, 501
DOI 10.1246/cl.1984.501
PROM-10
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Synthesis of Oligodeoxynucleotides Containing 5-(??-D-Glucopyranosyloxymethyl)-2??-deoxyuridine, a Modified Nucleoside in the DNA of Trypanosoma Brucei
Citation Eur. J. Org. Chem. 1999, 2337
DOI 10.1002/(SICI)1099-0690(199909)
PROM-100
Promoter TMSOTf
Leaving_Group ?
Title Stereoselective Synthesis of ??-Glucosides with l, l??-Diacetal Structure
Citation Angew. Chem., Int. Ed. EngL 1981, 20, 969
DOI 10.1002/anie.198109691
PROM-1000
Promoter Tf2O, DTBMP
Leaving_Group SPh
Title _-Mannopyranosides and Other Hindered Glycosides
Citation J. Am. Chem. Soc. 1998, 120, 435
DOI 10.1021/ja9734814
PROM-1001
Promoter Tf2O, DTBMP
Leaving_Group SPh
Title S-(4-Methoxyphenyl) Benzenethiosulfinate (MPBT)/Trifluoromethanesulfonic Anhydride:_ A Convenient System for the Generation of Glycosyl Triflates from Thioglycosides
Citation Org. Lett. 2000, 2, 4067
DOI 10.1021/ol006715o
PROM-1002
Promoter Tf2O, DTBMP
Leaving_Group S(O)Tol, STol
Title Mechanism of Glycosylations with 2,3-Anhydrofuranosyl Glycosyl Sulfoxides
Citation J. Am. Chem. Soc. 2003, 125, 13112
DOI 10.1021/ja0349610
PROM-1003
Promoter Tf2O, DTBMP
Leaving_Group 2'-caboxybenzyl glycoside
Title 2-(Hydroxycarbonyl)benzyl Glycosides:_ A Novel Type of Glycosyl Donors for Highly Efficient ??-Mannopyranosylation and Oligosaccharide Synthesis by Latent-Active Glycosylation
Citation J. Am. Chem. Soc. 2001, 123, 8477
DOI 10.1021/ja015842s
PROM-1004
Promoter Tf2O, DTBMP
Leaving_Group S(O)Ph
Title 4,6-O-Benzylidene-d-glycopyranosyl Triflates
Citation J. Org. Chem. 1999, 64, 4926
DOI 10.1021/jo990243d
PROM-1005
Promoter Tf2O, DTBMP
Leaving_Group sulfoxide
Title 4,6-O-benzylidene protected mannopyranosyl sulfoxides be reached with trichloroacetimidates?
Citation Tetrahedron Lett. 2000, 41, 8753
DOI 10.1016/S0040-4039(00)01497-0
PROM-1006
Promoter Tf2O, DTBMP
Leaving_Group S(O)Tol, STol
Title daburi
Citation daburi
DOI 10.1021/ja029302m
PROM-1007
Promoter Tf2O, DTBMP
Leaving_Group -S(O)Et
Title ??-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method
Citation J. Org. Chem. 1996, 61, 4506
DOI 10.1021/jo9606517
PROM-1008
Promoter Tf2O, DTBMP
Leaving_Group SPh, S(O)Et, S(O)Ph
Title Highly Diastereoselective ??-Mannopyranosylation in the Absence of Participating Protecting Groups
Citation J. Org. Chem. 2000, 65, 1291
DOI 10.1021/jo9910482
PROM-1009
Promoter Tf2O, DTBMP
Leaving_Group STol, S(O)Tol
Title ???Ԃ?
Citation ???Ԃ?
DOI 10.1021/ol007008y
PROM-101
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Solid-Phase Synthesis of 6-Deoxyoligosaccharides
Citation J. Am. Chem. Soc. 1996, 118, 9998
DOI 10.1021/ja962128f
PROM-1010
Promoter Tf2O, DTBMP
Leaving_Group STol, S(O)Tol
Title ???Ԃ?
Citation ???Ԃ?
DOI 10.1021/ja029302m
PROM-1011
Promoter Tf2O, DTBMP
Leaving_Group S(O)Ph
Title Synthesis of Vancomycin from the Aglycon
Citation J. Am. Chem. Soc. 1999, 121, 1237
DOI 10.1021/ja983504u
PROM-1012
Promoter Tf2O, DTBMP
Leaving_Group S(O)Ph
Title Generalizing Glycosylation: Synthesis of the Blood Group
Citation J. Am. Chem. Soc. 1996, 118, 9239
DOI 10.1021/ja9608555
PROM-1013
Promoter Tf2O, DTBMP
Leaving_Group ?
Title Catalysis-Based Total Synthesis of Putative Mandelalide_A
Citation Angew. Chem., Int. Ed. 2014, 53, 4217
DOI 10.1002/anie.201400605
PROM-1014
Promoter Tf2O, DTBMP
Leaving_Group SPh, PhS(O)OMe, PhS(O), SPhCl2
Title Scavenging Byproducts in the Sulfoxide Glycosylation Reaction:Application to the Synthesis of Ciclamycin 0
Citation J. Am. Chem. Soc. 1999, 121, 6176
DOI 10.1021/ja990690a
PROM-1015
Promoter Tf2O, TTBP
Leaving_Group SPh
Title ???Ԃ?
Citation ???Ԃ?
DOI 10.1021/ja0111481
PROM-1016
Promoter Tf2O, TTBP
Leaving_Group PhS(O)-
Title 1-Naphthylpropargyl Ether Group:_ A Readily Cleaved and Sterically Minimal Protecting System for Stereoselective Glycosylation
Citation Org. Lett. 2006, 8, 4879
DOI 10.1021/ol061938l
PROM-1017
Promoter Tf2O, TTBP
Leaving_Group SEt, S(O)Et
Title Direct Chemical Synthesis of the ??-D-Mannans: The ??-(1??2) and ??-(1??4) Series
Citation J. Am. Chem. Soc. 2004, 126, 14930
DOI 10.1021/ja047194t
PROM-1018
Promoter Tf2O, TBP
Leaving_Group SEt, -C(NH)CCl3, F, S(O)Ph
Title daburi
Citation daburi
DOI 10.1021/ja809554x
PROM-1019
Promoter Ph2SO-Tf2O
Leaving_Group SEt
Title Sequential One-Pot Glycosylations Using 1-Hydroxyl and 1-Thiodonors
Citation Org. Lett. 2003, 5,1947
DOI 10.1021/ol034528v
PROM-102
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title The Dimethylmaleoyl Group as Amino Protective Group _ Application to the Synthesis of Glucosamine-Containing Oligosaccharides
Citation Eur. J. Org. Chem. 1998, 2305
DOI ?10.1002/(SICI)1099-0690(199811)1998:11<2305::AID-EJOC2305>3.0.CO;2-W
PROM-1020
Promoter Ph2SO-Tf2O
Leaving_Group SPMP
Title daburi
Citation daburi
DOI 10.1021/ol034528v
PROM-1021
Promoter Ph2SO-Tf2O
Leaving_Group OH
Title Dehydrative Glycosylation with Activated Diphenyl Sulfonium Reagents. Scope, Mode of C(1)-Hemiacetal Activation, and Detection of Reactive Glycosyl Intermediates
Citation J. Am. Chem. Soc. 2000, 122, 4269
DOI 10.1021/ja993595a
PROM-1022
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title Synthesis of Hyaluronic Acid Oligomers Using Ph2SO/Tf2O-Mediated Glycosylations
Citation J. Org. Chem. 2007, 72, 5737
DOI 10.1021/jo070704s
PROM-1023
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title Equatorial Anomeric Triflates from Mannuronic Acid Esters
Citation J. Am. Chem. Soc. 2009, 131, 12080
DOI 10.1021/ja905008p
PROM-1024
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title Selective Synthesis of 1,2-cis-??-Glycosides without Directing Groups. Application to Iterative Oligosaccharide Synthesis
Citation Org. Lett. 2013, 15, 2566
DOI 10.1021/ol401095k
PROM-1025
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title Stereoselective Synthesis of 2,3-Diamino-2,3-dideoxy-??-d-mannopyranosyl Uronates
Citation J. Org. Chem. 2011, 76, 7301
DOI 10.1021/jo201179p
PROM-1026
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title Stereocontrolled Synthesis of ??-D-Mannuronic Acid Esters, Synthesis of an Alginate Trisaccharide
Citation J. Am. Chem. Soc. 2006, 128, 13066
DOI 10.1021/ja064787q
PROM-1027
Promoter Ph2SO-Tf2O
Leaving_Group SPh, OCO(NPh)CF3
Title Equatorial Anomeric Triflates from Mannuronic Acid Esters, excellent ??-selectivity in glycosylations
Citation J. Am. Chem. Soc. 2009, 131, 12080
DOI 10.1021/ja905008p
PROM-1028
Promoter Ph2SO-Tf2O
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1002/ejoc.201200717
PROM-1029
Promoter Ph2SO-Tf2O
Leaving_Group SPh, SPMP
Title Ph2SO/Tf2O:_ a Powerful Promotor System in Chemoselective Glycosylations Using Thioglycosides
Citation Org. Lett. 2003, 5,1519
DOI 10.1021/ol034312t
PROM-103
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Synthesis of chitotetraose and chitohexaose based on dimethylmaleoyl protection
Citation Carbohydr. Res. 2001, 331, 129
DOI 10.1016/S0008-6215(01)00024-6
PROM-1030
Promoter Ph2SO-Tf2O
Leaving_Group S(O)Tol, STol
Title daburi
Citation daburi
DOI 10.1021/jo061440x
PROM-1031
Promoter Ph2SO-Tf2O
Leaving_Group azid
Title Study of the Glycosidation Properties of 1-Thiomannosazidopyranosides and 1-Thiomannosaziduronic Acid Esters
Citation Eur. J. Org. Chem. 2007, 116
DOI 10.1002/ejoc.200600759
PROM-1032
Promoter Ph2SO-Tf2O
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/jo061417b
PROM-1033
Promoter Ph2SO-Tf2O
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-1034
Promoter Ph2SO-Tf2O
Leaving_Group Br, Cl, SPh
Title daburi
Citation daburi
DOI 10.1093/glycob/cwj125
PROM-1035
Promoter Ph2SO-Tf2O
Leaving_Group OSPh2
Title Direct Glycosylations with 1-Hydroxy Glycosyl Donors using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
Citation J. Am. Chem. Soc. 1997, 119, 7597.
DOI 10.1021/ja971067y
PROM-1036
Promoter Ph2SO-Tf2O
Leaving_Group OH
Title Dehydrative Glycosylation with Activated Diphenyl Sulfonium Reagents. Scope, Mode of C(1)-Hemiacetal Activation, and Detection of Reactive Glycosyl Intermediates
Citation J. Am. Chem. Soc. 2000, 122, 4269
DOI 10.1021/ja993595a
PROM-1037
Promoter PhIO-Tf2O
Leaving_Group SMe
Title Iodosobenzene-triflic anhydride as an efficient promoter for glycosidation reaction using thioglycosides as donors
Citation Tetrahedron Lett. 1992. 33, 7165
DOI 10.1016/S0040-4039(00)60863-8
PROM-1038
Promoter TTBP-Tf2O
Leaving_Group SPh
Title Mechanisms of ??- and ??_O- and ??_C-Glycosylation in the Mannopyranose Series
Citation J. Am. Chem. Soc. 2012, 134, 14746
DOI 10.1021/ja307266n
PROM-1039
Promoter SO2Cl2-TfOH
Leaving_Group SMe, SEt, SPh
Title Sulfurylchloride/trifluoromethanesulfonic acid. A novel promoter system for glycoside synthesis using thioglycosides as glycosyl donors
Citation Glycoconjugate J. 1987, 4, 117
DOI 10.1007/BF01049449
PROM-104
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Fluorous-Based Carbohydrate Microarrays
Citation J. Am. Chem. Soc. 2005, 127, 13162
DOI 10.1021/ja054811k
PROM-1040
Promoter SO2Cl2-TfOH
Leaving_Group SMe
Title Glycosidations with thioglycosides activated by sulfuryl chloride/trifluoromethanesulfonic acid: synthesis of a human blood group B trisaccharide glycoside
Citation Glycoconjugate J. 1988, 5, 3-8
DOI 10.1007/BF01048326
PROM-1041
Promoter MPBT-Tf2O
Leaving_Group SPMP
Title A novel approach towards the stereoselective synthesis of 2-azido-2-deoxy-??-d-mannosides
Citation Tetrahedron Lett. 2001, 42, 8693?
DOI 10.1016/S0040-4039(01)01880-9
PROM-1042
Promoter TrClO4 (cat)-TMSOTf
Leaving_Group SCN
Title Novel highly stereospecific method of 1,2-cis-glycosylation. Synthesis of ??-D-glucosyl-D-glucoses
Citation Tetrahedron Lett. 1989, 30, 5459
DOI 10.1016/S0040-4039(01)80593-1
PROM-1043
Promoter n-Bu2SO/TMSOTf
Leaving_Group trichloroacetimidate, F
Title daburi
Citation daburi
DOI 10.1021/ja971574f
PROM-1044
Promoter TMSOTf(cat.), SiF4(cat)
Leaving_Group F
Title Glycosylation using glucopyranosyl fluorides and silicon-based catalysts. Solvent dependency of the stereoselection
Citation Tetrahedron Lett. 1984. 25, 1379
DOI 10.1016/S0040-4039(01)80163-5
PROM-1045
Promoter BF3?EEt2O/TMSOTf
Leaving_Group -O-P(=NTs)-Ph2
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(97)01122-2
PROM-1046
Promoter BF3?EEt2O/TMSOTf
Leaving_Group -O-P(=O)-(NMe2)2
Title An efficient construction of 1,2-trans-??-glycosidic linkages capitalizing on glycopyranosyl N,N,N??,N??-tetramethylphosphroamidates as shelf-stable glycosyl donors
Citation Tetrahedron Lett. 1992, 33, 3523
DOI 10.1016/S0040-4039(00)92679-0
PROM-1047
Promoter BF3?EEt2O/TMSOTf
Leaving_Group isopropenyl glycoside
Title Isopropenyl glycosides and congeners as novel classes of glycosyl donors: theme and variations
Citation J. Am. Chem. Soc. 1992, 114, 6354
DOI 10.1021/ja00042a010
PROM-1048
Promoter BF3?EEt2O/TMSOTf
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1002/jlac.198419841108
PROM-1049
Promoter BF3?EEt2O/TMSOTf
Leaving_Group enol ether, OC(O)OC(=CH2)CH3
Title daburi
Citation daburi
DOI 10.1351/pac199163040519
PROM-105
Promoter TMSOTf
Leaving_Group trichloroacetimidate, F
Title New Synthetic Technology for the Stereocontrolled Construction of 1,1??-Disaccharides and 1,1??:1????,2-Trisaccharides. ynthesis of the FG Ring System of Everninomicin 13,384-1
Citation J. Am. Chem. Soc. 1997, 119, 9057
DOI 10.1021/ja971574f
PROM-1050
Promoter N-(p-methylphenylthio)-??-caprolactam-TMSOTf
Leaving_Group STol
Title Efficient activation of thioglycosides with N-(p-methylphenylthio)-??-caprolactam-TMSOTf
Citation Carbohydr. Res. 2012, 354, 40
DOI 10.1016/j.carres.2012.03.024
PROM-1051
Promoter TMSCIO4-(CCl3CO)2O
Leaving_Group OH
Title Novel Dehydrative Glycosylation by Using Acid Anhydride and TMSClO4
Citation Chem Lett. 1999, 27
DOI 10.1246/cl.1999.27
PROM-1052
Promoter TMSI-(C4H8N)3P=O
Leaving_Group OAc
Title Glycosyl Phosphonium Halide as a Reactive Intermediate in Highly ??-Selective Glycosylation
Citation Bull. Chem. Soc. Jpn. 2005, 78, 910
DOI 10.1246/bcsj.78.910
PROM-1053
Promoter TMSI-Ph3P=O
Leaving_Group OAc
Title Highly ??-Selective Glycosylation with Glycosyl Acetate via Glycosyl Phosphonium Iodide
Citation Chem. Lett. 2004, 33, 874
DOI 10.1246/cl.2004.874
PROM-1054
Promoter TMSI-Ph3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1984.907
PROM-1055
Promoter TMSI-(pyrrolidine)3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1056
Promoter TMSI-(Me2N)3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1057
Promoter TMSI-(N-Morpholinyl)3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1058
Promoter TMSI-Ph3P=S
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1059
Promoter TMSI-Ph2P(=O)OPh
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-106
Promoter TMSOTf
Leaving_Group tetrazole, -OP(OEt)2
Title daburi
Citation daburi
DOI 10.1021/ja973348b
PROM-1060
Promoter TMSI-n-Bu3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1061
Promoter TMSI-Ph2P(=O)Me
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1062
Promoter TMSI-(p-MeOPh)3P=O
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-1063
Promoter DEAD-Ph3P
Leaving_Group OH
Title A highly stereoselective synthesis of aryl 2-deoxy-.beta.-glycosides via the Mitsunobu reaction
Citation J. Org. Chem. 1991, 56, 5740
DOI 10.1021/jo00020a003
PROM-1064
Promoter (TMS)3SiH, AIBN
Leaving_Group Br
Title Addition of an Apiosyl Radical to Activated Olefins - Synthesis of C-Apiosyl Compounds
Citation Synthesis 1996, 1451
DOI 10.1055/s-1996-4407
PROM-1065
Promoter TBAI-DIPEA
Leaving_Group I
Title Glycosyl iodides are highly efficient donors under neutral conditions
Citation Carbohydr. Res. 1999, 320, 61
DOI 10.1016/S0008-6215(99)00146-9
PROM-1066
Promoter TBAI-DIPEA, reflux
Leaving_Group I
Title Solution-Phase Hexasaccharide Synthesis Using Glucosyl Iodides
Citation Org. Lett. 2002, 4, 2039
DOI 10.1021/ol025887d
PROM-1067
Promoter BF3 _ Et2O-DTBMP
Leaving_Group F
Title Highly Efficient ??-Glucosylation of the Acidic Hydroxyl Groups, Phenol and Carboxylic Acid, with an Peracetylated Glucosyl Fluoride Using a Combination of BF3 _ Et2O and DTBMP as a Promoter
Citation Synlett 1999, 1627
DOI 10.1055/s-1999-12529
PROM-1068
Promoter BF3?EEt2O, TMSOTf
Leaving_Group -O-P(=NTs)-Ph2
Title A Mild and Rapid 1,2-trans-Glycosidation Method via Benzoyl-protected Glycopyranosyl P,P-Diphenyl-N-(p-toluenesulfonyl)phosphinimidates
Citation Heterocycles 1990, 30, 775
DOI 10.3987/COM-89-S98
PROM-1069
Promoter BF3?EOEt2, p-TsOH
Leaving_Group ?
Title Synthesis and enzymic formation of a C-glucuronide of .DELTA.6-tetrahydrocannabinol
Citation J. Am. Chem. Soc. 1977, 99, 6444
DOI 10.1021/ja00461a048
PROM-107
Promoter TMSOTf
Leaving_Group STol, -C(NH)CCl3
Title Synthesis of the Docosanasaccharide Arabinan Domain of Mycobacterial Arabinogalactan and a Proposed ctadecasaccharide Biosynthetic Precursor
Citation J. Am. Chem. Soc. 2007, 129, 9885
DOI 10.1021/ja072892+
PROM-1070
Promoter HClO4?ESiO2
Leaving_Group trichloroimidate
Title HClO4_SiO2 catalyzed glycosylation using sugar trichloroacetimidates as glycosyl donors
Citation Tetrahedron Lett. 2006, 47, 307
DOI 10.1016/j.tetlet.2005.11.025
PROM-1071
Promoter HClO4?ESiO2
Leaving_Group trichloroimidate
Title From Solution Phase to ?gOn-Column?h Chemistry:_ Trichloroacetimidate-Based Glycosylation Promoted by Perchloric Acid?|Silica
Citation J. Org. Chem. 2005, 70, 9059
DOI 10.1021/jo051390g
PROM-1072
Promoter Trichloroisocyanuric acid (TCCA)_TMSOTf
Leaving_Group SR (R = ?)
Title Trichloroisocyanuric acid (TCCA)_TMSOTf: an efficient activator system for glycosylation reactions based on thioglycosides
Citation RSC Adv. 2012, 2, 12661
DOI 10.1039/C2RA21851H
PROM-1073
Promoter Me2S2-Tf2O
Leaving_Group SR (R = ?)
Title A New, Powerful Glycosylation Method:_ Activation of Thioglycosides with Dimethyl Disulfide?|Triflic Anhydride
Citation Org. Lett. 2007, 9, 4647
DOI 10.1021/ol702139u
PROM-1074
Promoter benzenesulfinyl morpholine, Tf2O
Leaving_Group SR (R = ?)
Title Benzenesulfinyl Morpholine: A New Promoter for One-Pot Oligosaccharide Synthesis Using Thioglycosides by Pre-Activation Strategy
Citation Synlett 2006, 2846
DOI 10.1055/s-2006-950247
PROM-1075
Promoter TrB(C6F5)4, PhthNSEt
Leaving_Group SEt
Title Effective Activation of ?eArmed?f Thioglycoside with a New Combination of Trityl Tetrakis(pentafluorophenyl)borate [TrB(C6F5)4] and N-(Ethylthio)phthalimide (PhthNSEt)
Citation Chem. Lett. 2000, 29, 1178
DOI 10.1246/cl.2000.1178
PROM-1076
Promoter TrClO4, I2
Leaving_Group -O=P(=S)-Me2
Title A Novel Glycosylation Reaction of 2-Amino-2-deoxy-D-glucopyranose Using Dimethylphosphinothioate
Citation Chem Lett. 1989. 69
DOI 10.1246/cl.1989.69
PROM-1077
Promoter TrClO4, I2
Leaving_Group -O=P(=S)-Me2
Title 1,2-cis-??-Mannopyranoside Formation by the Dimethylphosphinothioate Method
Citation Chem Lett. 1993. 343
DOI 10.1246/cl.1993.343
PROM-1078
Promoter TrClO4-TMSOTf
Leaving_Group OAc
Title Replicative Chirons:_ Stereoselective Synthesis of Oligo-Tetrahydrofuranic Lactones via C-Glycosylation with [(Trimethylsilyl)oxy]furan
Citation J. Org. Chem. 1997, 62, 3428
DOI 10.1021/jo970212n
PROM-1079
Promoter MeOTf, 2,6-lutidine
Leaving_Group SEt
Title Highly ??-Selective and Direct Formation of 2-O-Glycosylated Glucosides by Ring Restriction into Twist-Boat
Citation Org. Lett. 2007, 9, 2755
DOI 10.1021/ol070720b
PROM-108
Promoter TMSOTf
Leaving_Group OH, OAc, -C(NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja801008m
PROM-1080
Promoter DMTST, Bu4NBr
Leaving_Group SMe
Title Synthesis of 1,2-cis-linked glycosides using dimethyl(methylthio) sulfonium triflate as promoter and thioglycosides as glycosyl donors
Citation Tetrahedron Lett. 1986, 27, 3919
DOI 10.1016/S0040-4039(00)83917-9
PROM-1081
Promoter Tf2O, 1-benzenesulfinyl piperidine
Leaving_Group OSO2(2-CF3Ph)
Title On the nitrile effect in l-rhamnopyranosylation,? 5% acetonitrile or propionitrile
Citation Carbohydr. Res. 2006, 341, 1467
DOI 10.1016/j.carres.2006.03.036
PROM-1082
Promoter Tf2O, base
Leaving_Group S(O)Ph
Title Sulfenate Intermediates in the Sulfoxide Glycosylation Reaction
Citation J. Am. Chem. Soc. 1998, 120, 5961
DOI 10.1021/ja980827h
PROM-1083
Promoter KHMDS, Ts2O
Leaving_Group OTs
Title A Reagent-Controlled SN2_Glycosylation for the Direct Synthesis of ??_Linked 2_Deoxy-Sugars
Citation J. Am. Chem. Soc. 2014, 136, 5740
DOI 10.1021/ja500410c
PROM-1084
Promoter TfOH/TEP
Leaving_Group PhS(O)-
Title A new promoter system for the sulfoxide glycosylation reaction
Citation Tetrahedron Lett. 1996, 37, 1477
DOI 10.1016/0040-4039(96)00043-3
PROM-1085
Promoter I2/Et3SiH
Leaving_Group trichloroimidate, -O-C(=NPh)-CF3
Title Iodine/Triethylsilane as a Convenient Promoter System for the Activation of Disarmed Glycosyl Trichloro- and N-(Phenyl)trifluoroacetimidates
Citation Synlett. 2002, 269
DOI 10.1055/s-2002-19770
PROM-1086
Promoter I2/Et3SiH
Leaving_Group OAc
Title Efficient and direct synthesis of saccharidic 1,2-ethylidenes, orthoesters, and glycals from peracetylated sugars via the in situ generation of glycosyl iodides with I2/Et3SiH
Citation Tetrahedron Lett. 2003, 44, 7863
DOI 10.1016/j.tetlet.2003.09.022
PROM-1087
Promoter I2/Et3SiH
Leaving_Group ?
Title Direct and Stereoselective Synthesis of ??-Linked 2,6-Deoxyoligosaccharides
Citation Angew. Chem. Int. Ed. 2007, 46, 2505
DOI 10.1002/anie.200604031
PROM-1088
Promoter (p-NO2Ph)(Ph)SO, Tf2O
Leaving_Group OH
Title Dehydrative Sialylation with C2-Hemiketal Sialyl Donors
Citation Org. Lett. 2003, 5, 2539
DOI 10.1021/ol034815z
PROM-1089
Promoter LPTS(2,6-lutidinium p-toluenesulfonate)-nBu4NI
Leaving_Group -S-P(=NPh)-(NMe2)2
Title An extremely mild and general method for the stereocontrolled construction of 1,2-cis-glycosidic linkages via S-glycopyranosyl phosphorodiamidimidothioates
Citation Tetrahedron Lett. 1990, 31, 4769
DOI 10.1016/S0040-4039(00)97729-3
PROM-109
Promoter TMSOTf
Leaving_Group SPh, -C(NH)CCl3, S-2,6-MePh
Title daburi
Citation daburi
DOI 10.1021/ja807482t
PROM-1090
Promoter LPTS-nBu4NI
Leaving_Group -O-P(=NPh)-(OEt)2, -O-P-(NiPr2)(OEt)
Title GLYCOSYL DONORS WITH PHOSPHORIMIDATE LEAVING GROUPS FOR EITHER ??- OR ??- GLYCOSIDATION
Citation Tetrahedron Lett. 1997, 38, 6139
DOI 10.1016/S0040-4039(97)01418-4
PROM-1091
Promoter DTPBI-TBAI
Leaving_Group -O-P--(OEt)2
Title An extremely mild and stereocontrolled construction of 1,2-cis-??-glycosidic linkages via benzyl-protected glycopyranosyl diethyl phosphites
Citation Chem. Commun. 1999,?1259
DOI 10.1039/A902845E
PROM-1092
Promoter Br2/TMSOTf
Leaving_Group SePh
Title A New, Iterative Strategy of Oligosaccharide Synthesis Based on Highly Reactive ??-Bromoglycosides Derived from Selenoglycosides
Citation Org. Lett. 2001, 3, 3867
DOI 10.1021/ol016713j
PROM-1093
Promoter TsCl,?Bu4N+Cl-
Leaving_Group OH
Title An Efficient Synthesis of Benzothiazole Derivatives of Thiosugars under Phase-Transfer Conditions?
Citation Chem. Lett. 1988, 1975
DOI 10.1246/cl.1988.1975
PROM-1094
Promoter IBr-TfOH
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-1095
Promoter ICl-TfOH
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-1096
Promoter PhIO-TfOH
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-1097
Promoter PhIO-TMSOTf
Leaving_Group SPh
Title Stereoselective glycosylation using the long-range effect of a [2-(4-phenylbenzyl)oxycarbonyl]benzoyl group
Citation Tetrahedron: Asymmetry 2005, 16, 441
DOI 10.1016/j.tetasy.2004.11.042
PROM-1098
Promoter Me2(MeS)S+OTf- and Bu4N+Br-
Leaving_Group SR (R = ?)
Title Synthesis of 1,2-cis-linked glycosides using dimethyl(methylthio) sulfonium triplate as promoter and thioglycosides as glycosyl donors
Citation Tetrahedron Lett. 1986, 27, 3919
DOI 10.1016/S0040-4039(00)83917-9
PROM-1099
Promoter TMSOTf-PhSEt
Leaving_Group trichloroimidate
Title Stereoselective Glycosylations of 2-Azido-2-deoxy-glucosides Using Intermediate Sulfonium Ions
Citation Org. Lett. 2007, 9, 1959
DOI 10.1021/ol070513b
PROM-11
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Facile syntheses of a hexasaccharide and a nonasaccharide related to the cell wall D-mannan of yeast Candida albicans
Citation Tetrahedron Lett. 1999, 40, 1357
DOI 10.1016/S0040-4039(98)02625-2
PROM-110
Promoter TMSOTf (cat.)
Leaving_Group trichloroimidate
Title Synthesis of a Glycosylphosphatidylinositol Anchor Bearing Unsaturated Lipid Chains
Citation J. Am. Chem. Soc. 2010, 132, 6648
DOI 10.1021/ja1009037
PROM-1100
Promoter TMSOTf-thiophene
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1021/ol070513b
PROM-1101
Promoter HF-pyridine complex
Leaving_Group azid
Title A new method of anomeric protection and activation based on the conversion of glycosyl azides into glycosyl fluorides
Citation Carbohydr. Res. 1993, 249, 221
DOI 10.1016/0008-6215(93)84071-D
PROM-1102
Promoter HF-pyridine complex
Leaving_Group azid
Title O-(1-Phenyl-1H-tetrazol-5-yl) Glycosides: Alternative synthesis and transformation into glycosyl fluorides
Citation Helv. Chim. Acta 1995, 78, 959
DOI 10.1002/hlca.19950780418
PROM-1103
Promoter NaH, decyl trifluoromethanesulfonate
Leaving_Group OH
Title Glycoside Bond Formation via Anomeric O-Alkylation: How Many Protective Groups Are Required
Citation Synlett. 1991, 168
DOI 10.1055/s-1991-20665
PROM-1104
Promoter I2/Et3N
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes a new approach to glycoside synthesis. Part 1. Preparation of glycosylidene-derived diaziridines and diazirines
Citation Helv. Chim. Acta 1989, 72, 1371
DOI 10.1002/hlca.19890720626
PROM-1105
Promoter polymer bound triarylphosphane-iodine complex and imidazole
Leaving_Group OH
Title Mild Synthesis of Protected ??-D-Glycosyl Iodides
Citation Eur. J. Org. Chem. 1999, 3147
DOI 10.1002/(SICI)1099-0690(199911)1999:11<3147::AID-EJOC3147>3.0.CO;2-I
PROM-1106
Promoter CBr4, PPh3, N,N-tetramethylurea(TMU)
Leaving_Group Br
Title An easy access to halide ion-catalytic ??-glycosylation using carbon tetrabromide and triphenylphosphine as multifunctional reagents
Citation Org Biomol Chem 2003, 1, 2518
DOI 10.1039/B303984F
PROM-1107
Promoter CBr4, PPh3
Leaving_Group Br
Title One-pot ??-glycosylation pathway via the generation in situ of ??-glycopyranosyl imidates in N,N-dimethylformamide
Citation Carbohydr. Res. 2005, 340, 2236
DOI 10.1016/j.carres.2005.07.020
PROM-1108
Promoter Me3OBF4, 4-Me-DTBP
Leaving_Group tetrazole, -OP(OEt)2
Title Synthesis of the Hexasaccharide Fragment of Landomycin A: Application of Glycosyl Tetrazoles and Phosphites in the Synthesis of a Deoxyoligosaccharide
Citation J. Am. Chem. Soc. 1998, 120, 1392
DOI 10.1021/ja973348b
PROM-1109
Promoter MeOTf, DTBP
Leaving_Group SEt, -C(NH)CCl3, F, S(O)Ph
Title Toward Fully Synthetic Homogeneous ??-Human Follicle-Stimulating Hormone (??-hFSH) with a Biantennary N-Linked Dodecasaccharide. Synthesis of ??-hFSH with Chitobiose Units at the Natural Linkage Sites
Citation J. Am. Chem. Soc. 2009, 131, 5792
DOI 10.1021/ja809554x
PROM-111
Promoter TMSOTf
Leaving_Group OAc
Title Thiazolylketol acetates as glycosyl donors. Stereoselective synthesis of ??-linked ketodisaccharides
Citation Tetrahedron. 1996, 52, 3057
DOI 10.1016/0040-4020(95)01095-5
PROM-1110
Promoter MeOTf-TrClO4
Leaving_Group ?
Title A highly convergent synthesis of a hexasaccharide derived from the oligosaccharide of group B type III Streptococcus
Citation Tetrahedron Lett. 1997, 38, 1629
DOI 10.1016/S0040-4039(97)00106-8
PROM-1111
Promoter DMTST-DTBMP
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1021/ja982232s
PROM-1112
Promoter 1-benzenesulfinylpiperidine-Tf2O
Leaving_Group ?
Title Synthesis of a Pentasaccharide Fragment of Varianose, a Cell Wall Polysaccharide from Penicillium varians
Citation J. Org. Chem. 2006, 71, 9672
DOI 10.1021/jo061821a
PROM-1113
Promoter Br2, silver silicate
Leaving_Group SPh
Title An unusual course of thioglycoside activation with bromine: synthesis and crystal structure of 4-O-acetyl-2-bromo-2,3,6-trideoxy-3-C-methyl-3-trifluroacetamido-??-l-altropyranosyl bromide
Citation Carbohydr. Res. 2003, 338, 1121
DOI 10.1016/S0008-6215(03)00066-1
PROM-1118
Promoter PPh3-DIAD
Leaving_Group OH
Title Total Synthesis of Nucleoside Antibiotic A201A
Citation J. Am. Chem. Soc. 2014, 136, 4157
DOI 10.1021/ja501460j
PROM-1119
Promoter BSM-TTBP-Tf2O
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1039/B712591G
PROM-1120
Promoter BSM-Tf2O (additive: TTBP)
Leaving_Group STol
Title Additive-Controlled Stereoselective Glycosylations of Oxazolidinone-Protected Glucosamine and Galactosamine Thioglycoside Donors Based on Preactivation Protocol
Citation Synlett 2010, 2506
DOI 10.1055/s-0030-1258557
PROM-1121
Promoter BSP-Tf2O-TTBP
Leaving_Group SPhMe
Title glycosidation of 2,3-Oxazolidinone-Protected 1-Tolylthio-N-acetyl-d-glucosamine
Citation J. Org. Chem. 2005, 70, 4195
DOI 10.1021/jo047812o
PROM-1122
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title Synthesis and Stereoselective Glycosylation of d- and l-glycero-??-d-manno-Heptopyranoses
Citation Org. Lett. 2005, 7, 1395.
DOI 10.1021/ol050224s
PROM-1123
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title Synthesis of the D- and L-glycero-??-D-manno-Heptopyranosides
Citation J. Am. Chem. Soc. 2006, 128, 8078
DOI 10.1021/ja061594u
PROM-1124
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title 6-Mono-, Di-, and Trifluoro S-Phenyl 2,3,4-Tri-O-benzyl-thiorhamnopyranosides
Citation J. Am. Chem. Soc. 2007, 129, 11756
DOI 10.1021/ja0730258
PROM-1125
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title Direct Synthesis of the ??-L-Rhamnopyranosides
Citation Org. Lett. 2003, 5, 781
DOI 10.1021/ol0340890
PROM-1128
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title 1-Benzenesulfinyl Piperidine/Trifluoromethanesulfonic Anhydride:_ A Potent Combination of Shelf-Stable Reagents for the Low-Temperature Conversion of Thioglycosides to Glycosyl Triflates and for the Formation of Diverse Glycosidic Linkages
Citation J. Am. Chem. Soc.?2001, 123, 9015
DOI 10.1021/ja0111481
PROM-1129
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/jo3011655
PROM-113
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Synthesis of Verbascoside: A Dihydroxyphenylethyl Glycoside with Diverse Bioactivity
Citation Eur. J. Org. Chem. 1999, 2623
DOI 10.1002/(SICI)1099-0690(199910)1999:10<2623::AID-EJOC2623>3.0.CO;2-K
PROM-1130
Promoter BSP-Tf2O-TTBP
Leaving_Group SEt
Title Benzylidene Acetal Fragmentation Route to 6-Deoxy Sugars:_ Direct Reductive Cleavage in the Presence of Ether Protecting Groups, Permitting the Efficient, Highly Stereocontrolled Synthesis of ??-d-Rhamnosides from d-Mannosyl Glycosyl Donors. Total Synthesis of ??-d-Gal-(1??3)-??-d-Rha-(1??3)- ??-d-Rha-(1??4)-??-d-Glu-OMe, the Repeating Unit of the Antigenic Lipopolysaccharide from Escherichia hermannii ATCC 33650 and 33652
Citation J. Am. Chem. Soc. 2004, 126, 8232
DOI 10.1021/ja048070j
PROM-1131
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title Direct Chemical Synthesis of the ??-Mannans:_ Linear and Block Syntheses of the Alternating ??-(1??3)-??-(1??4)-Mannan Common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa
Citation J. Am. Chem. Soc. 2004, 126, 15081
DOI 10.1021/ja0471931
PROM-1132
Promoter BSP-Tf2O-TTBP
Leaving_Group SPh
Title Solid-Phase Synthesis of ??-Mannosides
Citation J. Am. Chem. Soc. 2002, 124, 8867
DOI 10.1021/ja011406u
PROM-1133
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group OH
Title Direct Glycosylations with 1-Hydroxy Glycosyl Donors using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
Citation J. Am. Chem. Soc. 1997, 119, 7597
DOI 10.1021/ja971067y
PROM-1134
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group SPh
Title 4,6-O-[1-Cyano-2-(2-iodophenyl)ethylidene] Acetals, Reductive Radical Fragmentation to ??-d-Rhamnopyranosides
Citation J. Org. Chem. 2006, 71, 3452
DOI 10.1021/jo0526688
PROM-1135
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group SPh
Title Stereoselectivity of glycosylations of conformationally restricted mannuronate esters
Citation Tetrahedron 2009, 65, 3780
DOI 10.1016/j.tet.2009.02.067
PROM-1136
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group SPh
Title Efficient Glycosidation of a Phenyl Thiosialoside Donor with Diphenyl Sulfoxide and Triflic Anhydride in Dichloromethane
Citation Org. Lett. 2006, 8, 959
DOI 10.1021/ol060030s
PROM-1137
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group SPh
Title Stereoselective C-Glycoside Formation, 2-O-Benzyl-4,6-O-benzylidene Protected 3-Deoxy Gluco- and Mannopyranoside Donors
Citation J. Org. Chem. 2012, 77, 8905
DOI 10.1021/jo3011655
PROM-1138
Promoter Ph2SO-TTBP-Tf2O?
Leaving_Group SEt
Title daburi
Citation daburi
DOI 10.1021/ja048070j
PROM-1139
Promoter Ph2SO-Tf2O-TBP
Leaving_Group OH, OAc, -C(NH)CCl3
Title Synthesis and Structure Verification of the Vaccine Adjuvant QS-7-Api. Synthetic Access to Homogeneous Quillaja saponaria Immunostimulants
Citation J. Am. Chem. Soc. 2008, 130, 5860
DOI 10.1021/ja801008m
PROM-114
Promoter TMSOTf
Leaving_Group SEt, trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1038/nature00937
PROM-1140
Promoter Me2S-Tf2O-TTBP
Leaving_Group OH
Title Sulfide-Mediated Dehydrative Glycosylation
Citation J. Am. Chem. Soc. 2001, 123, 8766
DOI 10.1021/ja015968p
PROM-1141
Promoter nBu2S=O/(PhSO2)2O/TTBP
Leaving_Group OH
Title Sulfoxide Covalent Catalysis: Application to Glycosidic Bond Formation
Citation Angew. Chem. Int. Ed. 2003, 42, 5874
DOI 10.1002/anie.200352761
PROM-1142
Promoter nBu2S=O/(PhSO2)2O/TTBP
Leaving_Group OH
Title Probing the Mechanism of Sulfoxide-Catalyzed Hemiacetal Activation in Dehydrative Glycosylation
Citation J. Org. Chem. 2005, 70, 5818
DOI 10.1021/jo050294c
PROM-1143
Promoter CBr4/PPh3/DMF
Leaving_Group OH
Title One-Pot ??-Glycosylation Method Using Appel Agents in N,N-Dimethylformamide
Citation Org. Lett. 2003, 5, 2377
DOI 10.1021/ol034269+
PROM-1144
Promoter CuCl2/dppf/AgClO4
Leaving_Group OH
Title Dehydrative glycosylation of tri-O-benzylated 1-hydroxyribofuranose catalyzed by a copper(II) complex
Citation Tetrahedron Lett. 2003, 44, 2561
DOI 10.1016/S0040-4039(03)00270-3
PROM-1145
Promoter NIS-I2-TMSOTf
Leaving_Group I
Title Glycosidation with a Disarmed Glycosyl Iodide: Promotion and Scope
Citation Org. Lett. 2003, 5, 4545
DOI 10.1021/ol035475k
PROM-1146
Promoter TrB(C6F5)4+ I2+ DDQ
Leaving_Group SEt
Title A Novel Activating Agents of 'Disarmed' Thioglycosides, Combination of Trityl Tetrakis(pentafluorophenyl)borate, Iodine and DDQ
Citation Chem. Lett. 2000, 29, 692
DOI 10.1246/cl.2000.692
PROM-1147
Promoter Ph3PAuOTf, BF3_Et2O and DBU
Leaving_Group ortho-alkynylbenzoates
Title Chemoselective glycosylation of carboxylic acid with glycosyl ortho-hexynylbenzoates as donors
Citation Tetrahedron Lett. 2010, 51, 1504
DOI 10.1016/j.tetlet.2010.01.039
PROM-1148
Promoter AgOTf-PhSCl-DTBMP
Leaving_Group SPh
Title ?N-benzyl-2,3-trans-oxazolidinones as the glycosyl donors, Selective ??-Glycosylation
Citation J. Am. Chem. Soc. 2006, 128, 10666
DOI 10.1021/ja062531e
PROM-1149
Promoter AgOTf-PhSCl-DTBMP
Leaving_Group SPh
Title Oxazolidinone Protected 2-Amino-2-deoxy-D-glucose Derivatives as Versatile Intermediates in Stereoselective Oligosaccharide Synthesis and the Formation of r-Linked Glycosides
Citation J. Am. Chem. Soc. 2001, 123, 9461
DOI 10.1021/ja0162109
PROM-115
Promoter TMSOTf
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/jhet.5570280526
PROM-1150
Promoter Phthalic anhydride-DBU-Tf2O
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1021/ja907252u
PROM-1152
Promoter MsOH-CoBr2-R'4NBrX (R'=Et, Bu; X=Br, ClO4)
Leaving_Group OH
Title DIRECT GLUCOSIDATION OF TETRA-O-BENZYL-??-D-GLUCOPYRANOSE BY SYSTEM OF METHANESULFONIC ACID AND COBALT(II) BROMIDE
Citation Chem. Lett. 1976,?1109
DOI 10.1246/cl.1976.1109
PROM-1153
Promoter Me3SiBr, CoBr2, n-Bu4NBr
Leaving_Group OH
Title Stereoselective ??-Glucosylation with Tetra-O-benzyl-??-D-glucose and a Mixture of Trimethylsilyl Bromide, Cobalt(II) Bromide, Tetrabutylammonium Bromide, and a Molecular Sieve. A Synthesis of 3,6-Di-O-(??-D-glucopyranosyl)-D-glucose
Citation Bull. Chem. Soc. Jpn,. 1982. 55, 2995
DOI 10.1246/bcsj.55.2995
PROM-1154
Promoter nBu3P=O-Tf2O-iPr2NEt
Leaving_Group OH
Title Diphosphonium Salts as Effective Reagents for Stereoselective Synthesis of 1,2-cis-Ribofuranosides
Citation Chem Lett. 1990, 1143
DOI 10.1246/cl.1990.1143
PROM-1155
Promoter Ph2Sn=S-Tf2O-CsF
Leaving_Group OH
Title An Efficient Method for the Stereoselective Synthesis of 1,2-cis- and 1,2-trans-Ribofuranosides from 1-Hydroxy Ribofuranose by the Use of Diphenyltin Sulfide and Trifluoromethanesulfonic Anhydride
Citation Chem Lett. 1991, 981
DOI 10.1246/cl.1991.981
PROM-1156
Promoter TMS2O-CaSO4-Sn(OTf)2
Leaving_Group OH
Title An Efficient Glycosylation Reaction of 1-Hydroxy Sugars with Various Nucleophiles Using A Catalytic Amount of Activator and Hexamethyldisiloxane
Citation Synthesis 1994, 1368
DOI 10.1055/s-1994-25695
PROM-1157
Promoter TMS2O-CaSO4-Yb(OTf)3
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1055/s-1994-25695
PROM-1158
Promoter TMS2O-CaSO4-La(OTf)3
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1055/s-1994-25695
PROM-1159
Promoter TMS2O-CaSO4-SnCl2
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1055/s-1994-25695
PROM-116
Promoter TMSOTf
Leaving_Group SEt
Title daburi
Citation daburi
DOI 10.1021/ja907358k
PROM-1160
Promoter TMSCl-Sn(OTf)2-LiClO4
Leaving_Group OH
Title Catalytic Stereoselective Synthesis of ??-D-Galactopyranosides from 2,3,4,6-Tetra-O-benzyl-D-galactopyranose and Several Alcoholic Nucleophiles
Citation Chem Lett. 1997, 403
DOI 10.1246/cl.1997.403
PROM-1161
Promoter TMSBr-Sn(OTf)2-LiClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.403
PROM-1162
Promoter TMSOCOCF3-Sn(OTf)2-LiClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.403
PROM-1163
Promoter TMSOTf-Sn(OTf)2-LiClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.403
PROM-1164
Promoter TMS2O-Sn(OTf)2-LiClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.403
PROM-1165
Promoter (Ph3P)3RhCl/BuLi/TMSOTf
Leaving_Group allyl glycoside
Title Vinyl Glycosides in Oligosaccharide Synthesis. 2. The Use of Allyl and Vinyl Glycosides in Oligosaccharide Synthesis
Citation J. Org. Chem. 1996, 61, 4262
DOI 10.1021/jo960131b
PROM-1166
Promoter (Ph3P)3RhCl-DABCO-TMSOTf
Leaving_Group allyl glycoside
Title Vinyl glycosides in oligosaccharide synthesis (part 1): A new latent-active glycosylation strategy
Citation Tetrahedron Lett. 1994, 35, 3593
DOI 10.1016/S0040-4039(00)73249-7
PROM-1167
Promoter TMSOTf(cat)-Ph2Sn=S-LiClO4
Leaving_Group OTMS
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1041
PROM-1168
Promoter TMSI-n-Bu4NI-(i-Pr)2NEt
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.2004.874
PROM-117
Promoter TMSOTf
Leaving_Group OC(=NPh)CF3, SPh
Title A New Chemical Approach to Human ABO Histo-Blood Group Type 2 Antigens
Citation Molecules 2014, 19, 414
DOI doi.rog/10.3390/molecules19010414
PROM-1171
Promoter Ni(COD)2/Zn, (R)-Ph-pyBox
Leaving_Group Br
Title Sn-Free Ni-Catalyzed Reductive Coupling of Glycosyl Bromides with Activated Alkenes
Citation Org. Lett. 2009, 11, 879
DOI 10.1021/ol8028737
PROM-1172
Promoter [Ru(bpy)3]2+, Visible light, amine reductant
Leaving_Group Br
Title Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light
Citation Angew. Chem., Int. Ed. 2010, 49, 7274
DOI 10.1002/anie.201004311
PROM-1173
Promoter AgClO4-SnCl2-di-tert-butylpyridine
Leaving_Group F, SEt
Title daburi
Citation daburi
DOI 10.1021/ja962048b
PROM-1174
Promoter DAST-Sn(OTf)2-Bu4NClO4-TEA
Leaving_Group OH
Title Dehydrative Glycosylation by Diethylaminosulfur Trifluoride (DAST)_Tin(II) Trifluoromethanesulfonate_Tetrabutylammonium Perchlorate_Triethylamine System
Citation Bull. Chem. Soc. Jpn,. 1998. 71, 2893
DOI 10.1246/bcsj.71.2893
PROM-1175
Promoter NsCl-AgOTf-Et3N-DMA(N,N-dimethylacetamide)
Leaving_Group OH
Title DEHYDRATIVE ??-GLUCOSYLATION USING A MIXTURE OF p-NITROBENZENESULFONYL CHLORIDE, SILVER TRIFLUOROMETHANESULFONATE, N,N-DIMETHYLACETAMIDE, AND TRIETHYLAMINE
Citation Chem. Lett. 1982,?1039
DOI 10.1246/cl.1982.1039
PROM-1176
Promoter NosCl-AgOTf-Et3N-DMA(N,N-dimethylacetamide)
Leaving_Group OH
Title A stereoselective ??-glucosylation by use of a mixture of 4-nitrobenzenesulfonyl chloride, silver tri-fluoromethanesulfonate, N,N-dimethylacetamide, and triethylamine
Citation Carbohydr. Res. 1984, 130, 73
DOI 10.1016/0008-6215(84)85271-4
PROM-1177
Promoter [1,2-benzenediolato(2-)-O,O']oxotitanium-Tf2O-CsF-iPrNEt
Leaving_Group OH
Title Stereoselective Synthesis of 1,2-trans-Ribofuranosides from 1-Hydroxy Sugars by the Use of [1,2-Benzenediolato(2?|)-O,O??]oxotitanium and Trifluoromethanesulfonic Anhydride
Citation Chem Lett. 1991, 431
DOI 10.1246/cl.1991.431
PROM-1178
Promoter [1,2-benzenediolato(2-)-O,O']oxotitanium-Tf2O-Base
Leaving_Group OH
Title An Efficient Method for the Stereoselective Synthesis of ??-D- and ??-D-Ribofuranosides from 2,3,5-Tri-O-benzyl-D-ribofuranose by the Use of [Catecholato(2?|)-O,O??]oxotitanium and Trifluoromethanesulfonic Anhydride
Citation Bull. Chem. Soc. Jpn,. 1993. 66, 1211
DOI 10.1246/bcsj.66.1211
PROM-1179
Promoter (C4H8N)3P=O
Leaving_Group Br
Title Highly ??-Selective Synthesis of Disaccharide Using Glycosyl Bromide by the Promotion of Phosphine Oxide
Citation Chem Lett. 2004, 33, 10
DOI 10.1246/cl.2004.10
PROM-118
Promoter TMSOTf
Leaving_Group ?
Title Nucleoside syntheses, XXII1) Nucleoside synthesis with trimethylsilyl triflate and perchlorate as catalysts
Citation Chem. Ber. 1981, 1234
DOI 10.1002/cber.19811140404
PROM-1180
Promoter (C4H8N)3P=O
Leaving_Group Br, I
Title daburi
Citation daburi
DOI 10.1246/bcsj.78.910
PROM-1183
Promoter BrCCl3, HFIP, blue LED(cat)
Leaving_Group SPMP
Title Visible Light Mediated Activation and O-Glycosylation of Thioglycosides
Citation Org. Lett. 2013, 15, 30
DOI 10.1021/ol302941q
PROM-1184
Promoter DDQ
Leaving_Group 3',4'-dimethoxybenzyl glycoside
Title Utility of 3,4-Dimethoxybenzyl (DMPM) Glycosides. A New Glycosylation Triggered by 2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) Oxidation
Citation Chem. Lett. 1993, 85
DOI 10.1246/cl.1993.85
PROM-1185
Promoter DDQ
Leaving_Group ODMPM
Title A New Glycosylation Triggered by 2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) Oxidation
Citation Chem. Lett. 1999, 22, 85
DOI 10.1246/cl.1993.85
PROM-1186
Promoter NMP(1-methyl-2-pyrrolidinone ),?? 40?|60 ??C
Leaving_Group methyl dinitrosalicylate (DISAL)
Title A New, Efficient Glycosylation Method for Oligosaccharide Synthesis under Neutral Conditions:_ Preparation and Use of New DISAL Donors
Citation J. Org. Chem. 2001, 66, 6268
DOI 10.1021/jo0057654
PROM-1187
Promoter Et3N
Leaving_Group Cl
Title Synthesis of 4-Aminophenyl N-Acetyl-??-D-glucosaminide : Kasai method
Citation Chem. Pharm. Bull. 1995, 43, 266
DOI 10.1248/cpb.43.266
PROM-1188
Promoter Et3N
Leaving_Group thiourea
Title A General Procedure for Conversion of S-Glycosyl Isothiourea Derivatives into Thioglycosides, Thiooligosaccharides and Glycosyl Thioesters
Citation Synthesis 2001, 419
DOI 10.1055/s-2001-11443
PROM-1189
Promoter organolithiums
Leaving_Group Cl
Title Expeditious entry to C-alkyl and C-aryl pyranoid glycals: reaction of anomeric glycosyl chlorides with organolithiums
Citation Chem. Commun. 1996, 2357
DOI 10.1039/CC9960002357
PROM-119
Promoter TMSOTf
Leaving_Group ?
Title Highly stereoselective c-allylation of glycopyranosides with allylsilanes catalyzed by silyl triflate or iodosilane
Citation Tetrahedron Lett. 1984, 25, 2383
DOI 10.1016/S0040-4039(01)80261-6
PROM-1190
Promoter Bu4NHSO4
Leaving_Group Br
Title Synthesis of 4-O-(beta-D-Glucopyranosiduronic Acid)-dopamine
Citation Acta Chem. Scand. 1976, 30b, 871
DOI 10.3891/acta.chem.scand.30b-0871
PROM-1191
Promoter 9-borabicyclo[3.3.1]nonyl trifluoromethanesulfonate (9-BBN_CF3SO3)
Leaving_Group trichloroimidate
Title ??-Selective O-rhamnosylation with a rhamnosyl trichloroacetimidate that has the 4C1 conformation
Citation Carbohydr. Res. 2000, 329, 889
DOI 10.1016/S0008-6215(00)00240-8
PROM-1194
Promoter NHTf2
Leaving_Group -O-P--(OEt)2
Title Direct and Stereoselective Synthesis of 2-Acetamido-2-deoxy-??-D-glycopyranosides by Using the Phosphite Method
Citation Angew. Chem. Int. Ed. 2005, 44, 2245
DOI 10.1002/anie.200461988
PROM-1195
Promoter NHTf2
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1016/j.tetlet.2004.07.128
PROM-1196
Promoter NHTf2
Leaving_Group -O-P--(OEt)2
Title A novel greener glycosidation using an acid_ionic liquid containing a protic acid
Citation Tetrahedron Lett. 2003, 44, 5605
DOI 10.1016/S0040-4039(03)01376-5
PROM-1197
Promoter MSB or MST
Leaving_Group SMe
Title Use of the methylsulfenyl cation as an activator for glycosylation reactions with alkyl (aryl) l-thioglycopyranosides: synthesis of methyl O-(2-acetamido-2-deoxy-??-d-glucopyranosyl)-(1?? 2)-??-d-glucopyranoside, a derivative of the core trisaccharide of E. coli K12
Citation Carbohydr. Res. 1990, 202, 225
DOI 10.1016/0008-6215(90)84082-6
PROM-1198
Promoter BTIB
Leaving_Group SPh, SBu
Title Stabilization of glycosyl sulfonium ions for stereoselective O-glycosylation
Citation Tetrahedron Lett. 1994. 35, 7147
DOI 10.1016/0040-4039(94)85346-0
PROM-1199
Promoter selectfluor(1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate))
Leaving_Group SMe, SPh
Title A New Method for the Synthesis of Fluoro-Carbohydrates and Glycosides Using Selectfluor
Citation J. Am. Chem. Soc. 1997, 119, 11743
DOI 10.1021/ja9723904
PROM-12
Promoter TMSOTf
Leaving_Group -O-C(O)-N(R)(Ts) Glycosyl Sulfonylcarbamates
Title Glycosyl Sulfonylcarbamates:_ New Glycosyl Donors with Tunable Reactivity
Citation J. Am. Chem. Soc. 2001, 123, 3379
DOI 10.1021/ja005735i
PROM-120
Promoter TMSOTf
Leaving_Group Cl, OP(OEt2), Br, SEt
Title daburi
Citation daburi
DOI 10.1021/ja9740327
PROM-1200
Promoter N-(phenylthio)-??-caprolactam
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/ja062531e
PROM-1201
Promoter TBPA
Leaving_Group SEt, SPh
Title Glycosylation Using a One-Electron-Transfer Homogeneous Reagent: A Novel and Efficient Synthesis of _-Linked Disaccharides
Citation Synlett. 1990, 572
DOI 10.1055/s-1990-22045
PROM-1202
Promoter CCl3CHO
Leaving_Group trichloroimidate
Title New catalysts for the glycosyl transfer with O-glycosyl trichloroacetimidates
Citation Tetrahedron Lett. 1990, 31, 327
DOI 10.1016/S0040-4039(00)94546-5
PROM-1203
Promoter 2-fluoro-l-methylpyridinium tosylate
Leaving_Group OH
Title STEREOSELECTIVE SYNTHESIS OF ??-RIBONUCLEOSIDES FROM 1-HYDROXY SUGARS BY USING 2-FLUOROPYRIDINIUM TOSYLATE
Citation Chem. Lett., 1984, 557
DOI 10.1246/cl.1984.557
PROM-1204
Promoter DMF
Leaving_Group -O-CH(=NMe2)+
Title Dimethylformamide: An Unusual Glycosylation Modulator
Citation Angew. Chem., Int. Ed. 2011, 50, 7315
DOI 10.1002/anie.201100076
PROM-1205
Promoter DMF
Leaving_Group -O-CH(=NMe2)+
Title In situ formation of ??-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed_armed iterative glycosylation
Citation Chem. Commun. 2012, 48, 10910
DOI 10.1039/C2CC35032G
PROM-1206
Promoter (Ph)2SO
Leaving_Group -O-P(=O)-(OR)2
Title Synthesis of Glycosyl-1-phosphates via Dehydrative Glycosylation
Citation Org. Lett. 2000, 2, 2135
DOI 10.1021/ol006041h
PROM-1207
Promoter 1,3-dithian-2-ylium tetrafluoroborate
Leaving_Group 4-pentenyl Glycoside
Title daburi
Citation daburi
DOI 10.1055/s-1990-21193
PROM-1208
Promoter NISac(N-Iodosaccharin)
Leaving_Group SMe, SPh
Title N-Iodosaccharin: A Potent New Activator of Thiophenylglycosides
Citation Synlett. 2001, 797
DOI 10.1055/s-2001-14612
PROM-1209
Promoter Ph-S-O-SO2CF3(benzene sulphenyl triflate; BST)
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4020(98)00426-8
PROM-121
Promoter TMSOTf
Leaving_Group trichloroacetimidates, thioglycosides
Title Synthesis of a group of diosgenyl saponins by a one-pot sequential glycosylation
Citation Tetrahedron Lett. 1999, 40, 8591
DOI 10.1016/S0040-4039(99)01839-0
PROM-1210
Promoter Bu4NOTf
Leaving_Group STol
Title Electrochemical Generation of Glycosyl Triflate Pools
Citation J. Am. Chem. Soc. 2007, 129, 10922
DOI 10.1021/ja072440x
PROM-1211
Promoter HF-pyridine
Leaving_Group OAc
Title SIMPLE SYNTHESIS OF GLYCOSYL FLUORIDES?
Citation Chem. Lett. 1984, 13, 1747
DOI 10.1246/cl.1984.1747
PROM-1212
Promoter Me3SiClO4
Leaving_Group N-trichloroacetylcarbamate
Title Catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate
Citation Tetrahedron Lett. 2006, 47, 267
DOI 10.1016/j.tetlet.2005.11.027
PROM-1213
Promoter Me3SiOTf
Leaving_Group N-trichloroacetylcarbamate
Title daburi
Citation daburi
DOI 10.1016/j.tetlet.2005.11.027
PROM-1216
Promoter imidazole(DMAP)??Bu3SnH, reflux??HF(nBu4NF)
Leaving_Group SePh
Title Synthesis of oligosaccharide mimetics
Citation Pure & Appl. Chem. 1997, 69, 459
DOI 10.1351/pac199769030459
PROM-1217
Promoter AgOTf-lutidine; TMSOTf
Leaving_Group Br
Title A highly stereocontrolled synthesis of 1??,1??-linked acetylated oligosaccharides via orthoester formation-rearrangement
Citation Tetrahedron Lett. 1999, 40, 1361
DOI 10.1016/S0040-4039(98)02626-4
PROM-1218
Promoter AgOTf; NIS-TfOH
Leaving_Group glycosyl bromides and phenylthio glycoside
Title One-pot sequential glycosylation:A new method for the synthesis of branched oligosaccharides
Citation Tetrahedron Lett. 1999, 40, 4581
DOI 10.1016/S0040-4039(99)00796-0
PROM-1219
Promoter AgOTf-lutidine; TMSOTf
Leaving_Group Br
Title Highly Regio- and Stereoselective Synthesis of Bioactive Oligosaccharides Using 1,2-O-Ethylidene-??-d-gluco- and -??-d-Mannopyranose as the Acceptors and Acetobromosugars as the Donors via Ortho Ester Intermediates
Citation J. Org. Chem. 1999, 64, 5091
DOI 10.1021/jo982508e
PROM-122
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1021/ja801669r
PROM-1220
Promoter TBPA+?E(radical)
Leaving_Group SEt, SPh
Title daburi
Citation daburi
DOI 10.1351/pac199163040519
PROM-1221
Promoter h??, TPT(triphenyltin?)
Leaving_Group SePh
Title Activation of selenoglycosides by photoinduced electron transfer
Citation Chem.Commun. 1996, 157
DOI 10.1039/CC9960000157
PROM-1223
Promoter h??
Leaving_Group diazide
Title Synthesis of C-1 spirocyclopropyl sugars from anomeric diazides
Citation Tetrahedron Lett. 1990, 31, 4441
DOI 10.1016/S0040-4039(00)97642-1
PROM-1224
Promoter Bu3SnAll, h??
Leaving_Group Cl
Title A stereocontrolled radical access to C-allyl ??-D-glycopyranosides from glycopyranosylidene dihalides found en route to C-glycodienes
Citation Tetrahedron Lett. 1997, 38, 8185
DOI 10.1016/S0040-4039(97)10215-5
PROM-1225
Promoter Bu3SnAll, h??
Leaving_Group ?
Title Synthesis of ??-C-Glycosides of N-Acetylglucosamine via Keck Allylation Directed by Neighboring Phthalimide Groups
Citation J. Org. Chem. 1996, 61, 6442
DOI 10.1021/jo960819o
PROM-1226
Promoter DDQ,??long-wavelength UV, (p-OMe)PhB(OH)2
Leaving_Group SPh
Title Light-induced O-glycosylation of unprotected deoxythioglycosyl donors
Citation Org. Biomol. Chem. 2013, 11, 5079
DOI 10.1039/C3OB41143E
PROM-1227
Promoter IPy2BF4
Leaving_Group SR (R = ?)
Title IPy2BF4-Mediated Glycosylation and Glycosyl Fluoride Formation
Citation Eur. J. Org. Chem. 2007, 1887
DOI 10.1002/ejoc.200700038
PROM-1228
Promoter (Ph3P+)2O-2TfO-
Leaving_Group diphosphonium salt
Title Dehydrative Glycosylation with the Hendrickson Reagent
Citation J. Org. Chem. 2011, 76, 9122.
DOI 10.1021/jo2015856
PROM-1229
Promoter Li naphthalenide
Leaving_Group SO2Ph
Title Synthesis of 2-deoxy-??-C-pyranosides by diastereoselective hydrogen atom transfer
Citation Tetrahedron 1990. 31, 1897
DOI 10.1016/S0040-4039(00)98814-2
PROM-123
Promoter TMSOTf
Leaving_Group ?
Title Total Synthesis of Woodrosin I?%5CPart 2: Final Stages Involving RCM and an Orthoester Rearrangement
Citation Chem. Eur. J. 2003, 9, 320
DOI 10.1002/chem.200390026
PROM-1231
Promoter Ph3C+ClO4-
Leaving_Group ?
Title A new stereospecific method for 1,2-cis-glycosylation
Citation Carbohydr. Res. 1991, 212, 77
DOI 10.1016/0008-6215(91)84047-I
PROM-1232
Promoter Iodonium-ion
Leaving_Group SEt
Title Stereoselective 1,2-cis-galactosylation assisted by remote neighboring group participation and solvent effects
Citation Tetrahedron Lett. 1999, 40, 6523
DOI 10.1016/S0040-4039(99)01203-4
PROM-1233
Promoter Iodonium-ion
Leaving_Group SEt
Title Iodonium ion-assisted glycosylation of alkyl (aryl) 1-thio-glycosides: regulation of stereoselectivity and reactivity
Citation Carbohydr. Res. 1991, 215, C1
DOI 10.1016/0008-6215(91)84036-E
PROM-1234
Promoter Iodonium-ion
Leaving_Group SEt
Title Synthesis of Carbohydrate-Antigenic Structures of Mycobacterium Tuberculosis using an Iodonium Ion Promoted Glycosidation Approach
Citation J. Carbohydr. Chem. 1990, 9, 783
DOI 10.1080/07328309008543874
PROM-1235
Promoter Iodonium-ion
Leaving_Group SEt
Title Iodonium ion-assisted glycosylation of alkyl (aryl) 1-thio-glycosides: regulation of stereoselectivity and reactivity
Citation Carbohydr. Res. 1991, 215, C1
DOI 10.1016/0008-6215(91)84036-E
PROM-1236
Promoter Iodonium-ion
Leaving_Group SEt
Title Iodonium-Ion Assisted Stereospecific Glycosylation: Synthesis of Oligosaccharides Containing ??(1-4)-Linked L-Fucopyranosyl Units
Citation Carbohydr. Chem. 1991, 10, 833
DOI 10.1080/07328309108543953
PROM-1237
Promoter Iodonium-ion
Leaving_Group 4-pentenyl glycoside
Title A New Activating Principle in Glycoside Synthesis Based on Electrophile-Induced?Lactonization of Glucosyl 4-Pentenoates
Citation Synlett. 1990, 631
DOI 10.1055/s-1990-21193
PROM-1239
Promoter [bmim][OTf] (ionic liquid promoter)
Leaving_Group trichloroimidate
Title [bmim][OTf]: a versatile room temperature glycosylation promoter
Citation Tetrahedron Lett. 2009, 50, 442
DOI 10.1016/j.tetlet.2008.11.042
PROM-124
Promoter TMSOTf
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1021/ja036521e
PROM-1240
Promoter [R4N] [AOT]? (ionic liquid promoter), NIS
Leaving_Group SPh
Title [R4N] [AOT]: A Surfactant Ionic Liquid as a Mild Glycosylation Promoter
Citation J. Carbohydr. Chem. 2011, 30, 486
DOI 10.1080/07328303.2011.609626
PROM-1241
Promoter e
Leaving_Group SePh
Title Selective electrochemical glycosylation by reactivity tuning
Citation Org. Biomol. Chem. 2004, 2, 2195
DOI 10.1039/B316728C
PROM-1242
Promoter e
Leaving_Group SPh
Title Generation of Alkoxycarbenium Ion Pools from Thioacetals and Applications to Glycosylation Chemistry
Citation Org. Lett. 2004, 6, 3755
DOI 10.1002/anie.200802036
PROM-1243
Promoter e
Leaving_Group SAr
Title Electrooxidative Glycosylation through C?|S Bond Cleavage of 1-Arylthio-2,3-dideoxyglycosides. Synthesis of 2?e,3?e-Dideoxynucleosides
Citation Tetrahedron Lett. 2005, 46, 5923
DOI 10.1021/ol051776d
PROM-1247
Promoter Eox = 0.90V, Ag/AgCl, electrolyte: LiClO4 or Bu4NBF4
Leaving_Group Telluruoglycoside
Title O-Glycosidation of Telluroglycoside by Electrochemical Oxidation
Citation Chem Lett. 1997, 111
DOI 10.1246/cl.1997.111
PROM-1248
Promoter electrolyte, catalytic amount of NaOTf
Leaving_Group SR (R = ?)
Title Electrochemical O-glycosylation using thioglycosides as glycosyl donors in the presence of a catalytic amount of sodium trifluoromethanesulfonate as a supporting electrolyte
Citation Tetrahedron Lett. 2007, 48, 7383
DOI 10.1016/j.tetlet.2007.08.004
PROM-1256
Promoter ??
Leaving_Group -S-C(O)-OPh
Title Synthetic studies by the use of carbonates.? IV.? New method for the synthesis of glycosyl compounds by the use of 1-O-aryloxycarbonyl sugar derivatives
Citation J. Am. Chem. Soc. 1973, 95, 2062
DOI 10.1021/ja00787a084
PROM-1257
Promoter 40?|60 ??C
Leaving_Group methyl dinitrosalicylate (DISAL)
Title Intramolecular Glycosylation under Neutral Conditions for Synthesis of 1,4-Linked Disaccharides
Citation Org. Lett. 2001, 3, 687
DOI 10.1021/ol006988j
PROM-1259
Promoter LiClO4, microwave, 100degree
Leaving_Group methyl dinitrosalicylate (DISAL)
Title Reconsidering glycosylations at high temperature: precise microwave heating
Citation Org. Biomol. Chem. 2005, 3, 3966
DOI 10.1039/B511266D
PROM-1260
Promoter catalyst: Et3N+BnBr- acceptor: ROH (R=aryl)
Leaving_Group Glycosyl bomide or Chloride
Title Phase-transfer-catalyzed synthesis of 2,3,4,6-tetra-O-acetyl-??-d-galactopyranosides
Citation Carbohydr. Res. 1985, 142, 333
DOI 10.1016/0008-6215(85)85036-9
PROM-1261
Promoter catalyst: Et3N+BnCl- acceptor: ROH (R=aryl)
Leaving_Group Glycosyl bomide or Chloride
Title Synthesis of aryl ??-D-glucopyranosides and aryl ??-D-glucopyranosiduronic acids
Citation Tetrahedron Lett. 1979. 20, 5051
DOI 10.1016/S0040-4039(01)86787-3
PROM-1262
Promoter catalyst: Me(CH2)15N+Me3Br- acceptor: ROH (R=aryl)
Leaving_Group Glycosyl bomide or Chloride
Title Phase-transfer-catalyzed d-glucosylation: Synthesis of benzoylated aryl ??-d-glucopyranosides and ??-d-glucopyranosyl-substituted cinnamates
Citation Carbohydr. Res. 1987, 162, 117
DOI 10.1016/0008-6215(87)80206-9
PROM-1263
Promoter catalyst: Bu4N+Br- acceptor: ROH (R=aryl)
Leaving_Group Cl
Title Stereospecific Synthesis of Aryl ??-D-N-Acetylglucopyranosides by Phase Transfer Catalysis
Citation Synth. Commun. 1990, 20, 2097
DOI 10.1080/00397919008053144
PROM-1264
Promoter catalyst: Bu4N+HSO4- acceptor: ROH (R=aryl)
Leaving_Group Br
Title Syntheses of glycosyl phosphates by phase transfer catalysis
Citation Can. J. Chem. 1991, 69, 1462
DOI 10.1139/v91-216
PROM-1265
Promoter catalyst: Aliquat336 acceptor: ROH (R=alkyl)
Leaving_Group Br
Title Glycosylation of acids under phase transfer conditions. Partial synthesis of saponins
Citation Tetrahedron Lett. 1994. 35, 6107
DOI 10.1016/0040-4039(94)88088-3
PROM-1266
Promoter catalyst: BuN+Bu3Cl- acceptor: ROH (R=aryl)
Leaving_Group Glycosyl bomide or Chloride
Title Solid-Liquid Phase Transfer Catalyzed Novel Glycosylation Reaction of Phenols
Citation Synth. Commun. 1999, 29, 2775
DOI 10.1080/00397919908086444
PROM-1267
Promoter Bu4N+Br-
Leaving_Group Glycosyl bomide or Chloride
Title Halide ion catalyzed glycosidation reactions. Syntheses of .alpha.-linked disaccharides
Citation J. Am. Chem. Soc. 1975, 97, 4056
DOI 10.1021/ja00847a032
PROM-1268
Promoter ?
Leaving_Group Br
Title Stereospecific Synthesis of 1,2-trans-1-Phenylthio-??-D-Disaccharides Under Phase Transfer Catalysis
Citation Synthesis 1991, 734
DOI 10.1055/s-1991-26559
PROM-1269
Promoter BTEAB
Leaving_Group Br
Title Phase-Transfer Catalyzed Synthesis of Acetylated Aryl _-D-Glucopyranosides and Aryl _-D-Galactopyranosides
Citation Synthesis. 1981, 883
DOI 10.1055/s-1981-29631
PROM-1270
Promoter TsCl/Bu4N+Cl-
Leaving_Group OH
Title Synthesis of S-Glycosyl N,N-Diethyldithiocarbamates from Protected, Reducing Monosaccharides Under Phase-Transfer Conditions
Citation Synthesis 1988, 224
DOI 10.1055/s-1988-27520
PROM-1271
Promoter TsCl-TEBA
Leaving_Group OH
Title Convenient Synthesis of ??-D-Glucopyranosides
Citation Synthesis 1988, 223
DOI 10.1055/s-1988-27519
PROM-1276
Promoter Cellulase
Leaving_Group ?
Title Cellulase-catalysed glycosylation reactions: simple route towards a highly selective synthesis of oligosaccharides
Citation J. Chem. Soc. Perkin Trans. 1 1994, 1851
DOI 10.1039/P19940001851
PROM-1277
Promoter Cellulase,? ??-galactosidase
Leaving_Group ?
Title A Novel Method for Synthesis of Cellooligosaccharide Derivatives by Using Enzyme Catalyst
Citation Chem. Lett. 1993, 685
DOI 10.1246/cl.1993.685
PROM-1278
Promoter Cellulase
Leaving_Group ?
Title Cellulase-catalysed, stereoselective synthesis of oligosaccharides
Citation J. Chem. Soc. Chem. Commun. 1993, 1402
DOI 10.1039/C39930001402
PROM-1279
Promoter Cellulase
Leaving_Group ?
Title Novel method for polysaccharide synthesis using an enzyme: the first in vitro synthesis of cellulose via a nonbiosynthetic path utilizing cellulase as catalyst
Citation J. Am. Chem. Soc. 1991, 113, 3079
DOI 10.1021/ja00008a042
PROM-128
Promoter TMSOTf
Leaving_Group SPh
Title Total Synthesis of Vineomycin B2
Citation J. Am. Chem. Soc. 2013, 135, 15909
DOI 10.1021/ja407827n
PROM-1280
Promoter Lipase
Leaving_Group ?
Title Lipase-Assisted Synthesis of ??-Gal-(1??3)-GalNAc
Citation Synlett. 1996, 966
DOI 10.1055/s-1996-5650
PROM-1281
Promoter Glycosidase
Leaving_Group ?
Title Glycosidases?%5Ca great synthetic tool
Citation J. Mol. Catal. B: Enzym. 1999, 6, 483
DOI 10.1016/S1381-1177(99)00012-0
PROM-1282
Promoter Glycosidase
Leaving_Group ?
Title Glycosidase-catalysed synthesis of di- and trisaccharide derivatives related to antigens involved in the hyperacure rejection of xenotransplants
Citation Tetrahedron Lett. 1997, 38, 133
DOI 10.1016/S0040-4039(96)02235-6
PROM-1283
Promoter Glycosidase
Leaving_Group ?
Title The first synthesis of neu5Ac??2-3Gal??1-4GlcNAc??1-2Man??1-ser ?%5C a newly discovered component of ??-dystroglycan
Citation Tetrahedron Lett. 1999, 40, 5046
DOI 10.1016/S0040-4039(99)00930-2
PROM-1284
Promoter Glycosidase
Leaving_Group ?
Title Enzymatic glycosidation in dry media under microwaveirradiation
Citation J. Chem. Soc., Perkin Trans. 1 1997, 1001
DOI 10.1039/A700144D
PROM-1285
Promoter glycosidase
Leaving_Group ?
Title A Multienzyme System for a One-Pot Synthesis of Sialyl T-Antigen
Citation Angew. Chem. Int. Ed. Engl. 1995, 34, 893
DOI 10.1002/anie.199508931
PROM-1286
Promoter ??-glycosidase from Thermus thermophilus
Leaving_Group ?
Title Transferase Activity of a ??-Glycosidase from Thermus thermophilus: Specificities and Limits _ Application to the Synthesis of ??-[13]-Disaccharides
Citation Eur. J. Org. Chem. 1999, 757
DOI 10.1002/(SICI)1099-0690(199904)1999:4<757::AID-EJOC757>3.0.CO;2-3
PROM-1287
Promoter ??-glycosidase from Aspergillus oryzae
Leaving_Group ?
Title ??-Galactosidase transferase activity in ice and use of vinyl-??-d-galactoside as donor
Citation Tetrahedron: Asymmetry. 1997, 8, 2017
DOI 10.1016/S0957-4166(97)00194-8
PROM-1288
Promoter ??-d-mannanase from Aspergillus niger
Leaving_Group ?
Title Enzymic synthesis of the trisaccharide core region of the carbohydrate chain of N-glycoprotein
Citation Glycoconjugate. J. 1994,?11, ?105
DOI 10.1007/BF00731150
PROM-1289
Promoter Glycosynthase
Leaving_Group F
Title Glycosynthases:_ Mutant Glycosidases for Oligosaccharide Synthesis
Citation J. Am. Chem. Soc. 1998, 120, 5583
DOI 10.1021/ja980833d
PROM-129
Promoter TMSOTf
Leaving_Group -OC(=NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja980588y
PROM-1290
Promoter ??-galactosidase from Bacillus circulans
Leaving_Group OpNP (p-nitrophenyl)
Title Chemoenzymatic synthesis of ethyl 1-thio-(??-D-galactopyranosyl)-O-??-D-glycopyranosyl disaccharides using the ??-galactosidase from Bacillus circulans
Citation Tetrahedron: Asymmetry. 1996, 7, 709.
DOI 10.1016/0957-4166(96)00066-3
PROM-1291
Promoter ??-galactosidase from Bacillus circulans
Leaving_Group ?
Title Enzymatic Synthesis of Galactose-Containing Disaccharides Employing ??-Galactosidase from Bacillus circulans
Citation Eur. J. Org. Chem. 1999, 3073
DOI 10.1002/(SICI)1099-0690(199911)1999:11<3073::AID-EJOC3073>3.0.CO;2-5
PROM-1292
Promoter ??-galactosidase from Bacillus circulans
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1039/P19960001921
PROM-1293
Promoter ??-galactosidase from Bacillus circulans
Leaving_Group o-nitrophenyl
Title ??-Galactosidase catalysed transglycosylation in aqueous organic media using glycosylasparagine mimics as novel acceptors
Citation Tetrahedron. 1999, 55, 1119
DOI 10.1016/S0040-4020(98)01090-4
PROM-1294
Promoter ??-galactosidase from Bacillus circulans
Leaving_Group ?
Title Glycosidase-catalysed synthesis of oligosaccharides: a one stepsynthesis of lactosamine and of the linear B type 2 trisaccharide??-d-Gal-(1??3)-??-d-Gal-(1??4)-??-d-GlcNAcSEtinvolved in the hyperacute rejection response in xenotransplantation frompigs to man and as the specific receptor for toxin A from Clostridiumdifficile
Citation Chem. Commun. 1997, 169
DOI 10.1039/A607255K
PROM-1295
Promoter ??-galactosidase from bovine testes
Leaving_Group ?
Title Chemoenzymatic synthesis of the Thomsen-Friedenreich antigen determinant
Citation Carbohydr. Res. 1997, 299, 85
DOI 10.1016/S0008-6215(96)00324-2
PROM-1296
Promoter ??-Galactosidase from Aspergillus oryzae
Leaving_Group ?
Title Glycosidase-catalysed synthesis of glycosides by an improved procedure for reverse hydrolysis: application to the chemoenzymatic synthesis of galactopyranosyl-(1??4)-O-??-galactopyranoside derivatives
Citation Tetrahedron: Asymmetry. 1996, 7, 1973
DOI 10.1016/0957-4166(96)00238-8
PROM-1297
Promoter ??-galactosidase
Leaving_Group 3-nitro-2-pyridyl and 5-nitro-2-pyridyl glycosides
Title
Citation Tetrahedron Lett. 1999, 40, 6585
DOI 10.1016/S0040-4039(99)01279-4
PROM-1298
Promoter ??-d-galactosidase
Leaving_Group ?
Title Transglycosylation catalyzed by a lipid-coated ??-d-galactosidase in a two-phase aqueous_organic system
Citation J. Mol. Catal. B: Enzym. 1998, 5, 119
DOI 10.1016/S1381-1177(98)00088-5
PROM-1299
Promoter ??-Galactosidase
Leaving_Group ?
Title Chemical and Enzymatic Synthesis of Glycoconjugates 2. High Yielding Regioselective Synthesis of N-Acetyllactosamine by Use of Recombinant Thermophilic Glycosidases Library
Citation Tetrahedron Lett. 1997, 38, 7967
DOI 10.1016/S0040-4039(97)10141-1
PROM-13
Promoter TMSOTf
Leaving_Group N-trichloroacetylcarbamate
Title Improved catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate: application to various 1-hydroxy sugars
Citation Carbohydr. Res. 2010, 345, 740
DOI 10.1016/j.carres.2010.01.011
PROM-130
Promoter DBBOTf??
Leaving_Group trichloroacetimidate
Title Polymer-supported syntheses of oligosaccharides: Using dibutylboron triflate to promote glycosylations with glycosyl trichloroacetimidates
Citation Tetrahedron Lett. 1996, 37, 6985
DOI 10.1016/0040-4039(96)01570-5
PROM-1300
Promoter ??-Galactosidase
Leaving_Group ?
Title Multienzyme System for Synthesis of the Sialylated Thomsen_Friedenreich Antigen Determinant
Citation Eur. J. Org. Chem. 1999, 107
DOI 10.1002/(SICI)1099-0690(199901)1999:1<107::AID-EJOC107>3.0.CO;2-M
PROM-1301
Promoter ??-galactosidase from Aspergillus niger
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/0957-4166(96)00238-8
PROM-1302
Promoter ??-glucosidase from almond
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/0957-4166(96)00238-8
PROM-1303
Promoter ??-galactosidase from Penicillium multicolor
Leaving_Group ?
Title Glycosidase-catalysed synthesis of ??-galactosyl epitopes important in xenotransplantation and toxin binding using the ??-galactosidase from Penicillium multicolor
Citation daburi
DOI 10.1039/A906020K
PROM-1304
Promoter ??-galactosidase from Aspergillus oryzae
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1039/A607255K
PROM-1305
Promoter ??-Galactosidases from Coffea arabica, Aspergillus niger and A. oryzae
Leaving_Group ?
Title Glycosidase-catalysed synthesis of oligosaccharides: trisaccharides with the ??-D-gal-(1 ?? 3)-D-gal terminus responsible for the hyperacute rejection response in cross-species transplant rejection from pigs to man
Citation Chem. Commun. 1996, 1473
DOI 10.1039/CC9960001473
PROM-1306
Promoter ??-galactosidase from Talaromyces flavus
Leaving_Group ?
Title Enzymatic synthesis of iso-globotriose from partially protected lactose
Citation Tetrahedron Lett. 1999, 40, 9297
DOI 10.1016/S0040-4039(99)01950-4
PROM-1307
Promoter thermophilic galactosidase
Leaving_Group OH
Title Chemical and enzymatic synthesis of glycoconjugates 3: Synthesis of lactosamine by thermophilic galactosidase catalyzed galactosylation on a multigram scale
Citation Tetrahedron Lett. 1998, 39, 919
DOI 10.1016/S0040-4039(97)10676-1
PROM-1308
Promoter lipid-coated ??-D-galactosidase
Leaving_Group ?
Title Effective biocatalytic transgalactosylation in a supercritical fluid using a lipid-coated enzyme
Citation Chem. Commun. 1998, 2215
DOI 10.1039/A806168H
PROM-1309
Promoter N-acetylhexosaminidase from Aspergillus oryzae
Leaving_Group ?
Title Glycosidase-catalysed oligosaccharide synthesis of di-, tri- and tetra-saccharides using the N-acetylhexosaminidase from Aspergillus oryzae and the ??-galactosidase from Bacillus circulans
Citation J. Chem. Soc., Perkin Trans. 1 1996, 1921
DOI 10.1039/P19960001921
PROM-131
Promoter MeOTf
Leaving_Group SEt
Title Glycosylation Using a Thioglycoside and Methyl Trifluoro-Methanesulfonate. A New and Efficient Method for CIS and Trans Glycoside Formation
Citation J. Carbohydr. Chem. 1987, 6, 301
DOI 10.1080/07328308708058879
PROM-1310
Promoter ??-N-Acetylhexosaminidase from Aspergillus oryzae
Leaving_Group p-nitrophenyl
Title Unusual nonreducing sugar GlcNAc??(1_1)Man?? formation by ??-N-acetylhexosaminidase from Aspergillus oryzae
Citation Tetrahedron Lett. 1998, 39, 9777
DOI 10.1016/S0040-4039(98)02171-6
PROM-1311
Promoter ??-N-acetylhexosaminidase
Leaving_Group ?
Title Glycosidase-catalysed synthesis of oligosaccharides: a two-step synthesis of the core trisaccharide of N-linked glycoproteins using the ??-N-acetylhexosaminidase and the ??-mannosidase from Aspergillus oryzae
Citation Chem. Commun. 1996, 993
DOI 10.1039/CC9960000993
PROM-1312
Promoter N-acetyl-??-hexosaminidase
Leaving_Group 3-nitro-2-pyridyl and 5-nitro-2-pyridyl glycosides
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(99)01279-4
PROM-1313
Promoter sialyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(99)00930-2
PROM-1314
Promoter ??2_3-Sialyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/(SICI)1099-0690(199901)1999:1<107::AID-EJOC107>3.0.CO;2-M
PROM-1315
Promoter sialyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/jo980074h
PROM-1316
Promoter (2??3)-??-sialyltransferase
Leaving_Group ?
Title Enzymic synthesis of oligosaccharides terminating in the tumor-associated sialyl-Lewis-a determinant
Citation Carbohydr. Res. 1989, 190, 1
DOI 10.1016/0008-6215(89)84141-2
PROM-1317
Promoter ??2-3-sialyltransferase (ST3Gal-I)
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/ja015570t
PROM-1318
Promoter ??2-6-sialyltransferase (ST6GalNAc-I)
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/ja015570t
PROM-1319
Promoter uridine-5?e-diphospho-galactose 4-epimerase
Leaving_Group ?
Title A Unique Chemoenzymatic Synthesis of ??-Galactosyl Epitope Derivatives Containing Free Amino Groups:_ Efficient Separation and Further Manipulation
Citation J. Org. Chem. 1999, 64, 4089
DOI 10.1021/jo990159y
PROM-132
Promoter MeOTf
Leaving_Group SPh
Title Stereoselective Synthesis of 2-S-Phenyl-2-deoxy-??-glycosides Using Phenyl 2,3-O-Thionocarbonyl-1-thioglycoside Donors via 1,2-Migration and Concurrent Glycosidation
Citation Org. Lett. 2001, 3, 377
DOI 10.1021/ol006894+
PROM-1320
Promoter ??(1??3) galactosyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/jo990159y
PROM-1321
Promoter ??-mannosidase from Aspergillus oryzae
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1039/CC9960000993
PROM-1322
Promoter ??-mannosidase from Helix pomatia
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/0957-4166(96)00238-8
PROM-1323
Promoter ??-glucosidase
Leaving_Group 3-nitro-2-pyridyl and 5-nitro-2-pyridyl glycosides
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(99)01279-4
PROM-1324
Promoter glycosyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/anie.199508931
PROM-1325
Promoter galactosyltransferase
Leaving_Group ?
Title Solid-Phase Enzymatic Synthesis of a Sialyl Lewis X Tetrasaccharide on a Sepharose Matrix
Citation J. Org. Chem. 1998, 63, 2705
DOI 10.1021/jo980074h
PROM-1326
Promoter ??-1,4-galactosyl transferase from bovine colostrum
Leaving_Group ?
Title Stereoselective enzymatic galactosylation of C-glucosides
Citation J. Chem. Soc., Perkin Trans. 1 1997, 1255
DOI 10.1039/A701747B
PROM-1327
Promoter ??-Mannosyltransferase
Leaving_Group ?
Title Efficient Enzymatic Synthesis of the Core Trisaccharide of N-Glycans with a Recombinant ??-Mannosyltransferase
Citation Angew. Chem., Int. Ed. Engl. 1997, 36, 2354
DOI 10.1002/anie.199723541
PROM-1328
Promoter ??-(1??4)-mannosyltransferase
Leaving_Group ?
Title Chemoenzymatic synthesis of the Salmonella group E1 core trisaccharide using a recombinant ??-(1??4)-mannosyltransferase
Citation Carbohydr. Res. 1999, 319, 184
DOI 10.1016/S0008-6215(99)00116-0
PROM-1329
Promoter fucosyltransferase
Leaving_Group ?
Title Enzymatic synthesis of sialyl Lex and derivatives based on a recombinant fucosyltransferase
Citation Bioorg. Med. Chem. Lett. 1991, 1, 425
DOI 10.1016/S0960-894X(00)80270-X
PROM-133
Promoter MeOTf
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1055/s-1993-22367
PROM-1330
Promoter fucosyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/jo980074h
PROM-1331
Promoter N-acetylglucosaminyltransferase
Leaving_Group ?
Title Use of the ?gcore-2?h-N-acetylglucosaminyltransferase in the chemical-enzymatic synthesis of a sialyl-Lex-containing hexasaccharide found on O-linked glycoproteins
Citation Carbohydr. Res. 1993, 244, 149
DOI 10.1016/0008-6215(93)80011-3
PROM-1332
Promoter human-milk (1??34)-??-fucosyltransferase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/0008-6215(89)84141-2
PROM-1333
Promoter sucrose synthase and UDP-Glc 4??-epimerase and ??-1,4-galactosyltransferase
Leaving_Group UDP
Title A Novel Three-Enzyme Reaction Cycle for the Synthesis of N-Acetyllactosamine with in Situ Regeneration of Uridine 5?e-Diphosphate Glucose and Uridine 5?e-Diphosphate Galactose
Citation J. Am. Chem. Soc. 1996, 118, 1836
DOI 10.1021/ja953495e
PROM-1336
Promoter calf intestinal phosphatase
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1021/ja015570t
PROM-1337
Promoter H4SiW12O40
Leaving_Group 1-Hydoroxy Sugar
Title Novel Dehydrative Glycosidations of 1-Hydroxy Sugars Using a Heteropoly Acid
Citation Synlett. 1999, 1420
DOI 10.1055/s-1999-2869
PROM-1338
Promoter H4SiW12O40
Leaving_Group trichloroimidate
Title Simple formylacetal (CH2) as a novel linker for saccharide synthesis on soluble-polymer support
Citation Tetrahedron Lett. 2004, 45, 787
DOI 10.1016/j.tetlet.2003.11.036
PROM-1339
Promoter H3PW12O40
Leaving_Group PhS(O)-
Title A novel promoter, heteropoly acid, mediated chemo- and stereoselective sulfoxide glycosidation reactions
Citation Tetrahedron Lett. 2000, 41, 10233
DOI 10.1016/S0040-4039(00)01821-9
PROM-134
Promoter MeOTf
Leaving_Group -S-C(S)-OEt
Title ??-selectivity and glycal formation are temperature dependent in glycosylation with sialic acid. Synthesis of a Neu5Ac??(2-6)Gal thioglycoside building block
Citation Tetrahedron Lett. 1991, 32, 7453
DOI 10.1016/0040-4039(91)80132-P
PROM-1340
Promoter EDCl?EHCl-HOBt (TBTU)
Leaving_Group ?
Title Synthesis and Conformational Analysis of Linear and Cyclic Peptides Containing Sugar Amino Acids
Citation J. Am. Chem. Soc. 1996, 118, 10156
DOI 10.1021/ja961068a
PROM-1341
Promoter ArS(ArSSAr)+B(C6F5)4-
Leaving_Group STol
Title Electrochemically Generated ArS(ArSSAr)+B(C6F5)4- as an Activator of Thioglycosides for Glycosylation
Citation Chem. Lett. 2011, 40, 678
DOI 10.1246/cl.2011.678
PROM-1342
Promoter Volt (+1.5), n-Bu4NClO4
Leaving_Group SPMP
Title Protecting Group and Solvent Effects in Electrochemical Glycosylation
Citation Synlett 2007, 2711
DOI 10.1055/s-2007-986644
PROM-1343
Promoter insoluble silver salts
Leaving_Group Br
Title Substituent effects on carbohydrate coupling reactions promoted by insoluble silver salts
Citation Tetrahedron, 1984, 40, 4097
DOI 10.1016/0040-4020(84)85091-7
PROM-1344
Promoter Montomorillonite K-10
Leaving_Group -O-P-(OEt)2
Title Environmentally Benign and Stereoselective Construction of 2-Deoxy and 2,6-Dideoxy-??-glycosidic Linkages Employing 2-Deoxy and 2,6-Dideoxyglycosyl Phosphites and Montmorillonite K-10
Citation Chem. Lett. 2002, 31, 1100
DOI 10.1246/cl.2002.1100
PROM-1345
Promoter Montomorillonite K-10
Leaving_Group -O-P-(OEt)2
Title Environmentally benign ??-stereoselective glycosidations of glycosyl phosphites using a reusable heterogeneous solid acid, montmorillonite K-10
Citation Carbohydr. Res. 2005, 340, 337
DOI 10.1016/j.carres.2004.11.025
PROM-1346
Promoter Montomorillonite K-10
Leaving_Group -O-P-(OEt)2
Title Environmentally benign and stereoselective formation of ??-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10
Citation Carbohydr. Res. 2003, 338, 1531
DOI 10.1016/S0008-6215(03)00234-9
PROM-1347
Promoter Montomorillonite K-10
Leaving_Group -O-P-(OEt)2
Title Environmentally benign and stereoselective formation of ??-O-glycosidic linkages using benzyl-protected glucopyranosyl phosphite and montmorillonite K-10
Citation Tetrahedron Lett. 2002, 43, 847
DOI 10.1016/S0040-4039(01)02252-3
PROM-1348
Promoter Montomorillonite K-10
Leaving_Group OAc
Title Stereocontrolled route to 3-amino-2,3,6-trideoxy-hexopyranoses. K-10 Montmorillonite as a glycosidation reagent for acosaminide synthesis
Citation J. Chem. Soc. Chem. Commun. 1987, 1171
DOI 10.1039/C39870001171
PROM-135
Promoter MeOTf
Leaving_Group -S-C(S)-OEt
Title Glycosylation with sialic acid at HO-3 of three different O-protected D-galactosides in acetonitrile/dichloromethane at low temperature
Citation Tetrahedron Lett. 1991, 32, 7457
DOI 10.1016/0040-4039(91)80133-Q
PROM-1351
Promoter Montomorillonite K-10
Leaving_Group OH or OMe
Title Environmentally benign aryl C-glycosidations of unprotected sugars using montmorillonite K-10 as a solid acid
Citation Tetrahedron Lett. 1997, 38, 7375
DOI 10.1016/S0040-4039(97)01724-3
PROM-1353
Promoter Montomorillonite K-10
Leaving_Group OH
Title Novel stereocontrolled glycosidations of olivoses using montmorillonite K-10 as an environmentally benign catalyst
Citation Tetrahedron Lett. 1999, 40, 5023
DOI 10.1016/S0040-4039(99)00924-7
PROM-1357
Promoter Amberlyst 15
Leaving_Group trichloroimidate
Title Amberlyst 15 as a mild and effective activator for the glycosylation with disarmed glycosyl trichloroacetimidate donors
Citation Tetrahedron 2007, 63, 2142
DOI 10.1016/j.tet.2006.12.091
PROM-1358
Promoter ACF(carbon? fiber)
Leaving_Group OAc
Title A new method of solvent free O- and N-glycosylation using activated carbon fiber (ACF) as a promoter. Application to the synthesis of saponin and nucleoside analogues
Citation Chem. Commun. 2004, 586
DOI 10.1039/B315699K
PROM-1359
Promoter 4A?AW MS (Acid-Washed Molecular Sieves)
Leaving_Group -O-C(=NPh)-CF3, trichloroimidate
Title Activation of Glycoyl Trihaloacetimidates with Acid-Washed Molecular Sieves in the Glycosidation Reaction
Citation Org. Lett. 2003, 5, 987
DOI 10.1021/ol027353i
PROM-136
Promoter MeOTf
Leaving_Group -S-C(S)-OEt
Title Exceptionally high yield in glycosylation with sialic acid. Synthesis of a GM3 glycoside.
Citation Tetrahedron Lett. 1992, 33, 115
DOI 10.1016/S0040-4039(00)77688-X
PROM-1360
Promoter Nafion-TMS
Leaving_Group trichloroimidate
Title First Total Synthesis of the Re-Type Lipopolysaccharide
Citation Angew. Chem., Int. Ed.?2001, 40, 1475
DOI 10.1002/1521-3773(20010417)40:8<1475::AID-ANIE1475>3.0.CO;2-V
PROM-1361
Promoter recyclable solid superacid promoter(SO4/ZrO2 ?)
Leaving_Group ?
Title Glycosidation Promoted by a Reusable Solid Superacid in Supercritical Carbon Dioxide
Citation J. Org. Chem. 2005, 70, 9059
DOI 10.1002/anie.200602161
PROM-1362
Promoter pTSA/[bmim][BF4] ionic liquid
Leaving_Group ?
Title pTSA/[bmim][BF4] Ionic Liquid: A Powerful Recyclable Catalytic System for the Synthesis of ??-2-Deoxyglycosides
Citation Top. Catal. 2012, 55, 644
DOI 10.1007/s11244-012-9847-6
PROM-1364
Promoter Ag_NHC complex
Leaving_Group Br
Title O-Glycosidation reactions promoted by in situ generated silver N-heterocyclic carbenes in ionic liquids
Citation Carbohydr Res 2011, 346, 883
DOI 10.1016/j.carres.2011.03.007
PROM-1366
Promoter silver zeolite
Leaving_Group Cl
Title Ultrasonic Agitation Accelerates cis-Glycosylation with Heterogeneous Promoters
Citation Collect. Czech. Chem. Comm. 1993, 58, 159
DOI 10.1135/cccc19930159
PROM-1367
Promoter cadmium zeolite
Leaving_Group Cl
Title daburi
Citation daburi
DOI 10.1135/cccc19930159
PROM-1369
Promoter vitamin12a, Zn, NH4Cl
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/jlac.199619960109
PROM-137
Promoter MeOTf
Leaving_Group SePh
Title 1,2-Diacetals in Synthesis: Total Synthesis of a Glycosylphosphatidylinositol Anchor of Trypanosoma brucei
Citation Chem. Eur. J. 2000, 6, 172
DOI 10.1002/(SICI)1521-3765(20000103)6:1<172::AID-CHEM172>3.0.CO;2-5
PROM-1374
Promoter ?
Leaving_Group 4-pentenyl Glycoside
Title n-Pentenyl 2-amino-2-deoxy glycosides undergo stereoselective coupling under mild, chemospecific conditions
Citation Tetrahedron Lett. 1989, 30, 2363
DOI 10.1016/S0040-4039(01)80399-3
PROM-1375
Promoter ?
Leaving_Group n-pentenyl glycoside
Title n-Pentenyl esters versus n-pentenyl glycosides. Synthesis and reactivity in glycosidation reactions
Citation J. Chem. Soc., Chem. Commun., 1991, 159
DOI 10.1039/C39910000159
PROM-1376
Promoter ?
Leaving_Group n-pentenyl
Title Preparation, Properties, and Applications of n-Pentenyl Arabinofuranosyl Donors
Citation Org. Lett. 2004, 6, 3051
DOI 10.1021/ol0490680
PROM-1377
Promoter ?
Leaving_Group allyl glycoside
Title Vinyl Glycosides in Oligosaccharide Synthesis: A Strategy for the Preparation of Trisaccharide Libraries Based on Latent-Active Glycosylation
Citation Angew. Chem. Int. Ed.?1996, 35, 2845
DOI 10.1002/anie.199628451
PROM-1378
Promoter ?
Leaving_Group allyl glycoside
Title Vinyl glycosides in oligosaccharide synthesis (part 5): A latent-active glycosylation strategy for the preparation of branched trisaccharide libraries
Citation Tetrahedron Lett. 1998, 39, 9801
DOI 10.1016/S0040-4039(98)02177-7
PROM-1379
Promoter ?
Leaving_Group SePh
Title Novel glycosidation methodology. The use of phenyl selenoglycosides as glycosyl donors and acceptors in oligosaccharide synthesis
Citation J. Org. Chem, 1993, 58, 3269
DOI 10.1021/jo00064a012
PROM-138
Promoter MeOTf
Leaving_Group -S-P(=S)-(OEt)2
Title Anomeric Phosphorodithioates as Novel Glycosylating Agents
Citation J. Org. Chem. 1998, 63, 9150
DOI 10.1021/jo981552r
PROM-1380
Promoter ?
Leaving_Group Alkyloxytris(dimethylamino)phosphonium salts
Title Anomeric hydroxy-group activation of 2,3:4,6-di-O-isopropylidene-??-D-mannopyranose, thioglycosylation and glycosylation
Citation J. Chem. Soc., Perkin Trans. 1 1980, 381
DOI 10.1039/P19800000381
PROM-1381
Promoter ?
Leaving_Group -O-P-(OBn)2
Title Synthesis of dibenzyl glycosyl phosphites using dibenzyl N,N-diethylphosphoramidite as phosphitylating reagent: an effective route to glycosyl phosphates, nucleotides, and glycosides
Citation J. Am. Chem. Soc. 1993, 115, 2260
DOI 10.1021/ja00059a023
PROM-1382
Promoter ?
Leaving_Group -O-P-(OBn)2
Title Glycosyl Phosphites as Glycosylation Reagents: Scope and Mechanism
Citation J. Org. Chem. 1994, 59, 864
DOI 10.1021/jo00083a032
PROM-1383
Promoter ?
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Synthesis of fucosidase substrates using propane-1,3-diyl phosphate as the anomeric leaving group
Citation Tetrahedron Lett. 1999, 40, 3925
DOI 10.1016/S0040-4039(99)00571-7
PROM-1384
Promoter ?
Leaving_Group -O-P(=O)-(NMe2)2
Title ?gArmed-disarmed?h glycosidation strategy based on glycosyl donors and acceptors carrying phosphoroamidate as a leaving group: A convergent synthesis of globotriaosylceramide
Citation Tetrahedron Lett. 1997, 38, 8969
DOI 10.1016/S0040-4039(97)10365-3
PROM-1385
Promoter ?
Leaving_Group -S-P(=S)(OMe)2, -S-P(=S)(O-CH2)2-C-Me2
Title Efficient Synthesis of 2-Deoxyglycosyl-1-O-Acyl Esters via 2-Deoxyglycosyl Phosphorodithioates as Glycosyl Donors
Citation Synthesis 1994, 709
DOI 10.1055/s-1994-25554
PROM-1386
Promoter ?
Leaving_Group ?
Title Stereoselective synthesis of s-(2-deoxy-??-D-glycosyl)- phosphorodithioates1 and of their (2R)-2-deoxy-2-deuterio- analogues. Novel route to C-2 d
Citation Tetrahedron. 1988, 44, 2067
DOI 10.1016/S0040-4020(01)90350-3
PROM-1387
Promoter ?
Leaving_Group ?
Title First Stereqselective Synthesis of Nitrophenyl 2-Deoxy- ??-D-glycosides
Citation J. Carbohydr. Chem. 1986, 5, 445
DOI 10.1080/07328308608058848
PROM-1388
Promoter ?
Leaving_Group -S-P(=S)-(OMe)2
Title A Novel Stereoselective Route to Alkyl 2-Deoxy-??-D-glucosides via S-(2-Deoxy-??-glucosyl) Phosphorodithioates
Citation J. Carbohydr. Chem. 1983, 2, 99
DOI 10.1080/07328308308058811
PROM-1389
Promoter ?
Leaving_Group N-methylacetimidoyl
Title Application of the imidate procedure to ??-d-galactosyltion
Citation Carbohydr. Res. 1982, 100, 263
DOI 10.1016/S0008-6215(00)81040-X
PROM-139
Promoter MeOTf
Leaving_Group SPh
Title Stereoselective Synthesis of 2-S-Phenyl-2-deoxy-??-glycosides Using Phenyl 2,3-O-Thionocarbonyl-1-thioglycoside Donors via 1,2-Migration and Concurrent Glycosidation
Citation Org. Lett. 2001, 3, 377
DOI 10.1021/ol006894+
PROM-1390
Promoter ?
Leaving_Group -O-CH(=NMe2)+, O-CH(=N(iPr2))+, -O-CH(N-Formylmorpholine)
Title Tuning Reactivity of Glycosyl Imidinium Intermediate for 2-Azido-2-deoxyglycosyl Donors in ??-Glycosidic Bond Formation
Citation Org. Lett. 2013, 15, 5290
DOI 10.1021/ol402519c
PROM-1391
Promoter ?
Leaving_Group -O-C(=NPh)-CF3, S(O)Et
Title Is an acyl group at O-3 in glucosyl donors able to control ??-stereoselectivity of glycosylation? The role of conformational mobility and the protecting group at O-6
Citation Carbohydr. Res. 2014, 384, 70
DOI 10.1016/j.carres.2013.11.016
PROM-1392
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Synthesis of a Sialic Acid ??(2?|3) Galactose Building Block and Its Use in a Linear Synthesis of Sialyl Lewis X
Citation Org. Lett. 2007, 9, 1777
DOI 10.1021/ol0704946
PROM-1393
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Synthetic oligorhamnans related to the most common O-chain backbone from phytopathogenic bacteria
Citation Tetrahedron 2006, 62, 8474
DOI 10.1016/j.tet.2006.06.084
PROM-1394
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Synthesis of the tetrasaccharide residue of clarhamnoside, a novel glycosphingolipid isolated from the marine sponge Agelas clathrodes
Citation Carbohydr. Res. 2006, 341, 2769
DOI 10.1016/j.carres.2006.09.018
PROM-1395
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title First synthesis of an ??-d-Fucp3NAc containing oligosaccharide: a study on d-Fucp3NAc glycosylation
Citation Tetrahedron 2005, 61, 5439
DOI 10.1016/j.tet.2005.04.013
PROM-1396
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods
Citation Chem. Commun. 2010, 46, 4668
DOI 10.1039/C0CC00563K
PROM-1397
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Glycosyl Trifluoroacetimidates. 2. Synthesis of Dioscin and Xiebai Saponin I
Citation J. Org. Chem. 2002. 67, 9099
DOI 10.1021/jo026103c
PROM-1398
Promoter ?
Leaving_Group trichloroimidate, OAc
Title Aromatic O-glycosylation
Citation Carbohydr. Res. 2006, 341, 1266
DOI 10.1016/j.carres.2006.04.004
PROM-1399
Promoter ?
Leaving_Group trichloroimidate
Title Study of the Stereoselectivity of 2-Azido-2-deoxygalactosyl Donors: Remote Protecting Group Effects and Temperature Dependency
Citation J. Org. Chem. 2011, 76, 5207
DOI 10.1021/jo1025157
PROM-14
Promoter TMSOTf
Leaving_Group Thiazolylketoses
Title Thiazolylketoses: a new class of versatile intermediates for glycoside synthesis
Citation Chem. Commun. 1999, 2133
DOI 10.1039/A903758F
PROM-140
Promoter MeOTf
Leaving_Group -S-C(S)-piperidine
Title daburi
Citation daburi
DOI 10.1016/0008-6215(91)84154-7
PROM-1400
Promoter ?
Leaving_Group trichloroimidate, alkylsulfenyl, halide
Title Extended Applications of Di-tert-butylsilylene-Directed ??-Predominant Galactosylation Compatible with C2-Participating Groups toward the Assembly of Various Glycosides
Citation Chem. Eur. J. 2006, 12, 8862
DOI 10.1002/chem.200600832
PROM-1401
Promoter ?
Leaving_Group trichloroimidate, SPh, F
Title Trifluoroethylsulfonate protected monosaccharides in glycosylation reactions
Citation Tetrahedron Lett. 2004, 45, 6433
DOI 10.1016/j.tetlet.2004.06.131
PROM-1402
Promoter ?
Leaving_Group trichloroimidate
Title Protection of Hydroxy Groups with Diphenylmethyl and 9-Fluorenyl Trichloroacetimidates ?| Effect on Anomeric Stereocontrol
Citation Eur. J. Org. Chem. 2003, 4121
DOI 10.1002/ejoc.200300323
PROM-1403
Promoter ?
Leaving_Group trichloroimidate
Title 4-Acetoxy-2,2-dimethylbutanoate: a useful carbohydrate protecting group for the selective formation of ??-(1??3)-d-glucans
Citation Tetrahedron Lett. 2005, 46, 3417
DOI 10.1016/j.tetlet.2005.03.099
PROM-1404
Promoter ?
Leaving_Group trichloroimidate
Title ??- and ??-d-glucopyranosyl phosphates from O-??-D-glucoypyranosyl trichloroacetimidates
Citation Tetrahedron Lett. 1982, 23, 405
DOI 10.1016/S0040-4039(00)86843-4
PROM-1405
Promoter ?
Leaving_Group Br or Cl
Title Chemical synthesis of 2-acetamido-2-deoxy-4-O-(.alpha.-L-fucopyranosyl)-3-O-(.beta.-D-galactopyranosyl)-D-glucose. Lewis a blood-group antigenic determinant
Citation J. Am. Chem. Soc. 1975, 97, 4063
DOI 10.1021/ja00847a033
PROM-1406
Promoter ?
Leaving_Group Br or Cl
Title Chemical synthesis of 2-O-(.alpha.-L-fucopyranosyl)-3-O-(.alpha.-D-galactopyranosyl)-D-galactose. Terminal structure of the blood-group B antigenic determinant
Citation J. Am. Chem. Soc. 1975, 97, 4069
DOI 10.1021/ja00847a034
PROM-1407
Promoter ?
Leaving_Group Br or Cl
Title Properties of a synthetic antigen related to the human blood-group Lewis a
Citation J. Am. Chem. Soc. 1975, 97, 4076
DOI 10.1021/ja00847a035
PROM-1408
Promoter ?
Leaving_Group Br or Cl
Title AN IMPROVED PHASE TRANSFER CATALYZED SYNTHETIC METHOD FOR ONONIN AND ROTHINDIN
Citation Synth. Commun. 2001, 31, 3423
DOI 10.1081/SCC-100106200
PROM-1409
Promoter ?
Leaving_Group Br or Cl
Title Phase-transfer-catalyzed d-glucosylation: Synthesis of benzoylated aryl ??-d-glucopyranosides and ??-d-glucopyranosyl-substituted cinnamates
Citation Carbohydr. Res., 1987, 162, 117
DOI 10.1016/0008-6215(87)80206-9
PROM-141
Promoter MeOTf
Leaving_Group SEt
Title Synthesis of a tri- and a hepta-saccharide which contain ??-l-fucopyranosyl groups and are part of the complex type of carbohydrate moiety of glycoproteins
Citation Carbohydr. Res. 1985, 139, 105
DOI 10.1016/0008-6215(85)90011-4
PROM-1410
Promoter ?
Leaving_Group Br or Cl
Title Expedient syntheses of neoglycoproteins using phase transfer catalysis and reductive amination as key reactions
Citation Glycoconjugate Journal, 1991, 8, 75
DOI 10.1007/BF00731015
PROM-1411
Promoter ?
Leaving_Group Br
Title Studies on 1,2,4-triazine derivatives. III. The Behaviour of some Derivatives of 1,2,4-Triazine toward diazomethane, amines, ethyl monobromoacetate and tetra-O-acetyl-??-D-glucopyranosyl bromide
Citation J. Parkt. Chem. (B) 1973, 315, 221
DOI 10.1002/prac.19733150205
PROM-1412
Promoter ?
Leaving_Group Br
Title Glycosylation of 4?]Aryl?]1?]thioxo[1,2,4] triazolo[4,3?]a] quinazolin?]5(4H)?]one
Citation J. Carbohydr. Chem. 2003, 22, 79
DOI 10.1081/CAR-120020479
PROM-1413
Promoter ?
Leaving_Group Br
Title An expedient route to acylated glucosyl halides with a free 2-OH group
Citation Carbohydr. Res. 1994, 258, 77
DOI 10.1016/0008-6215(94)84076-8
PROM-1414
Promoter ?
Leaving_Group Br
Title Synthesis of aryl ??-D-glucopyranosides and aryl ??-D-glucopyranosiduronic acids
Citation Tetrahedron Lett., 1979, 52, 5051
DOI 10.1016/S0040-4039(01)86787-3
PROM-1415
Promoter ?
Leaving_Group Br
Title Effect of the nature of protecting group at O-4 on stereoselectivity of glycosylation by 4-O-substituted 2,3-di-O-benzylfucosyl bromides
Citation Mendeleev Commun. 1999, 114
DOI 10.1070/MC1999v009n03ABEH001073
PROM-1416
Promoter ?
Leaving_Group Br
Title Substituent effects in carbohydrate chemistry, Part II+. Coupling reactions involving gluco- and galacto-pyranosyl bromides promoted by insoluble silver salts
Citation Recl. Trav. Chim. Pays-Bas, 1985, 104, 171
DOI 10.1002/recl.19851040604
PROM-1417
Promoter ?
Leaving_Group I
Title Anionic Additions to Glycosyl Iodides:_ Highly Stereoselective Syntheses of ?? C-, N-, and O-Glycosides
Citation J. Org. Chem. 1997, 62, 6961
DOI 10.1021/jo970922t
PROM-1418
Promoter ?
Leaving_Group I
Title Glycal Scavenging in the Synthesis of Disaccharides Using Mannosyl Iodide Donors
Citation J. Org. Chem. 2005, 70, 2387
DOI 10.1021/jo0478609
PROM-1419
Promoter ?
Leaving_Group I
Title Efficient Synthesis of ??-Galactosyl Ceramide Analogues Using Glycosyl Iodide Donors
Citation Org. Lett. 2005, 7, 2063
DOI 10.1021/ol050659f
PROM-142
Promoter MeOTf
Leaving_Group SEt
Title Synthesis of a tetra- and a nona-saccharide which contain ??-l-fucopyranosyl groups and are part of the complex type of carbohydrate moiety of glycoproteins
Citation Carbohydr. Res. 1985, 139, 115
DOI 10.1016/0008-6215(85)90012-6
PROM-1420
Promoter ?
Leaving_Group F
Title Total synthesis of cyclomaltohexaose
Citation Carbohydr. Res. 1987, 164, 277
DOI 10.1016/0008-6215(87)80136-2
PROM-1421
Promoter ?
Leaving_Group F
Title Directed stereoselective synthesis of ??- and ??-N-acetyl neuraminic acid_galactose disaccharides using 2-choro and 2-fluoro derivatives of neuraminic acid allyl ester
Citation J. Chem. Soc., Chem. Commun. 1985, 638
DOI 10.1039/C39850000638
PROM-1422
Promoter ?
Leaving_Group F
Title 2-Deoxyglycosyl fluorides in oligosaccharide synthesis
Citation Liebigs Ann. Chem. 1991, 759
DOI 10.1002/jlac.1991199101130
PROM-1423
Promoter ?
Leaving_Group F?H
Title Total synthesis of the tumor-associated Lex family of glycosphingolipids
Citation J. Am. Chem. Soc. 1990, 112, 3693??
DOI 10.1021/ja00165a084
PROM-1424
Promoter ?
Leaving_Group F?H
Title Total synthesis of sialyl dimeric Lex
Citation J. Am. Chem. Soc.?1992, 114, 3126?
DOI 10.1021/ja00034a063
PROM-1425
Promoter ?
Leaving_Group F?H
Title Practical synthesis of oligosaccharides. Partial synthesis of avermectin B1a
Citation J. Am. Chem. Soc. 1984, 106, 4189
DOI 10.1021/ja00327a021
PROM-1426
Promoter ?
Leaving_Group F?H
Title Stereospecific synthesis of rhynchosporosides, a family of fungal metabolites causing scald disease in barley and other grasses
Citation J. Am. Chem. Soc. 1986, 107, 5556
DOI 10.1021/ja00305a056
PROM-1427
Promoter ?
Leaving_Group F?H
Title A practical and enantioselective synthesis of glycosphingolipids and related compounds. Total synthesis of globotriaosylceramide (Gb3)
Citation J. Am. Chem. Soc. 1988, 110, 7910
DOI 10.1021/ja00231a071
PROM-1428
Promoter ?
Leaving_Group F
Title Total synthesis of globotriaosylceramide (Gb3) and lysoglobotriaosylceramide (lysoGb3)
Citation Carbohydr. Res. 1990, 202, 177
DOI 10.1016/0008-6215(90)84079-A
PROM-1429
Promoter ?
Leaving_Group F?H(Cl?)
Title Total synthesis of baiyunoside by a novel 2?? discriminated glycosidation
Citation Tetrahedron Lett. 1987, 28, 4315
DOI 10.1016/S0040-4039(00)96495-5
PROM-143
Promoter MeOTf
Leaving_Group trichloroimidate
Title A Novel and Effective Procedure for the Preparation of Glucuronides
Citation Org. Lett. 2000, 2,?2539
DOI 10.1021/ol0062143
PROM-1430
Promoter ?
Leaving_Group F?H
Title Syntheses of sweet tasting diterpene glycosides, baiyunoside and analogs
Citation Tetrahedron 1992, 48, 3021
DOI 10.1016/S0040-4020(01)92246-X
PROM-1431
Promoter ?
Leaving_Group F
Title Reactions of glycosyl fluorides. Synthesis of C-glycosides
Citation J. Chem. Soc. Chem. Commun. 1984, 1153
DOI 10.1039/C39840001153
PROM-1432
Promoter ?
Leaving_Group F
Title Synthesis of N-linked glycan derived from Gram-negative bacterium, Campylobacter jejuni
Citation Tetrahedron 2007, 63, 8181
DOI 10.1016/j.tet.2007.05.126
PROM-1433
Promoter ?
Leaving_Group F
Title Synthesis and glycosylating properties of ketopyranosyl donors
Citation Tetrahedron 1995, 51, 5657
DOI 10.1016/0040-4020(95)00225-W
PROM-1434
Promoter rare earth metal salts, with or without ZnCl2 and Ba(ClO4)2
Leaving_Group F
Title Rare Earth Salts Promoted Glycosidation of Glycosyl Fluorides
Citation Heterocycles 1996, 42, 795
DOI 10.3987/COM-95-S87
PROM-1435
Promoter ?
Leaving_Group F
Title Preparations and reactions of acylated and partially acylated glycosyl fluorides
Citation Carbohydr. Res. 1993, 249, 197.
DOI 10.1016/0008-6215(93)84069-I
PROM-1436
Promoter ?
Leaving_Group F
Title Chemistry and Developments of Fluorinated Carbohydrates
Citation Adv. Carbohydr. Chem. Biochem. 1990, 48, 91
DOI 10.1016/S0065-2318(08)60032-3
PROM-1437
Promoter ?
Leaving_Group SR
Title Thioglycosides in sequential glycosylation strategies
Citation Chem. Soc. Rev. 2005, 34, 769
DOI 10.1039/B417138C
PROM-1438
Promoter ?
Leaving_Group SR
Title Thioglycosides in Carbohydrate Research
Citation Carbohydr. Res. 2015, 403, 13
DOI 10.1016/j.carres.2014.06.009
PROM-1439
Promoter ?
Leaving_Group SR
Title The 2-N,N-Dibenzylamino Group as a Participating Group in the Synthesis of ??-Glycosides
Citation Angew. Chem., Int. Ed. 1999, 38, 346
DOI 10.1002/(SICI)1521-3773(19990201)38:3<346::AID-ANIE346>3.0.CO;2-L
PROM-144
Promoter MeOTf
Leaving_Group OH
Title 1-O-Alkylation of D-Glucopyranose
Citation J. Carbohydr. Chem. 1984, 3, 6
DOI 10.1080/07328308408057898
PROM-1440
Promoter ?
Leaving_Group SR
Title Incidence and avoidance of stereospecific 1,2-ethylthio group migration during the synthesis of ethyl 1-thio-??-l-rhamnopyranoside 2,3-orthoester
Citation Carbohydr. Res. 1991, 212, 13
DOI 10.1016/0008-6215(91)84041-C
PROM-1441
Promoter ?
Leaving_Group SR
Title Syntheses and properties of some photolabile ??-thioglycosides. Potential photoaffinity reagents for ??-glycoside hydrolases
Citation Tetrahedron 1990, 46, 3129
DOI 10.1016/S0040-4020(01)85452-1
PROM-1442
Promoter ?
Leaving_Group SR
Title Synthesis of p-nitrobenzyl and p-nitrophenyl 1-trioglycopyranosides
Citation Carbohydr. Res. 1975, 43, 101
DOI 10.1016/S0008-6215(00)83976-2
PROM-1443
Promoter ?
Leaving_Group SR
Title (5-Nitro-2-pyridyl) 1-thio-??-d-glucopyranoside as a stable and reactive acceptor
Citation Tetrahedron Lett. 2000, 41, 9923
DOI 10.1016/S0040-4039(00)01765-2
PROM-1444
Promoter ?
Leaving_Group SR
Title Glycosylations Directed by the Armed-Disarmed Effect with Acceptors Containing a Single Ester Group
Citation Eur. J. Org. Chem. 2007, 3935
DOI 10.1002/ejoc.200700347
PROM-1445
Promoter ?
Leaving_Group SR
Title Extended applications and potential limitations of ring-fused 2,3-oxazolidinone thioglycosides in glycoconjugate synthesis
Citation Tetrahedron Lett. 2003, 44, 8069
DOI 10.1016/j.tetlet.2003.09.058
PROM-1446
Promoter ?
Leaving_Group STol
Title Stereoselective Synthesis of a Fragment of Mycobacterial Arabinan
Citation Org. Lett. 2006, 8, 5525
DOI 10.1021/ol062198j
PROM-1447
Promoter ?
Leaving_Group STol
Title Versatile acetylation of carbohydrate substrates with bench-top sulfonic acids and application to one-pot syntheses of peracetylated thioglycosides
Citation Carbohydr. Res. 2008, 343, 957
DOI 10.1016/j.carres.2008.01.014
PROM-1448
Promoter ?
Leaving_Group SMe
Title Synthetic oligosaccharides related to group B streptococcal polysaccharides. 3. Synthesis of oligosaccharides corresponding to the common polysaccharide antigen of group B streptococci
Citation J. Org. Chem. 1988, 53, 4042
DOI 10.1021/jo00252a030
PROM-1449
Promoter ?
Leaving_Group SMe
Title Total synthesis of a sulfated glucuronyl glycosphingolipid, IV3GlcA(3-SO3)nLcOse4Cer, a carbohydrate epitope of neural cell adhesion molecules
Citation Tetrahedron Lett. 1990, 31, 1597
DOI 10.1016/0040-4039(90)80026-I
PROM-1450
Promoter ?
Leaving_Group SMe
Title Stereoselectivity of cycloglycosylation in mannooligose series depends on carbohydrate chain length: Syntheses of manno isomers of ??- and ??- cyclodextrins
Citation Tetrahedron Lett. 1990, 31, 3191
DOI 10.1016/S0040-4039(00)94729-4
PROM-1451
Promoter ?
Leaving_Group SMe
Title Highly Optimized ??-Mannosylation via p-Methoxybenzyl Assisted Intramolecular Aglycon Delivery
Citation Synlett. 1998, 1102
DOI 10.1055/s-1998-1894
PROM-1452
Promoter ?
Leaving_Group SMe
Title A Stereoselective Approach for the Synthesis of ??-Sialosides
Citation J. Org. Chem. 2001, 66, 5490
DOI 10.1021/jo010345f
PROM-1453
Promoter ?
Leaving_Group SEt
Title Total synthesis of a sulfated glucuronic acid containing glycoheptaosyl ceramide, a minor glycolipid isolated from human cauda equina tissue
Citation Tetrahedron Lett. 1991, 32, 1569
DOI 10.1016/S0040-4039(00)74274-2
PROM-1454
Promoter ?
Leaving_Group SEt
Title Total synthesis of a stage specific embryonic antigen-1 (SSEA-1) a glycoheptaosyl ceramide V3FucnLc6Cer
Citation Tetrahedron Lett. 1988, 29, 4759
DOI 10.1016/S0040-4039(00)80600-0
PROM-1455
Promoter ?
Leaving_Group SEt
Title Total synthesis of nonasaccharide repeating unit of plant cell wall xyloglucan: An endogenous hormone which regulates cell growth
Citation Tetrahedron Lett. 1990, 31, 3035
DOI 10.1016/S0040-4039(00)89019-X
PROM-1456
Promoter ?
Leaving_Group SEt
Title Synthesis and Conformational Analysis of a Conformationally Constrained Trisaccharide, and Complexation Properties with Concanavalin A
Citation Chem. Eur. J. 1999, 5, 2281
DOI 10.1002/(SICI)1521-3765(19990802)5:8<2281::AID-CHEM2281>3.0.CO;2-D
PROM-1457
Promoter ?
Leaving_Group SEt
Title Synthesis of Tethered Trisaccharides To Probe Inter-Saccharide Flexibility in Carbohydrate?|Protein Interactions
Citation J. Org. Chem. 1998, 63, 6288
DOI 10.1021/jo9806097
PROM-1458
Promoter ?
Leaving_Group SEt
Title A novel donor for stereoselective ??-sialylation; efficient synthesis of an ??(2_8)-linked bis-sialic acid unit
Citation Tetrahedron Lett. 1999, 40, 2217
DOI 10.1016/S0040-4039(99)00175-6
PROM-1459
Promoter ?
Leaving_Group SEt
Title Intermolecular aglycon transfer of ethyl 1-thiorhamnopyranosides under Koenigs?%5CKnorr and Helferich glycosylation conditions
Citation Carbohydr. Res. 1995, 276, 417
DOI 10.1016/0008-6215(95)00182-S
PROM-1460
Promoter ?
Leaving_Group SEt
Title Highly ??-Selective O-Glucosidation Due to the Restricted Twist-Boat Conformation
Citation Org. Lett. 2007, 9, 1573
DOI 10.1021/ol070427b
PROM-1461
Promoter ?
Leaving_Group SPh
Title Organometallics in organic synthesis. Applications of a new diorganozinc reaction to the synthesis of C-glycosyl compounds with evidence for an oxonium-ion mechanism
Citation Carbohydr. Res. 1987, 171, 109
DOI 10.1016/S0008-6215(00)90882-6
PROM-1462
Promoter ?
Leaving_Group SPh
Title 6-O-Benzyl- and 6-O-Silyl-N-acetyl-2-amino-2-N,3-O-carbonyl-2-deoxyglucosides: Effective Glycosyl Acceptors in the Glucosamine 4-OH Series. Effect of Anomeric Stereochemistry on the Removal of the Oxazolidinone Group
Citation J. Org. Chem. 2005, 70, 1291
DOI 10.1021/jo0482559
PROM-1463
Promoter ?
Leaving_Group SPh
Title Dialkylphosphates as Stereodirecting Protecting Groups in Oligosaccharide Synthesis
Citation Angew. Chem. Int. Ed. 2006, 45, 7575
DOI 10.1002/anie.200602699
PROM-1464
Promoter ?
Leaving_Group SPh
Title The 3,4-O-Carbonate Protecting Group as a ??-Directing Group in Rhamnopyranosylation in Both Homogeneous and Heterogeneous Glycosylations As Compared to the Chameleon-like 2,3-O-Carbonates
Citation J. Org. Chem. 2003, 68, 8453
DOI 10.1021/jo035003j
PROM-1465
Promoter ?
Leaving_Group SPh
Title Application of 4,5-O,N-oxazolidinone protected thiophenyl sialosyl donor to the synthesis of ??-sialosides
Citation Tetrahedron Lett. 2007, 48, 1225
DOI 10.1016/j.tetlet.2006.12.061
PROM-1466
Promoter ?
Leaving_Group SPy
Title A mild general method for the synthesis of ??-2-deoxy-disaccharides: Synthesis of L-oleandrosyl-L-oleandrose from D-glucose
Citation Tetrahedron Lett. 1989, 30, 4287
DOI 10.1016/S0040-4039(01)80712-7
PROM-1467
Promoter ?
Leaving_Group SPy
Title C-Glycosidation of pyridyl thioglycosides
Citation J. Am. Chem. Soc. 1985, 107, 4289
DOI 10.1021/ja00300a036
PROM-1468
Promoter ?
Leaving_Group SPh, SR, SPh-4-OMe
Title Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry
Citation J. Org. Chem. 2011, 76, 9193
DOI 10.1021/jo2017026
PROM-1469
Promoter ?
Leaving_Group Dicyclohexylmethyl thioglycosides
Title Chemoselective Glycosylation Strategy for the Convergent Assembly of Phytoalexin-Elicitor Active Oligosaccharides and Their Photoreactive Derivatives
Citation J. Org. Chem. 1999, 64, 7828
DOI 10.1021/jo990836o
PROM-147
Promoter MeOTf
Leaving_Group ?
Title Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts
Citation Org. Lett. 2011, 13, 2928
DOI 10.1021/ol2009818
PROM-1470
Promoter ?
Leaving_Group SCN
Title Stereospecific 1,2-cis-glycosylation: a modified thiocyanate method
Citation Carbohydr. Res. 1992, 232, C1
DOI 10.1016/S0008-6215(00)91007-3
PROM-1471
Promoter ?
Leaving_Group SCN, SEt, STaz, SBox
Title On the stereoselectivity of glycosidation of thiocyanates, thioimidates, and thioglycosides
Citation Carbohydr. Res. 2010, 345, 2146
DOI 10.1016/j.carres.2010.08.003
PROM-1472
Promoter ?
Leaving_Group STaz, SEt
Title Potent, Versatile, and Stable: Thiazolyl Thioglycosides as Glycosyl Donors
Citation Angew. Chem., Int. Ed. 2004, 43, 3069
DOI 10.1002/anie.200454047
PROM-1473
Promoter ?
Leaving_Group STaz
Title S-Thiazolinyl (STaz) Glycosides as Versatile Building Blocks for Convergent Selective, Chemoselective, and Orthogonal Oligosaccharide Synthesis
Citation Chem. Eur. J. 2006, 12, 6630
DOI 10.1002/chem.200600262
PROM-1474
Promoter ?
Leaving_Group S-Box? (S-benzoxazolyl)
Title Thiomidoyl approach to the synthesis of ??-sialosides
Citation Tetrahedron: Asymmetry 2005, 16, 303
DOI 10.1016/j.tetasy.2004.11.043
PROM-1475
Promoter ?
Leaving_Group 1-thioimidoyl
Title Synthesis of galactofuranose-containing disaccharides using thioimidoyl-type donors
Citation Carbohydr. Res. 2006, 341, 2759
DOI 10.1016/j.carres.2006.10.001
PROM-1476
Promoter ?
Leaving_Group S-Benzimidazolyl
Title A novel synthesis of d-galactofuranosyl, d-glucofuranosyl and d-mannofuranosyl 1-phosphates based on remote activation of new and free hexofuranosyl donors
Citation Bioorg. Med. Chem. Lett. 2002, 12, 3515
DOI 10.1016/S0960-894X(02)00822-3
PROM-1477
Promoter ?
Leaving_Group 1-thioimidoyl
Title General One-Step Synthesis of Free Hexofuranosyl 1-Phosphates Using Unprotected 1-Thioimidoyl Hexofuranosides
Citation J. Org. Chem. 2005, 70, 847
DOI 10.1021/jo0484934
PROM-1478
Promoter ?
Leaving_Group SPhCl
Title Synthesis of (1??4)-Linked 2-Deoxy-2-fluoroglucose Oligomers. 1
Citation Org. Lett. 2000, 2, 3489
DOI 10.1021/ol006529i
PROM-1479
Promoter ?
Leaving_Group PhS(O)-
Title Toward the Development of a General Chiral Auxiliary. 5. High Diastereofacial Selectivity in Cycloadditions with Trienol Silyl Ethers:_ An Application to an Enantioselective Synthesis of (?|)-Cassioside
Citation J. Org. Chem. 1996, 61, 7984
DOI 10.1021/jo961613q
PROM-148
Promoter MeOTf
Leaving_Group SEt
Title Total synthesis of the trisaccharide unit of the molecular chaperone down-regulator versipelostatin
Citation Synthesis 2006, 2397
DOI 10.1055/s-2006-942450
PROM-1480
Promoter ?
Leaving_Group PhS(O)2-
Title D-glycopyranosyl phenylsulfones: Their use in a stereocontrolledsynthesis of cis-2,6-disubstituted tetrahydropyrans (??-d-c-clycosides)
Citation Tetrahedron Lett. 1985, 26, 6189
DOI 10.1016/S0040-4039(00)95049-4
PROM-1481
Promoter ?
Leaving_Group PhS(O)2-
Title D-glycopyranosyl phenylsulfones: Acylation of their lithiated anions and reductive desulfonylation of the resulting acylated sulfones. A synthesis of ??-D-C-glycosides
Citation Tetrahedron Lett. 1985, 26, 6193
DOI 10.1016/S0040-4039(00)95050-0
PROM-1482
Promoter ?
Leaving_Group ?
Title A synthesis of ??-d-mannopyranosides by glycosidation at C-1
Citation Carbohydr. Res. 1980, 79, C13
DOI 10.1016/S0008-6215(00)85144-7
PROM-1483
Promoter ?
Leaving_Group ?
Title Reactions of trifluoromethanesulfonic anhydride at the anomeric centre
Citation Carbohydr. Res. 1976, 47, C8
DOI 10.1016/S0008-6215(00)84206-8
PROM-1484
Promoter ?
Leaving_Group SPy
Title Rhamnosylation: Diastereoselectivity of Conformationally Armed Donors
Citation J. Org. Chem. 2012, 77, 5559
DOI 10.1021/jo300591k
PROM-1485
Promoter ?
Leaving_Group ?
Title 1-O-tosyl-d-glucopyranose derivatives in ??-d-glucoside synthesis
Citation Carbohydr. Res. 1974, 34, 79
DOI 10.1016/S0008-6215(00)80372-9
PROM-1486
Promoter ?
Leaving_Group ?
Title beta-D-mannopyranosides and beta-L-rhamnopyranosides
Citation J. Org. Chem. 1981, 46, 1121
DOI 10.1021/jo00319a016
PROM-1487
Promoter ?
Leaving_Group -OSO2CF3
Title CHEMISTRY OF GLYCOSYL TRIFLATES: SYNTHESIS OF ??-MANNOPYRANOSIDES
Citation J. Carbohydr. Chem. 2002, 21, 663
DOI 10.1081/CAR-120016486
PROM-1488
Promoter ?
Leaving_Group -OSO2CF3
Title 1,2-cis O-Glycosylation: Methods, Strategies, Principles
Citation Curr. Org. Chem. 2003, 7, 35.
DOI 10.2174/1385272033373175
PROM-1489
Promoter ?
Leaving_Group -OSO2CF3
Title Influence of Protecting Groups on the Reactivity and Selectivity of Glycosylation: Chemistry of the 4,6-O-Benzylidene Protected Mannopyranosyl Donors and Related Species
Citation Top. Curr. Chem. 2011, 301, 141
DOI 10.1007/128_2010_102
PROM-149
Promoter MeOTf
Leaving_Group SR (R = ?)
Title daburi
Citation daburi
DOI 10.1016/0008-6215(87)80137-4
PROM-1490
Promoter ?
Leaving_Group sulfoxide
Title Concise Synthesis of the Calicheamicin Oligosaccharide Using the Sulfoxide Glycosylation Method
Citation J. Am. Chem. Soc. 1994, 116, 1766
DOI 10.1021/ja00084a018
PROM-1491
Promoter ?
Leaving_Group SPh
Title Synthesis of a ??-(1??3)-d-Rhamnotetraose by a One-Pot, Multiple Radical Fragmentation
Citation Org. Lett. 2006, 8, 4327
DOI 10.1021/ol061706m
PROM-1492
Promoter ?
Leaving_Group ?
Title Significant Substituent Effect on the Anomerization of Pyranosides: Mechanism of Anomerization and Synthesis of a 1,2-cis Glucosamine Oligomer from the 1,2-trans Anomer
Citation Chem. Eur. J. 2014, 20, 124
DOI 10.1002/chem.201303474
PROM-1493
Promoter ?
Leaving_Group SPh
Title Superarming of Glycosyl Donors by Combined Neighboring and Conformational Effects
Citation Org. Lett. 2013, 15, 4904
DOI 10.1021/ol402371b
PROM-1494
Promoter ?
Leaving_Group -S(NTs)Et
Title Synthesis of Anomeric Sulfimides and Their Use as a New Family of Glycosyl Donors
Citation Eur. J. Org. Chem. 2002, 171
DOI 10.1002/1099-0690(20021)2002:1<171::AID-EJOC171>3.0.CO;2-7
PROM-1495
Promoter TsOH or ZnCl2 ?
Leaving_Group OAc
Title Eine neue Methode zur Synthese von Glykosiden der Phenole
Citation Chem. Ber. 1933, 66, 378
DOI 10.1002/cber.19330660313
PROM-1496
Promoter ?
Leaving_Group OAc
Title C-Mannose derivatives as potent mimics of sialyl Lewis X
Citation Tetrahedron Lett. 1996, 37, 9037
DOI 10.1016/S0040-4039(96)02124-7
PROM-1497
Promoter ?
Leaving_Group OAc
Title Design and Synthesis of Sialyl Lewis X Mimetics
Citation J. Am. Chem. Soc. 1995, 117, 5395
DOI 10.1021/ja00124a037
PROM-1498
Promoter ?
Leaving_Group OAc
Title Design and synthesis of C-linked fucosides as inhibitors of E-selectin
Citation Bioorg. & Med. Chem. 1996, 4, 1149
DOI 10.1016/0968-0896(96)00127-7
PROM-1499
Promoter ?
Leaving_Group OAc
Title C-Fucopeptides as selectin antagonists: Attachment of lipid moieties enhances the activity
Citation Tetrahedron Lett. 1996, 37, 9033
DOI 10.1016/S0040-4039(96)02121-1
PROM-15
Promoter TMSOTf
Leaving_Group PhS(O)
Title Trimethylsilyl triflate mediated chemoselective condensation of arylsulfenyl glycosides
Citation Tetrahedron Lett. 1994, 35, 4015
DOI 10.1016/S0040-4039(00)76728-1
PROM-150
Promoter MeOTf
Leaving_Group SEt, trichloroacetimidate
Title Application and limitations of the methyl imidate protection strategy of N-acetylglucosamine for glycosylations at O-4: synthesis of Lewis A and Lewis X trisaccharide analogues
Citation Carbohydr. Res. 2008, 343, 2914
DOI 10.1016/j.carres.2008.08.025
PROM-1500
Promoter ?
Leaving_Group -S-C(O)-OPh
Title Synthetic studies with carbonates. Part 11. D-Glucopyranose 1-carbonate derivatives; pyrolytic behaviour and use for glucosylation of phenols
Citation J. Chem. Soc., Perkin Trans 1977, 1, 1382
DOI 10.1039/P19770001382
PROM-1501
Promoter ?
Leaving_Group -O-C(O)-S-(2-Py)
Title Synthesis of a Potent Antagonist of E-Selectin
Citation J. Org. Chem. 2002, 67, 3346
DOI 10.1021/jo0110956
PROM-1502
Promoter ?
Leaving_Group Glycosyl-N-allyl carbamates
Title Oligosaccharide Synthesis via Electrophile-Induced Activation of Glycosyl-N-Allylcarbamates
Citation J. Carbohydr. Chem. 1998, 17, 759
DOI 10.1080/07328309808002350
PROM-1503
Promoter ?
Leaving_Group N-unsubstituted, mono-, disubstituted carbamates
Title Synthesis of N-unsubstituted, mono- and disubstituted carbohydrate-1-O-carbamates and their behaviour in glycoside syntheses
Citation Carbohydr. Res. 2004, 339, 2821
DOI 10.1016/j.carres.2004.10.002
PROM-1504
Promoter ?
Leaving_Group trichloroacetylcarbamate
Title Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation
Citation Carbohydr. Res. 2005, 340, 2688
DOI 10.1016/j.carres.2005.07.024
PROM-1505
Promoter gold(I)
Leaving_Group ortho-alkynylbenzoates
Title Assembly of Digitoxin by Gold(I)-Catalyzed Glycosidation of Glycosyl o-Alkynylbenzoates
Citation J. Org. Chem. 2011, 76, 9748
DOI 10.1021/jo201850z
PROM-1506
Promoter gold(I)
Leaving_Group ortho-alkynylbenzoates
Title Characterization of the Isochromen-4-yl-gold(I) Intermediate in the Gold(I)-Catalyzed Glycosidation of Glycosyl ortho-Alkynylbenzoates and Enhancement of the Catalytic Efficiency Thereof
Citation Angew. Chem. Int. Ed. 2011, 50, 8329
DOI 10.1002/anie.201103409
PROM-1507
Promoter ?
Leaving_Group trichloroimidate
Title Total synthesis of amphotericin B. 3. The final stages
Citation J. Am. Chem. Soc. 1988, 110, 4696
DOI 10.1021/ja00222a030
PROM-1508
Promoter Acyl Sulfonamide (?⑫?Q??)
Leaving_Group trichloroimidate
Title Acyl Sulfonamide Catalysts for Glycosylation Reactions with Trichloroacetimidate Donors
Citation Synlett. 2003, 1923
DOI 10.1055/s-2003-41493
PROM-1509
Promoter ?
Leaving_Group trichloroimidate
Title A novel synthesis of 1,2-cis-disaccharides
Citation J. Am. Chem. Soc. 1977, 99, 6762
DOI 10.1021/ja00462a052
PROM-151
Promoter MeOTf
Leaving_Group F, SEt
Title daburi
Citation daburi
DOI 10.1021/ja962048b
PROM-1510
Promoter ?
Leaving_Group trichloroimidate
Title Glycosyl Imidates, 43 Synthesis of Lactoneotetraosyl Ceramide
Citation Liebigs Ann. Chem. 1989, 1107
DOI 10.1002/jlac.198919890277
PROM-1511
Promoter ?
Leaving_Group trichloroimidate
Title Total synthesis of a hexaosyl ceramide glycolipid acting as a receptor for macrophage migration inhibition-factor
Citation Tetrahedron Lett. 1990, 31, 1849
DOI 10.1016/S0040-4039(00)98802-6
PROM-1512
Promoter ?
Leaving_Group trichloroimidate
Title Glycosyl imidates. 49. Synthesis of the octasaccharide moiety of the dimeric Lex antigen
Citation Liebigs Ann. Chem. 1991, 425
DOI 10.1002/jlac.199119910178
PROM-1513
Promoter ?
Leaving_Group trichloroimidate
Title Glycosyl Imidates, 52. Synthesis of Globotriaosylceramide (Gb3) and Isoglobotriaosylceramide (isoGb3)
Citation Liebigs Ann. Chem. 1992, 21
DOI 10.1002/jlac.199219920140
PROM-1514
Promoter ?
Leaving_Group trichloroimidate
Title An efficient synthesis of the Lewis X (Lex) antigen family
Citation Tetrahedron Lett. 1992, 33, 5161
DOI 10.1016/S0040-4039(00)79122-2
PROM-1515
Promoter ?
Leaving_Group trichloroimidate
Title An efficient approach to stereoselective glycosylation of ceramide derivatives: Use of pivaloyl group as a stereocontrolling auxiliary
Citation Tetrahedron Lett. 1988, 29, 4097
DOI 10.1016/S0040-4039(00)80426-8
PROM-1516
Promoter ?
Leaving_Group trichloroimidate
Title A total synthesis of dimeric Lex antigen, III3V3Fuc2nLc6Cer: Pivaloyl auxiliary for stereocontrolled glycosylation
Citation Tetrahedron Lett. 1988, 29, 5267
DOI 10.1016/S0040-4039(00)80733-9
PROM-1517
Promoter ?
Leaving_Group trichloroimidate
Title A total synthesis of a stage specific embryonic antigen-3 (SSEA-3), globopentaosyl ceramide, IV3GalGb4Cer. Use of 2,4,6-trimethylbenzoyl group as a stereocontrolling auxiliary
Citation Tetrahedron Lett. 1988, 29, 5681
DOI 10.1016/S0040-4039(00)80845-X
PROM-1518
Promoter ?
Leaving_Group trichloroimidate
Title A synthetic approach to keratan sulfate I: Synthesis of trisulfated glycotetraose
Citation Tetrahedron Lett. 1989, 30, 4547
DOI 10.1016/S0040-4039(01)80741-3
PROM-1519
Promoter ?
Leaving_Group trichloroimidate
Title Stereoselective synthesis of a core glycoheptaose of bisected biantenarry complex type glycan of glycoproteins
Citation Tetrahedron Lett. 1989, 30, 4417
DOI 10.1016/S0040-4039(00)99376-6
PROM-152
Promoter TBSOTf
Leaving_Group -O-P(=O)-(OBu)2
Title daburi
Citation daburi
DOI 10.1021/ja016227r
PROM-1520
Promoter ?
Leaving_Group trichloroimidate
Title Building blocks for oligonucleotide analogs with dimethylene-sulfide, -sulfoxide, and -sulfone groups replacing phosphodiester linkages
Citation Tetrahedron Lett. 1990, 31, 385
DOI 10.1016/S0040-4039(00)94548-9
PROM-1521
Promoter ?
Leaving_Group trichloroimidate
Title Stereocontrolled syntheses of phytoalexin elicitor-active ??-D-glucohexaoside and ??-D-glucononaoside
Citation Tetrahedron Lett. 1990, 31, 3179
DOI 10.1016/S0040-4039(00)94726-9
PROM-1522
Promoter ?
Leaving_Group trichloroimidate
Title Synthetic studies on cell-surface glycans. 65. Highly stereoselective synthesis of ganglioside GD3
Citation J. Am. Chem. Soc. 1989, 111, 8508
DOI 10.1021/ja00204a028
PROM-1523
Promoter ?
Leaving_Group trichloroimidate
Title Synthesis of allosamidin
Citation J. Chem. Soc., Chem. Commun. 1991, 1099
DOI 10.1039/C39910001099
PROM-1524
Promoter ?
Leaving_Group trichloroimidate
Title Total syntheses of bulgecinine and bulgecin C from (2S,4R)-hydroxyproline
Citation J. Org. Chem. 1990, 55, 5194
DOI 10.1021/jo00305a007
PROM-1525
Promoter ?
Leaving_Group trichloroimidate
Title Synthesis of the Calicheamicin Aryltetrasaccharide Domain Bearing a Reducing Terminus: Coupling of Fully Synthetic Aglycone and Carbohydrate Domains by the Schmidt Reaction
Citation Angew. Chem. Int. Ed. Engl. 1992, 31, 338
DOI 10.1002/anie.199203381
PROM-1526
Promoter ?
Leaving_Group trichloroimidate
Title Total Synthesis of Calicheamicin_Dynemicin Hybrid Molecules
Citation Angew. Chem. Int. Ed. Engl. 1992, 31, 340
DOI 10.1002/anie.199203401
PROM-1527
Promoter ?
Leaving_Group trichloroimidate
Title 6-S-Phenyl-glycopyranosides as ready precursors to the synthesis of glycuronides
Citation Tetrahedron 2001, 57, 9403
DOI 10.1016/S0040-4020(01)00959-0
PROM-1528
Promoter ?
Leaving_Group trichloroimidate
Title Stereoselective Synthesis of ??-D-Mannopyranosides Neighboring EWG
Citation Angew. Chem., Int. Ed. 2004, 43, 4389
DOI 10.1002/anie.200490119
PROM-1529
Promoter ?
Leaving_Group 2'-caboxybenzyl glycoside
Title Synthesis of the Trisaccharide Repeating Unit of the Atypical O-Antigen Polysaccharide from Danish Helicobacter pylori Strains Employing the 2?e-Carboxybenzyl Glycoside
Citation Org. Lett. 2004, 6, 3901
DOI 10.1021/ol048648u
PROM-153
Promoter TBSOTf
Leaving_Group -C(NH)CCl3, OAc
Title A Highly Stereoselective Synthesis of the Landomycin A Hexasaccharide Unit
Citation J. Am. Chem. Soc. 2000, 122, 6124
DOI 10.1021/ja000743k
PROM-1530
Promoter ?
Leaving_Group trichloroimidate
Title Glycosylation with Trichloroacetimidates in Ionic Liquids:_ Influence of the Reaction Medium on the Stereochemical Outcome
Citation J. Org. Chem. 2005, 70, 7765
DOI 10.1021/jo050704x
PROM-1531
Promoter ?
Leaving_Group trichloroimidate
Title Glycosyl Imidates, 76. Synthesis of Aryl C-Glycosides of Glucosamine
Citation Liebigs Ann. Chem. 1996, 1623
DOI 10.1002/jlac.199619961019
PROM-1532
Promoter ?
Leaving_Group trichloroimidate
Title Glycosyl imidates, 69. Synthesis of flavone C-glycosides vitexin, isovitexin, and isoembigenin
Citation Liebigs Ann. Chem. 1995, 461
DOI 10.1002/jlac.199519950362
PROM-1533
Promoter ?
Leaving_Group trichloroimidate
Title A practical synthesis of ??-d-mannopyranosides
Citation Tetrahedron Lett. 1998, 39, 5721
DOI 10.1016/S0040-4039(98)01163-0
PROM-1534
Promoter ?
Leaving_Group trichloroimidate
Title Glycosylimidate, 8. Synthese von 1-Thioglycosiden
Citation Liebigs Ann. Chem. 1983, 1249
DOI 10.1002/jlac.198319830717
PROM-1535
Promoter ?
Leaving_Group trichloroimidate
Title C-glycosides from O-glycosyl trichloroacetimidates
Citation Tetrahedron Lett. 1982, 23, 409
DOI 10.1016/S0040-4039(00)86844-6
PROM-1536
Promoter ?
Leaving_Group trichloroimidate
Title Intermolecular aglycon transfer of a phenyl 1-thiogalactosaminide derivative under trichloroacetimidate glycosylation conditions
Citation Carbohydr. Res. 1996, 290, 79
DOI 10.1016/0008-6215(96)00116-4
PROM-1537
Promoter ?
Leaving_Group 2'-caboxybenzyl glycoside
Title Synthesis of the tetrasaccharide repeat unit of the O-antigen polysaccharide from Escherichia coli O77 employing the 2??-carboxybenzyl glycoside
Citation Can. J. Chem. 2006, 84, 506
DOI 10.1139/v06-030
PROM-1538
Promoter ?
Leaving_Group 2'-caboxybenzyl glycoside
Title Synthesis of Tri-, Hexa-, and Nonasaccharide Subunits of the Atypical O-Antigen Polysaccharide of the Lipopolysaccharide from Danish Helicobacter pylori Strains
Citation J. Org. Chem. 2007, 72, 9963
DOI 10.1021/jo701531x
PROM-1539
Promoter ?
Leaving_Group methyl dinitrosalicylate (DISAL)
Title Efficient synthesis of glycosylated phenazine natural products and analogs with DISAL (methyl 3,5-dinitrosalicylate) glycosyl donors
Citation Org. Biomol. Chem. 2003, 1, 3147
DOI 10.1039/B306789K
PROM-154
Promoter TBSOTf
Leaving_Group OH, OAc, -C(NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja801008m
PROM-1540
Promoter ?
Leaving_Group methyl dinitrosalicylate (DISAL)
Title DISAL Glycosyl Donors for the Synthesis of a Linear Hexasaccharide under Mild Conditions
Citation Org. Lett. 2003, 5, 1309
DOI 10.1021/ol034242q
PROM-1541
Promoter ?
Leaving_Group 2,4-Dichloro-1,3,5-triazinyl glycoside
Title Synthesis of Hetaryl Glycosides and Their Glycosyl Donor Properties
Citation Eur. J. Org. Chem. 1998, 1353
DOI 10.1002/(SICI)1099-0690(199807)1998:7<1353::AID-EJOC1353>3.0.CO;2-C
PROM-1542
Promoter ?
Leaving_Group OH
Title Chemoselective Iterative Dehydrative Glycosylation
Citation Angew. Chem. Int. Ed. 2001, 40, 414
DOI 10.1002/1521-3773(20010119)40:2<414::AID-ANIE414>3.0.CO;2-6
PROM-1543
Promoter ?
Leaving_Group OH
Title Nouvelle m_thode de synth_se St_r_os_lective de glycosides. Synt_se des ??,??-tr_halose, analogues galacto, manno et autres ??-d-glycosides
Citation Carbohydr.Res. 1980, 79, 79
DOI 10.1016/S0008-6215(00)85133-2
PROM-1544
Promoter ?
Leaving_Group Br
Title A novel method for stereoselective glucuronidation
Citation J. Org. Chem. 1984, 49, 4988
DOI 10.1021/jo00199a046
PROM-1545
Promoter ?
Leaving_Group OH
Title Facile, Highly Selective Synthesis of ??- and ??-Disaccharides from 1-O-Metalated D-Ribofuranoses
Citation Angew. Chem., Int. Ed. Engl. 1979, 18, 466
DOI 10.1002/anie.197904661
PROM-1546
Promoter ?
Leaving_Group OH
Title Synthesis of ??- and ??-D-mannofuranosides via 1-O-alkylation
Citation Tetrahedron Lett. 1980, 21, 3661
DOI 10.1016/0040-4039(80)80235-8
PROM-1547
Promoter ?
Leaving_Group OH
Title Synthesis of ??- and ??-glycopyranosides via 1-O-alkylation
Citation Tetrahedron Lett. 1980, 21,?3565
DOI 10.1016/0040-4039(80)80236-X
PROM-1548
Promoter ?
Leaving_Group OH
Title Synthesis of ??-D-mannopyranosides and? ??-L-rhamnopyranosides by glycosidation at C-1
Citation J. Org. Chem. 1981, 46, 1121
DOI 10.1021/jo00319a016
PROM-1549
Promoter ?
Leaving_Group OH
Title O-Alkylierung am anomeren Zentrum, 4. 1-O-Alkylierung von D-Mannofuranose und D-Mannopyranose
Citation Chem. Ber. 1982, 115, 39
DOI 10.1002/cber.19821150106
PROM-155
Promoter TBSOTf
Leaving_Group SEt, trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1038/nature00937
PROM-1550
Promoter ?
Leaving_Group OH
Title Simple Synthesis of KDO ??-Glycosides by Anomerically Selective O-Alkylation
Citation Angew. Chem., Int. Ed. Engl. 1988, 27, 1178
DOI 10.1002/anie.198811781
PROM-1551
Promoter secondary alkyl trifluoromethanesulfonates
Leaving_Group OH
Title Anomeric O-Alkylation, 9. Disaccharide Synthesis via Anomeric O-Alkylation
Citation Liebigs Ann. Chem. 1992, 37
DOI 10.1002/jlac.199219920165
PROM-1552
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes. Part 2. Synthesis of O-Aryl Glycosides
Citation Helv. Chim. Acta 1990, 73, 1764
DOI 10.1002/hlca.19900730621
PROM-1553
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title New reactions and intermediates involving the anomeric center
Citation Pure Apple. Chem. 1991, 63, 507
DOI 10.1351/pac199163040507
PROM-1554
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes. Part 6. Synthesis of alkyl and fluoroalkyl glycosides
Citation Helv. Chim. Acta 1992, 75, 621
DOI 10.1002/hlca.19920750218
PROM-1555
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes. Part 19. Regioselective glycosidation of allyl 2-deoxy-2-phthalimido-D-allopyranosides
Citation Helv. Chim. Acta 1994, 77, 1969
DOI 10.1002/hlca.19940770724
PROM-1556
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes. Part 14. Glycosidation of partially protected galactopyranose-, glucopyranose-, and mannopyranose-derived vicinal diols
Citation Helv. Chim. Acta 1994, 77, 257
DOI 10.1002/hlca.19940770128
PROM-1557
Promoter ?
Leaving_Group diazirine sugar via glycosylidene carbene?
Title Glycosylidene Carbenes. Part 16. Glycosidation of methyl 6-O-trityl-??-D-altropyranoside
Citation Helv. Chim. Acta, 1994, 77, 745
DOI 10.1002/hlca.19940770316
PROM-1558
Promoter ?
Leaving_Group ?
Title Challenges in the stereocontrolled syntheses of ??-rhamnosides
Citation Tetrahedron 2008, 64, 10631
DOI 10.1016/j.tet.2008.09.001
PROM-1559
Promoter ?
Leaving_Group ?
Title Mannuronic Acids: Reactivity and Selectivity
Citation J. Carbohydr. Chem. 2011, 30, 438
DOI 10.1080/07328303.2011.624284
PROM-156
Promoter TBSOTf
Leaving_Group OAc
Title Studies on the Synthesis of Apoptolidin A. 2. Synthesis of the Disaccharide Unit
Citation J. Org. Chem. 2008, 73, 1036
DOI 10.1021/jo7022526
PROM-1560
Promoter ?
Leaving_Group ?
Title Recent Advances in Monosaccharide Synthesis: A Journey into L-Hexose World
Citation Curr. Org. Chem. 2009, 13, 71
DOI 10.2174/138527209787193828
PROM-1561
Promoter ?
Leaving_Group ?
Title Stereoselective Synthesis of L-Guluronic Acid Alginates
Citation Chem. - Eur. J. 2008, 14, 9400
DOI 10.1002/chem.200800960
PROM-1562
Promoter ?
Leaving_Group -O-C(=NPh)-CF3
Title Automated Solid-Phase Synthesis of ??-Mannuronic Acid Alginates
Citation Angew. Chem., Int. Ed. 2012, 51, 4393
DOI 10.1002/anie.201108744
PROM-1563
Promoter ?
Leaving_Group ?
Title Glycosyl donors in ?gunusual?h conformations _ influence on reactivity and selectivity
Citation C. R. Chim. 2011, 14, 17
DOI 10.1016/j.crci.2010.03.030
PROM-1564
Promoter ?
Leaving_Group ?
Title Going to Extremes: ?gSuper?h Armed Glycosyl Donors in Glycosylation Chemistry
Citation Chem. - Eur. J. 2007, 13, 7576
DOI 10.1002/chem.200700947
PROM-1565
Promoter ?
Leaving_Group ?
Title Conformational analysis of nitrilium intermediates in glycosylation reactions
Citation Carbohydr. Res. 1993, 246, 23
DOI 10.1016/0008-6215(93)84021-W
PROM-1566
Promoter ?
Leaving_Group ?
Title Low-Concentration 1,2-trans ??-Selective Glycosylation Strategy and Its Applications in Oligosaccharide Synthesis
Citation Chem. - Eur. J. 2009, 15, 10972
DOI 10.1002/chem.200901119
PROM-1567
Promoter ?
Leaving_Group ?
Title Strategies of Synthetic Methodologies for Constructing ??-Mannosidic Linkage
Citation Curr. Org. Synth. 2005, 2, 175
DOI 10.2174/1570179053545378
PROM-1568
Promoter ?
Leaving_Group ?
Title Stereoselective ??-Glycosylation with 3-O-Acetylated d-Gluco Donors
Citation Synlett 2006, 921
DOI 10.1055/s-2006-939037
PROM-1569
Promoter ?
Leaving_Group ?
Title The anomers of p-nitrophenyl 2,3,5-tri-O-benzyl-D-arabinofuranoside
Citation Carbohydr. Res. 1976, 50, 292
DOI 10.1016/S0008-6215(00)83863-X
PROM-157
Promoter TBSOTf
Leaving_Group trichloroimidate
Title Total Synthesis of Olivomycin A
Citation J. Am. Chem. Soc. 1999, 121, 1990
DOI 10.1021/ja984229e
PROM-1570
Promoter ?
Leaving_Group ?
Title Synthesis of methyl ??- and ??-maltotriosides and aryl ??-maltotriosides
Citation Carbohydr. Res. 1976, 48, 197
DOI 10.1016/S0008-6215(00)83215-2
PROM-1571
Promoter ?
Leaving_Group ?
Title Aryl glycosides of oligosaccharides : part I. p-bromophenyl ??-glycosides of cellobiose, lactose, and maltose
Citation Carbohydr. Res. 1969, 11, 363
DOI 10.1016/S0008-6215(00)80578-9
PROM-1572
Promoter ?
Leaving_Group ?
Title Synthesis of a potential water-soluble radiographic contrast medium, 2,4,6-triiodo-3-acetamido-5-N-methylcarboxamidophenyl .beta.-D-glucopyranoside
Citation J. Med. Chem. 1976, 19, 353
DOI 10.1021/jm00225a001
PROM-1573
Promoter ?
Leaving_Group ?
Title Synthesis of Substituted Phenyl-??-D-xylo-pyranosides
Citation Nature, 1965, 205, 900
DOI 10.1038/205900a0
PROM-1574
Promoter ?
Leaving_Group Br
Title Convenient Syntheses of Nitrophenyl _-D-Galactopyranosides and Nitrophenyl _-D-Glucopyranosides using Resin-bound Phenoxides
Citation Synthesis, 1979, 823
DOI 10.1055/s-1979-28849
PROM-1575
Promoter ?
Leaving_Group ?
Title Phase-transfer-catalyzed synthesis of 2,3,4,6-tetra-O-acetyl-??-d-galactopyranosides
Citation Carbohydr. Res. 1985, 142, 333
DOI 10.1016/0008-6215(85)85036-9
PROM-1576
Promoter ?
Leaving_Group ?
Title A convenient preparation of p-nitrophenyl 2-acetamido-2-deoxy-??-d-glucopyranoside
Citation Carbohydr. Res. 1969, 10, 311
DOI 10.1016/S0008-6215(00)80473-5
PROM-1577
Promoter ?
Leaving_Group ?
Title Highly stereoselective glycosylation of N-acetylneuraminic acid aided by a phenylthio substituent as a stereocontrolling auxilliary
Citation Tetrahedron Lett. 1988, 29, 3987
DOI 10.1016/S0040-4039(00)80400-1
PROM-1578
Promoter ?
Leaving_Group ?
Title Sialic Acid Donors: Chemical Synthesis and Glycosylation
Citation Curr. Org. Synth. 2004, 1, 31
DOI 10.2174/1570179043485448
PROM-1579
Promoter ?
Leaving_Group ?
Title Mechanism of 4,6-O-Benzylidene-Directed ??-Mannosylation as Determined by ??-Deuterium Kinetic Isotope Effects
Citation Angew. Chem., Int. Ed. 2004, 43, 5386
DOI 10.1002/anie.200453688
PROM-158
Promoter TBSOTf
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/ja407827n
PROM-1580
Promoter ?
Leaving_Group ?
Title DTBS Effect: The Unique Sterically Driven Director for ??-Galactosylation
Citation Heterocycles 2008, 76, 883
DOI 10.3987/REV-08-SR(N)4
PROM-1581
Promoter ?
Leaving_Group ?
Title Neighboring-Group Participation by C-2 Ether Functions in Glycosylations Directed by Nitrile Solvents
Citation Chem._Eur. J. 2011, 17, 12193
DOI 10.1002/chem.201100732
PROM-1582
Promoter ?
Leaving_Group ?
Title Convenient Multigram Scale Glycosylations of Scented Alcohols Employing Phase?]Transfer Reactions
Citation J. Carbohydr. Chem. 2003, 22, 9
DOI 10.1081/CAR-120019010
PROM-1583
Promoter ?
Leaving_Group ?
Title The stepwise synthesis of methyl ??-isomaltooligoside derivatives and methyl ??-isomaltopentaoside
Citation Carbohydr. Res. 1976, 50, 203
DOI 10.1016/S0008-6215(00)83852-5
PROM-1584
Promoter ?
Leaving_Group ?
Title The synthesis of ??-isomalto-oligosaccharide derivatives and their protein conjugates
Citation Carbohydr. Res. 1979, 70, 75
DOI 10.1016/S0008-6215(00)83271-1
PROM-1585
Promoter ?
Leaving_Group ?
Title The synthesis of antigenic determinants for yeast d-mannan, and a linear (1??6)-??-d-gluco-d-mannan, and their protein conjugates
Citation Carbohydr.Res. 1979, 77, 61
DOI 10.1016/S0008-6215(00)83793-3
PROM-1586
Promoter ?
Leaving_Group ?
Title Synthesis and characterization of methyl 6-O-??-d-galactopyranosyl-??-d-galactopyranoside and methyl O-??-d-galactopyranosyl-(1??6)-O-??-d-galactopyranosyl-(1??6)-??-d-galactopyranoside
Citation Carbohydr. Res. 1980, 86, 203
DOI 10.1016/S0008-6215(00)85899-1
PROM-1587
Promoter ?
Leaving_Group ?
Title The synthesis of ??-and ??-(1 ?? 2)- and -(1 ?? 3)-linked glucopyranose disaccharides and their protein conjugates
Citation Carbohydr. Res. 1982, 102, 131
DOI 10.1016/S0008-6215(00)88056-8
PROM-1588
Promoter ?
Leaving_Group trichloroacetimidate
Title A comparative study of the influence of some protecting groups on the reactivity of d-glucosamine acceptors with a galactofuranosyl donor
Citation Carbohydr. Res. 2006, 341, 1096
DOI 10.1016/j.carres.2006.03.030
PROM-1589
Promoter ?
Leaving_Group Hg
Title Intramolecular oximercuration-demercuration reaction: a new stereocontrolled approach to sialic acid containing disaccharides
Citation Tetrahedron Lett. 1984, 25, 3071
DOI 10.1016/0040-4039(84)80010-6
PROM-159
Promoter TBDMSOTf
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1021/ol027066e
PROM-1591
Promoter ?
Leaving_Group ?
Title Application of the 2,5-Dimethylpyrrole Group as a New and Orthogonal Amine-Protecting Group in Oligosaccharide Synthesis
Citation J. Org. Chem. 1998, 63, 4570
DOI 10.1021/jo9808728
PROM-1592
Promoter ?
Leaving_Group ?
Title Use of the p-nitrobenzyloxycarbonyl group as an orthogonalamine protecting group in the synthesis of ??-GlcNAc terminatingglycosides
Citation Chem. Commun. 1997, 1059
DOI 10.1039/A700549K
PROM-1595
Promoter gold(I) complex
Leaving_Group o-hexynylbenzoate
Title Synthesis of Kaempferol 3-O-(3????,6????-Di-O-E-p-coumaroyl)-??-d-glucopyranoside, Efficient Glycosylation of Flavonol 3-OH with Glycosyl o-Alkynylbenzoates as Donors
Citation J. Org. Chem. 2010, 75, 6879
DOI 10.1021/jo1014189
PROM-16
Promoter TMSOTf
Leaving_Group OAc
Title Trimethylsilyl trifluoromethanesulfonate as an effective catalyst for glycoside synthesis
Citation Carbohydr. Res. 1981, 93, C6
DOI 10.1016/S0008-6215(00)80765-X
PROM-160
Promoter TBDMSOTf
Leaving_Group ?
Title A novel intramolecular decarboxylative glycosylation via mixed carbonate
Citation Tetrahedron Lett. 1996, 37, 2267
DOI 10.1016/0040-4039(96)00272-9
PROM-1601
Promoter palladium
Leaving_Group 1-tributylstannyl glycals
Title Arylation of 1-tributylstannyl glycals catalyzed by palladium: A synthetic route to the basic skeleton of the papulacandins and chaetiacandin
Citation Terrahedron Lett. 1990, 31, 5165
DOI 10.1016/S0040-4039(00)97832-8
PROM-1609
Promoter ?
Leaving_Group ?
Title First Examples of ??-(1??4)-Glycosylation Reactions on Ionic Liquid Supports
Citation Eur. J. Org. Chem. 2010, 6366
DOI 10.1002/ejoc.201000754
PROM-161
Promoter DTBS(OTf)2
Leaving_Group ?
Title A Novel Synthetic Route to ??-Galactosyl Ceramides and iGb3 Using DTBS-Directed ??-Selective Galactosylation
Citation Synlett 2006, 2379
DOI 10.1055/s-2006-949649
PROM-162
Promoter (CH3)5SiOSO2C4F9
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/cber.19811140404
PROM-163
Promoter (CH3)3SiClO4
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/cber.19811140404
PROM-164
Promoter TMSI
Leaving_Group I
Title Efficient Route to 2-Deoxy ??-O-Aryl-d-Glycosides via Direct Displacement of Glycosyl Iodides : conversion of glycals to 2-deoxy glycosyl acetates
Citation Org. Lett. 2003, 5, 4219
DOI 10.1021/ol035705v
PROM-165
Promoter TMSI
Leaving_Group I
Title Per-O-Trimethylsilyl-??-L-Fucopyranosyl Iodide: A Novel Glycosylating Agent for Terminal ??-L-Fucosylation
Citation Synlett. 1996, 499
DOI 10.1055/s-1996-5491
PROM-166
Promoter TMSI
Leaving_Group I
Title Efficient Synthesis of O-, S-, N- and C-Glycosides of 2-Amino-2-Deoxy-d-Glucopyranose from Glycosyl Iodides
Citation Synlett 2004, 2, 341
DOI 10.1055/s-2003-44978
PROM-167
Promoter TMSI?or (Me3Si)2, I2
Leaving_Group I
Title Preparation, X-ray structure and reactivity of a stable glycosyl iodide
Citation Chem. Commun. 2003, 1266
DOI 10.1039/B302629A
PROM-168
Promoter TMSI
Leaving_Group ?
Title
Citation
DOI 10.1016/S0040-4039(01)80261-6
PROM-1687
Promoter base promoted, acid catalyzed
Leaving_Group Br
Title Synthesis of a thio-linked analogue of sialyl Lewis X
Citation Tetrahedron Lett. 1996, 37, 1389
DOI 10.1016/0040-4039(96)00061-5
PROM-169
Promoter IBr
Leaving_Group Br, SMe
Title Glycosylation chemistry promoted by iodine monobromide: Efficient synthesis of glycosyl bromides from thioglycosides, and O-glycosides from ?edisarmed?f thioglycosides and glycosyl bromides
Citation Tetrahedron Lett. 1997. 87, 8233
DOI 10.1016/S0040-4039(97)10124-1
PROM-17
Promoter TMSOTf
Leaving_Group F
Title Glycosylation using glucopyranosyl fluorides and silicon-based catalysts. Solvent dependency of the stereoselection
Citation Tetrahedron Lett. 1984. 25, 1379
DOI 10.1016/S0040-4039(01)80163-5
PROM-170
Promoter IBr
Leaving_Group PhS(O)-
Title daburi
Citation daburi
DOI 10.1055/s-2003-40346
PROM-171
Promoter IBr
Leaving_Group SMe
Title daburi
Citation daburi
DOI 10.1016/S0957-4166(99)00501-7
PROM-172
Promoter IBr
Leaving_Group -S-S-Et
Title daburi
Citation
DOI 10.1021/jo051374j
PROM-173
Promoter ICl
Leaving_Group SMe
Title daburi
Citation daburi
DOI 10.1016/S0957-4166(99)00501-7
PROM-174
Promoter BF3?EEt2O
Leaving_Group F
Title Reactions of glycosyl fluorides. Synthesis of O-, S-, and N-glycosides
Citation J. Chem.Soc. Chem. Commun. 1984, 1155
DOI 10.1039/C39840001155
PROM-175
Promoter BF3?EEt2O
Leaving_Group F
Title Stereoselective glycosylation of Alcohols and Silyl Ethers Using Glycosyl Fluorides and Boron Trifluoride Etherate
Citation Helv. Chim. Acta. 1985, 68, 283
DOI 10.1002/hlca.19850680134
PROM-176
Promoter BF3?EEt2O
Leaving_Group Ac
Title Boron trifluoride etherate-induced glycosidation: formation of alkyl glycosides and thioglycosides of 2-deoxy-2-phthalimidoglycopyranoses
Citation Carbohydr. Res. 1983, 114, 328
DOI 10.1016/0008-6215(83)88202-0
PROM-177
Promoter BF3?EEt2O
Leaving_Group Ac
Title A stereoconvergent synthesis of the oligosaccharide segment of glyco- peptidolipid antigen of mycobacterium avium serotype 4 : a dominant serovariant observed in patients with acquired immune deficiency syndrome
Citation Tetrahedron Lett. 1991, 32, 6191
DOI 10.1016/0040-4039(91)80786-6
PROM-178
Promoter BF3?EEt2O
Leaving_Group Ac
Title Reaction of 1,2-trans-glycosyl acetates with thiourea: a new entry to 1-thiosugars
Citation Tetrahedron Lett. 2003, 44, 7961
DOI 10.1016/j.tetlet.2003.08.120
PROM-1788
Promoter insoluble silver salts
Leaving_Group ?
Title Studies directed towards the synthesis of sulphated and non-sulphated glyco-conjugate fragments using insoluble silver-salt promoters
Citation Recl. Trav. Chim. Pays-Bas 1989, 108, 360
DOI 10.1002/recl.19891081008
PROM-179
Promoter BF3?EEt2O
Leaving_Group COCCl3
Title daburi
Citation daburi
DOI 10.1080/00397919508011769
PROM-1791
Promoter palladium(II) complex
Leaving_Group STaz
Title A Novel Strategy for Oligosaccharide Synthesis via Temporarily Deactivated S-Thiazolyl Glycosides as Glycosyl Acceptors
Citation Org. Lett. 2004, 6, 4515
DOI 10.1021/ol048043y
PROM-18
Promoter TMSOTf
Leaving_Group trichloroimidate
Title N-Dimethylphosphoryl-protected glucosamine trichloroacetimidate as an effective glycosylation donor
Citation Tetrahedron Lett. 2007, 48, 4557
DOI 10.1016/j.tetlet.2007.04.150
PROM-180
Promoter BF3?EEt2O
Leaving_Group COC6H4-p-NO2
Title Practical Synthesis of Disaccharide H
Citation J. Carbohydr. Chem. 1992, 11, 397
DOI 10.1080/07328309208018001
PROM-181
Promoter BF3?EEt2O
Leaving_Group COC6H4-p-NO2
Title Stereoselective ??-glycosylation of nitro sugar evernitrose: synthesis of the terminal AB unit of everninomicin antibiotics
Citation J. Org. Chem. 1991, 56, 7144
DOI 10.1021/jo00025a034
PROM-182
Promoter BF3?EEt2O
Leaving_Group COCF3
Title daburi
Citation daburi
DOI 10.1080/00397919208021347
PROM-183
Promoter BF3?EEt2O
Leaving_Group C(S)SMe
Title Anomeric Xanthates: A New Activation of the Anomeric Center for Rapid Glycosylation
Citation J. Carbohydr. Chem. 1986, 5, 529
DOI 10.1080/07328308608058854
PROM-184
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title Total Synthesis of the Anticancer Natural Product OSW-1
Citation J. Am. Chem. Soc. 2002, 124, 6576
DOI 10.1021/ja012119t
PROM-185
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title A One-Step Procedure for Facile Preparation of D-Glucopyranosides with a free 2-OH from O-Peracetylated ??-D-Glucopyranose
Citation J. Carbohydr. Chem. 1996, 15, 1139
DOI 10.1080/07328309608006502
PROM-186
Promoter BF3?EEt2O
Leaving_Group trichloroimidate (or C(=NPh)-CF3)
Title daburi
Citation daburi
DOI 10.1016/j.carres.2012.09.025
PROM-187
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1021/ja972764t
PROM-188
Promoter BF3?EEt2O
Leaving_Group F
Title Novel synthesis of aryl 2,3,4,6-tetra-O-acetyl-D-glucopyranosides
Citation J. Chem. Soc. Perkin Trans. 1 1990, 1079
DOI 10.1039/P19900001079
PROM-189
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title Differential reactivity of carbohydrate hydroxyls in glycosylations. II. The likely role of intramolecular hydrogen bonding on glycosylation reactions. Galactosylation of nucleoside 5??-hydroxyls for the syntheses of novel potential anticancer agents
Citation Can. J. Chem. 1994, 72, 2225
DOI 10.1139/v94-284
PROM-19
Promoter TMSOTf
Leaving_Group -C(=NPh)-CF3
Title Glycosyl trifluoroacetimidates. Part 1: Preparation and application as new glycosyl donors
Citation Tetrahedron Lett. 2001, 42, 2405
DOI 10.1016/S0040-4039(01)00157-5
PROM-190
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title Direct and Stereoselective Synthesis of ??-Linked 2-Deoxyglycosides
Citation Org. Lett. 2008, 10, 4367
DOI 10.1021/ol801833n
PROM-191
Promoter BF3?EEt2O
Leaving_Group -C(=NPh)-CF3
Title Facile Synthesis of Flavonoid 7-O-Glycosides
Citation J. Org. Chem. 2003, 68, 6842
DOI 10.1021/jo034553e
PROM-192
Promoter BF3?EEt2O
Leaving_Group STol
Title Lewis Acids as ??-Directing Additives in Glycosylations by Using 2,3-O-Carbonate-Protected Glucose and Galactose Thioglycoside Donors Based on Preactivation Protocol
Citation J. Org. Chem. 2012, 77, 5255
DOI doi.rog/10.1021/jo3002084
PROM-193
Promoter BF3?EEt2O
Leaving_Group OH
Title One-pot synthesis of per-O-acetylated thioglycosides from unprotected reducing sugars
Citation Carbohydr. Res. 2005, 340, 1393
DOI 10.1016/j.carres.2005.02.027
PROM-194
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title Direct synthesis of mono-glycosylated catechols from glycosylacetates or imidates using BF3.OEt2 as catalyst
Citation Tetrahedron Lett., 1993, 34, 4531
DOI 10.1016/0040-4039(93)88077-V
PROM-195
Promoter BF3?EEt2O
Leaving_Group -O-C(=N-Ph)(SCF3)? ?
Title Catalytic Glycosylation with Glycosyl Thioimidate Donors
Citation Eur. J. Org. Chem. 2008, 4401
DOI 10.1002/ejoc.200800503
PROM-196
Promoter BF3?EEt2O
Leaving_Group TMS
Title Studies on Glycosides VI. Facile Synthesis of Alkyl ??-and ??-D-Glucopyranosides
Citation Synth. Commun. 1989, 19, 3453
DOI 10.1080/00397918908052754
PROM-197
Promoter BF3?EEt2O
Leaving_Group -O-P(=NTs)-Ph2
Title A new and general glycosidation method for podophyllum lignan glycosides
Citation Tetrahedron Lett. 1991, 32, 1653
DOI 10.1016/S0040-4039(00)74296-1
PROM-198
Promoter BF3?EEt2O
Leaving_Group -O-P(=NTs)-Ph2
Title Oligosaccharide synthesis based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups
Citation Tetrahedron Lett. 1997, 38, 5181
DOI 10.1016/S0040-4039(97)01122-2
PROM-199
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title C-glucosylarenes from O-??-d-glucosyl trichloroacetimidates. Structure of bergenin derivatives
Citation Carbohydr. Res. 1987, 171, 59
DOI 10.1016/S0008-6215(00)90879-6
PROM-2
Promoter TMSOTf
Leaving_Group SnBu3
Title A New Method for the Synthesis of Stannyl Ethers by Acid-Catalyzed Reaction of Alcohols with Allyltributylstannane
Citation Chem Lett. 2002, 152
DOI 10.1246/cl.2002.152
PROM-20
Promoter TMSOTf
Leaving_Group SR (R= ?)
Title Stereoselective synthesis of 2-S-ethyl(phenyl)-2-thio-??-glucopyranosides via 1,2-migration and concurrent glycosidation of ethyl(phenyl) 2,3-orthoester-1-thio-??-mannopyranosides
Citation Carbohydr. Res. 2001, 333, 105
DOI 10.1016/S0008-6215(01)00124-0
PROM-200
Promoter BF3?EEt2O
Leaving_Group -O-C(=NH)-CF3
Title Allyl, epoxy and glycosyl perfluoroimidates. One-pot preparation and reaction
Citation Tetrahedron. 2002, 58, 3579
DOI 10.1016/S0040-4020(02)00305-8
PROM-201
Promoter BF3?EEt2O
Leaving_Group -O-P(=NPh)(NiPr2)(OEt)
Title Glycosyl Phosphoramidimidates as Versatile Glycosyl Donors
Citation Heterocycles 1997, 45, 1247
DOI 10.3987/COM-96-7466
PROM-202
Promoter BF3?EEt2O
Leaving_Group -O-P-(NiPr2)(OEt)
Title Glycosidation of Glycosyl Phosphoramidites
Citation Heterocycles 1998, 48, 21
DOI 10.3987/COM-97-8009
PROM-2026
Promoter Pd compound
Leaving_Group tributylstannyl
Title Formation of C-glycosides by a palladium-catalysed coupling reaction of tributylstannyl glycals with organic halides
Citation J. Chem. Soc., Chem. Commun. 1990, 1191
DOI 10.1039/C39900001191
PROM-2027
Promoter palladium(0)
Leaving_Group tributylstannyl
Title Synthesis of C-glycopyranosyl compounds by a palladium-catalyzed coupling reaction of 1-tributylstannyl-d-glucals with organic halides
Citation Carbohydr. Res. 1992, 228, 103
DOI 10.1016/S0008-6215(00)90552-4
PROM-203
Promoter BF3?EEt2O
Leaving_Group -O-P--(OEt)2
Title An extremely mild and stereocontrolled construction of 1,2-trans-??-glycosidic linkages capitalizing on benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors
Citation Tetrahedron Lett. 1995, 36, 2251
DOI 10.1016/0040-4039(95)00263-C
PROM-204
Promoter BF3?EEt2O
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.969
PROM-205
Promoter BF3?EEt2O
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1021/ja804589j
PROM-206
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title O-(??-D-Glucopyranosyl)trichloroacetimidate as a Glucosyl Donor
Citation J. Carbohydr. Chem. 1985, 4, 141
DOI 10.1080/07328308508058829
PROM-207
Promoter BF3?EEt2O
Leaving_Group F
Title Highly stereoselective C-??-d-ribofuranosylation. Reactions of d-ribofuranosyl fluoride derivatives with enol trimethylsilyl ethers and with allyltrimethylsilane
Citation Carbohydr. Res. 1987, 171, 125
DOI 10.1016/S0008-6215(00)90883-8
PROM-208
Promoter BF3?EEt2O
Leaving_Group F
Title A novel procedure for C-glycosylation involving Lewis acid-catalyzed coupling-reactions of glycosyl fluorides with enol trimethylsilyl ethers
Citation Carbohydr. Res. 1984, 127, C5
DOI 10.1016/0008-6215(84)85121-6
PROM-209
Promoter BF3?EEt2O
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1055/s-1992-21464
PROM-21
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Glycosylation in Ionic Liquids
Citation Synthesis 2003, 2074
DOI 10.1055/s-2003-41446
PROM-210
Promoter BF3?EEt2O
Leaving_Group SR (R = ?)
Title Synthesis of 1,2-trans-related 1-thioglycoside esters
Citation Carbohydr. Res. 1976, 52, 63
DOI 10.1016/S0008-6215(00)85946-7
PROM-211
Promoter BF3?EEt2O
Leaving_Group SR (R = ?)
Title The application of phenylmethanethiol and benzenethiol derivatives as odorless organosulfur reagents in the synthesis of thiosugars and thioglycosides
Citation Carbohydr. Res. 2005, 340, 2360
DOI 10.1016/j.carres.2005.07.011
PROM-212
Promoter BF3?EEt2O
Leaving_Group SR (R = ?)
Title One-pot synthesis of per-O-acetylated thioglycosides from unprotected reducing sugars
Citation Carbohydr. Res. 2005, 340, 1393
DOI 10.1016/j.carres.2005.02.027
PROM-213
Promoter BF3?EEt2O
Leaving_Group SEt
Title Benzoylated ethyl 1-thioglycosides: direct preparation from per-O-benzoylated sugars
Citation Carbohydr. Res. 2012, 357, 47
DOI 10.1016/j.carres.2012.05.012
PROM-214
Promoter BF3?EEt2O
Leaving_Group SEt
Title An improved method for the preparation of some ethyl 1-thioglycosides
Citation Carbohydr. Res. 1996, 296, 275
DOI 10.1016/S0008-6215(96)00235-2
PROM-215
Promoter BF3?EEt2O
Leaving_Group OAc
Title Thioglycosylation of 1,2-cis-glycosyl acetates: a long-standing overlooked issue in preparative carbohydrate chemistry
Citation Carbohydr. Res. 2011, 346, 1149
DOI 10.1016/j.carres.2011.03.033
PROM-216
Promoter BF3?EEt2O
Leaving_Group OAc
Title The application of phenylmethanethiol and benzenethiol derivatives as odorless organosulfur reagents in the synthesis of thiosugars and thioglycosides
Citation Carbohydr. Res. 2005, 340, 2360
DOI 10.1016/j.carres.2005.07.011
PROM-217
Promoter BF3?EEt2O
Leaving_Group OAc
Title A Novel Stereoselective Synthesis of S-Glycosyl Phosphorodithioates from Peracetylated Sugars
Citation Synthesis. 1995, 1539
DOI 10.1055/s-1995-4435
PROM-219
Promoter BF3?EEt2O
Leaving_Group F
Title O??C-Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl C-Glycosides
Citation Synlett. 1991, 709
DOI 10.1055/s-1991-34769
PROM-22
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Stereoselective O-glycosylation reactions employing diphenylphosphinate and propane-1,3-diyl phosphate as anomeric leaving groups
Citation Chem. Commun. 1998, 2129
DOI 10.1039/A805206I
PROM-220
Promoter BF3?EEt2O
Leaving_Group OAc
Title C-Glycosylation Reactions of Sulfur-Substituted Glycosyl Donors: Evidence against the Role of Neighboring-Group Participation
Citation J. Am. Chem. Soc. 2008, 130, 2082
DOI 10.1021/ja0767783
PROM-221
Promoter BF3?EEt2O
Leaving_Group N-(4-methoxyphenyl)-trifluoroacetimidate
Title A facile synthesis of isoflavone 7-O-glucuronides
Citation Tetrahedron Lett. 2006, 47, 8703
DOI 10.1016/j.tetlet.2006.10.034
PROM-222
Promoter BF3?EEt2O
Leaving_Group ?
Title Use of Polystyrene-Supported DBU in the Synthesis and ??-Selective Glycosylation Study of the Unstable Schmidt Donor of l-Kedarosamine
Citation Org. Lett. 2004, 6, 719
DOI 10.1021/ol036353v
PROM-223
Promoter BF3?EEt2O
Leaving_Group trichloroacetimidate
Title On-Resin Real-Time Reaction Monitoring of Solid-Phase Oligosaccharide Synthesis
Citation J. Am. Chem. Soc. 2002, 124, 12638
DOI 10.1021/ja020781z
PROM-224
Promoter BF3?EEt2O
Leaving_Group ?
Title A simple and ready internal C-glycosylation of 2,3,5-tri-O-benzylglycofuranoses promoted by the boron trifluoride-diethyl ether complex
Citation Carbohydr. Res. 1990, 208, 264
DOI 10.1016/0008-6215(90)80108-F
PROM-225
Promoter BF3?EEt2O
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97693-7
PROM-227
Promoter BF3?EEt2O
Leaving_Group F
Title Structural elucidation and a novel reductive cleavage of ribofuranosyl ring C-1 - O bond of the intramolecular-C-arylation? product of tri-O-benzyl-??-D-ribofuranosyl fluoride
Citation Tetrahedron Lett. 1989, 30, 1115
DOI 10.1016/S0040-4039(01)80374-9
PROM-228
Promoter BF3?EEt2O
Leaving_Group OH, OAc, -C(NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja801008m
PROM-229
Promoter BF3?EEt2O
Leaving_Group ?
Title Synthesis of bergenin-type C-glucosylarenes
Citation Carbohydr. Res. 1991, 209, 101
DOI 10.1016/0008-6215(91)80148-G
PROM-23
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Glycosylation Based on Glycosyl Phosphates as Glycosyl Donors
Citation Synlett 2002, 16
DOI 10.1055/s-2002-19315
PROM-231
Promoter BF3?EEt2O
Leaving_Group SEt, trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1016/j.carres.2008.08.025
PROM-232
Promoter BF3?EEt2O
Leaving_Group Br
Title daburi
Citation daburi
DOI 10.1016/0008-6215(87)80138-6
PROM-233
Promoter BF3?EEt2O
Leaving_Group trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1021/ja9055245
PROM-234
Promoter BF3?EEt2O
Leaving_Group trichloroimidate
Title Structure Assignment, Total Synthesis, and Antiviral Evaluation of Cycloviracin B1
Citation J. Am. Chem. Soc. 2003, 125, 13132
DOI 10.1021/ja036521e
PROM-236
Promoter BF3?EEt2O
Leaving_Group -OC(=NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja980588y
PROM-237
Promoter I2
Leaving_Group PhS(O)-, SePh
Title Observations on Iodine-promoted ??-Mannosylation
Citation Synlett. 2003, 1376
DOI 10.1055/s-2003-40346
PROM-238
Promoter I2
Leaving_Group SMe
Title Iodine: A versatile reagent in carbohydrate chemistry II. Efficient chemospecific activation of thiomethylglycosides
Citation Tetrahedron Lett. 1996, 37, 5175
DOI 10.1016/0040-4039(96)01029-5
PROM-239
Promoter I2
Leaving_Group SR (R = ?)
Title Iodine and its Interhalogen Compounds: Versatile Reagents in Carbohydrate Chemistry XII. Tuning Promoter Reactivity for Thioglycoside Activation
Citation Synlett 2000, 1279
DOI 10.1055/s-2000-7152
PROM-24
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Stereoselective O-glycosylation reactions using glycosyl donors with diphenylphosphinate and propane-1,3-diyl phosphate leaving groups
Citation Tetrahedron: Asymmetry 2001,12, 1373
DOI 10.1016/S0957-4166(01)00227-0
PROM-240
Promoter I2
Leaving_Group SR (R = ?)
Title Glycosylation with in situ separation: carbohydrate chemistry on a TLC plate
Citation Org. Biomol. Chem. 2005, 3, 3468
DOI 10.1039/B509417H
PROM-241
Promoter I2
Leaving_Group trichloroimidate, -O-P-(OEt)2, 4-pentenyl Glycoside, 1,2-orthoester
Title Iodine and its Interhalogen Compounds: Versatile Reagents in Carbohydrate Chemistry XIII. General Activation of `Armed' Glycosyl Donors
Citation Synlett. 2001, 260
DOI 10.1055/s-2001-10771
PROM-242
Promoter I2
Leaving_Group SMe, Br
Title Iodine and its interhalogen compounds: versatile reagents in carbohydrate chemistry. XIV. Glycosylated amino acid synthesis
Citation J. Chem. Soc. Perkin Trans. 1 2001, 770
DOI 10.1039/B009682M
PROM-243
Promoter I2
Leaving_Group I
Title Iodine Promoted Glycosylation with Glycosyl Iodides: ???]Glycoside Synthesis
Citation J. Carbohydr. Chem. 2005, 24, 463
DOI 10.1081/CAR-200067028
PROM-244
Promoter I2
Leaving_Group SMe
Title Observations on the activation of methyl thioglycosides by iodine and its interhalogen compounds?
Citation Tetrahedron: Asymmetry 2000, 11, 581
DOI 10.1016/S0957-4166(99)00501-7
PROM-245
Promoter I2
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-246
Promoter I2
Leaving_Group I
Title Two-Step Functionalization of Oligosaccharides Using Glycosyl Iodide and Trimethylene Oxide
Citation Chem. - Eur. J. 2014, 20, 6444
DOI 10.1002/chem.201400024
PROM-247
Promoter Br2
Leaving_Group SEt
Title SYNTHESES OF ISOMALTOSE, ISOMALTOTETRAOSE, AND ISOMALTOOCTAOSE
Citation Chem Lett. 1972, 1049
DOI 10.1246/cl.1972.1049
PROM-248
Promoter Br2
Leaving_Group SEt
Title Glycosidation of Thioglycosides in the Presence of Bromine: Mechanism, Reactivity, and Stereoselectivity
Citation J. Org. Chem. 2012, 77, 291
DOI 10.1021/jo2019174
PROM-249
Promoter Br2
Leaving_Group SEt
Title SYNTHESES OF ISOMALTOSE, ISOMALTOTETRAOSE, AND ISOMALTOOCTAOSE
Citation Chem Lett. 1972, 1049
DOI 10.1246/cl.1972.1049
PROM-25
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title A new glycosylation strategy for the synthesis of mannopyranosides
Citation Tetrahedron: Asymmetry 2000,11, 125
DOI 10.1016/S0957-4166(99)00487-5
PROM-250
Promoter NBS
Leaving_Group SPh, SPy
Title Chemistry of the glycosidic linkage. Exceptionally fast and efficient formation of glycosides by remote activation
Citation Carbohydr. Res. 1980, 80, C17
DOI 10.1016/S0008-6215(00)84882-X
PROM-251
Promoter NBS
Leaving_Group SPh
Title A mild and general method for the synthesis of 0-glycosides
Citation J. Am. Chem. Soc. 1983, 105, 2430
DOI 10.1021/ja00346a053
PROM-252
Promoter NBS
Leaving_Group SPh
Title A highly stereoselective synthesis of the AB disaccharide unit of olivomycin A
Citation J. Org. Chem. 1991, 56, 1649
DOI 10.1021/jo00004a054
PROM-253
Promoter NBS
Leaving_Group SPh
Title Highly stereoselective glycosylation by conformational assistance of glycosyl donor
Citation Tetrahedron Lett. 1991, 32, 6887
DOI 10.1016/0040-4039(91)80435-9
PROM-254
Promoter NBS
Leaving_Group SPh
Title Rhamnosylation Reaction with a Phenyl 1-Thiorhamnoside and a Rhamnosyl Fluoride Which Have 4C1 Conformation
Citation Chem. Lett. 2000, 432
DOI 10.1246/cl.2000.432
PROM-255
Promoter NBS
Leaving_Group SR (R = ?)
Title A stereoselective glycosidation using thioglycosides, activation by combination of N-bromosuccinimide and strong acid salts
Citation Tetrahedron 1995, 51, 4923
DOI 10.1016/0040-4020(95)98690-J
PROM-256
Promoter NBS
Leaving_Group 4-pentenyl Glycoside
Title n-Pentenyl glycosides permit the chemospecific liberation of the anomeric center
Citation J. Am. Chem. Soc. 1988,110, 2662
DOI 10.1021/ja00216a057
PROM-257
Promoter NBS
Leaving_Group SPh
Title Total Synthesis and Absolute Configuration of Polycavernoside A
Citation J. Am. Chem. Soc. 1998, 120, 10770
DOI 10.1021/ja982431b
PROM-258
Promoter NBS
Leaving_Group SPh
Title The use of 2,6-anhydro-2-thio sugar for a highly stereocontrolled glycosylation: A novel strategy for synthesis of 2,6-dideoxy-??-glycosides
Citation Tetrahedron Lett. 1990, 31, 333
DOI 10.1016/S0040-4039(00)89059-0
PROM-26
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Stereoselective synthesis of ??-L-Fucp-(1,2)- and -(1,3)-??-D-Galp(1)-4-methylumbelliferone using glycosyl donor substituted by propane-1,3-diyl phosphate as leaving group
Citation J. Chem. Soc., Perkin Trans 2000,1, 2187
DOI 10.1039/B002754P
PROM-260
Promoter NBS
Leaving_Group SPh
Title Polycavernoside A: The Prins Macrocyclization Approach
Citation J. Am. Chem. Soc. 2010, 132, 4564
DOI 10.1021/ja1009579
PROM-261
Promoter NBS
Leaving_Group SPh
Title Total Synthesis of the Marine Toxin Polycavernoside A via Selective Macrolactonization of a Trihydroxy Carboxylic Acid
Citation J. Am. Chem. Soc. 2001, 123, 8593
DOI 10.1021/ja011256n
PROM-262
Promoter NIS
Leaving_Group SEt
Title Erosion of Stereochemical Control with Increasing Nucleophilicity: O-Glycosylation at the Diffusion Limit
Citation J. Org. Chem. 2010, 75, 1107
DOI 10.1021/jo902222a
PROM-263
Promoter NIS
Leaving_Group Br or Cl
Title Glucuronidation of alcohols using the bromosugar_iodonium reagent method
Citation Tetrahedron Lett. 2001. 42, 6611
DOI 10.1016/S0040-4039(01)01333-8
PROM-264
Promoter NIS
Leaving_Group SePh
Title Synthesis of Kojitriose using Silicon-Tethered Glycosidation.
Citation Acta Chem. Scand. 1996, 50, 931
DOI 10.3891/acta.chem.scand.50-0931
PROM-265
Promoter NIS
Leaving_Group -S-P(=S)-(OEt)2
Title Convenient Iodonium-Promoted Stereoselective Synthesis of 2-Deoxy-??-glycosides by Use of S-(2-Deoxyglycosyl) Phosphorodithioates as Donors
Citation Synthesis 1992, 1133
DOI 10.1055/s-1992-26321
PROM-266
Promoter NIS
Leaving_Group allyl glycoside
Title Simple Glycosylation Reaction of Allyl Glycosides
Citation J. Org. Chem. 2007, 72,?5870
DOI 10.1021/jo070512x
PROM-267
Promoter NIS
Leaving_Group -O-C(=NPh)-CF3
Title A Versatile Strategy for the Synthesis of N-Acetyl-bacillosamine-Containing Disaccharide Building Blocks Related to Bacterial O-Antigens
Citation Synlett 2006, 825
DOI 10.1055/s-2006-939057
PROM-268
Promoter NIS
Leaving_Group I, trichloroacetimidate
Title Glucuronidation of steroidal alcohols using iodosugar and imidate donors
Citation Org. Biomol. Chem. 2005, 3, 1501
DOI 10.1039/B412217H
PROM-269
Promoter NIS
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-27
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OCH2)2CH
Title Synthesis of d-arabinofuranosides using propane-1,3-diyl phosphate as the anomeric leaving group
Citation Tetrahedron Lett. 2001, 42, 6615
DOI 10.1016/S0040-4039(01)01327-2
PROM-271
Promoter NIS
Leaving_Group ?
Title Double Asymmetric Induction During Intramolecular Glycosylation
Citation Eur. J. Org. Chem. 1998, 1998, 163
DOI 10.1002/(SICI)1099-0690(199801)1998:1<163::AID-EJOC163>3.0.CO;2-I
PROM-272
Promoter NIS
Leaving_Group SPh
Title Intramolecular glycosylation of prearranged glycosides part 5. ??-(1??4)-Selective glucosylation of glucosides and glucosamines
Citation Tetrahedron Lett. 1997, 38, 3715
DOI 10.1016/S0040-4039(97)00729-6
PROM-273
Promoter NIS
Leaving_Group ?
Title Steroselective Synthesis of ??-Glucosides and ??-Mannosides: Tethering and Activation with N-Iodosuccinimide
Citation Synlett, 1999, 1387
DOI 10.1055/s-1999-2855
PROM-274
Promoter NIS
Leaving_Group SPh
Title Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters
Citation Carbohydr. Res. 2010, 345, 45
DOI 10.1016/j.carres.2009.09.034
PROM-275
Promoter NIS
Leaving_Group ?
Title Studies of Hexuronic Acid Ester Glycals and the Synthesis of 2-Deoxy-??-glycoside Precursors
Citation J. Carbohydr. Chem. 1984, 3, 287
DOI 10.1080/07328308408058822
PROM-276
Promoter NIS
Leaving_Group n-pentenyl glycoside
Title Highly efficient preparation of tumor antigen-containing glycopeptide building blocks from novel pentenyl glycosides
Citation Carbohydr. Res. 2003, 338, 1925
DOI 10.1016/S0008-6215(03)00323-9
PROM-277
Promoter NIS
Leaving_Group trichloroacetimidates, thioglycosides
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(99)01839-0
PROM-279
Promoter MeI
Leaving_Group Spy
Title A mild general method for the synthesis of ??-linked disaccharides
Citation Tetrahedron Lett. 1989, 30, 4283
DOI 10.1016/S0040-4039(01)80711-5
PROM-28
Promoter TMSOTf
Leaving_Group -O-P-(OEt)2
Title Efficient sialylation with phosphite as leaving group
Citation Tetrahedron Lett. 1992, 33, 6123
DOI 10.1016/S0040-4039(00)60022-9
PROM-280
Promoter MeI
Leaving_Group Spy
Title A mild general method for the synthesis of ??-2-deoxy-disaccharides: Synthesis of L-oleandrosyl-L-oleandrose from D-glucose
Citation Tetrahedron Lett. 1989, 30, 4287
DOI 10.1016/S0040-4039(01)80712-7
PROM-281
Promoter MeI
Leaving_Group Spy
Title Stereoselective synthesis of ??-linked saccharides by use of per O-benzylated 2-pyridyl 1-thio hexopyranosides as glycosyl donors and methyl iodide as an activator
Citation Tetrahedron 1991, 47, 6435
DOI 10.1016/S0040-4020(01)86571-6
PROM-282
Promoter MeI
Leaving_Group Spy
Title Directed, iterative, stereoselective synthesis of oligosaccharides by use of suitably 2-O-substituted 2-pyridyl 1-thioglycopyranosides on activation by methyl iodide
Citation Tetrahedron 1991, 47, 9721
DOI 10.1016/S0040-4020(01)91035-X
PROM-283
Promoter MeI
Leaving_Group Spy
Title Stereoselective synthesis of ??-linked 2-deoxysaccharides and furanosaccharides by use of 2-deoxy 2-pyridyl-1-thio pyrano- and furanosides as donors and methyl iodide as an activator
Citation Tetrahedron 1992, 48, 545
DOI 10.1016/S0040-4020(01)89016-5
PROM-284
Promoter MeI
Leaving_Group Spy
Title Stereoselective synthesis of ??-O-fucosylated serine, threonine, tyrosine and saccharides
Citation J. Chem. Soc., Perkin Trans. 1, 1997, 3179
DOI 10.1039/A704310D
PROM-285
Promoter MeI
Leaving_Group S-Box? (S-benzoxazolyl)
Title A Highly Stereoselective Synthesis of ??-Glucosides from 1-Thioglucoside Derivative under High Pressure
Citation Chem. Lett. 1993, 319
DOI 10.1246/cl.1993.319
PROM-286
Promoter MeI
Leaving_Group Spy
Title Stereoselective synthesis of ??-linked 2-deoxysaccharides and furanosaccharides by use of 2-deoxy 2-pyridyl-1-thio pyrano- and furanosides as donors and methyl iodide as an activator
Citation Tetrahedron. 1992. 48, 545
DOI 10.1016/S0040-4020(01)89016-5
PROM-287
Promoter MeI
Leaving_Group Spy
Title A mild general method for the synthesis of ??-linked disaccharides
Citation Tetrahedron Lett. 1989, 30, 4283
DOI 10.1016/S0040-4039(01)80711-5
PROM-288
Promoter MeI
Leaving_Group ?
Title Use of 2-pyridyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-1-thio-??-d-glucopyranoside as a glycosyl donor and methyl iodide as an activator for the synthesis of 1,2-trans-linked saccharides
Citation Carbohydr. Res. 1993, 242, 277
DOI 10.1016/0008-6215(93)80041-C
PROM-289
Promoter MeI
Leaving_Group Spy
Title A novel, iterative, stereoselective route to the synthesis of axially linked 2-deoxysaccharides
Citation Tetrahedron Lett. 1991, 32, 7317
DOI 10.1016/0040-4039(91)80508-4
PROM-29
Promoter TMSOTf
Leaving_Group -O-P-(OEt)2
Title An Attempt at the Direct Construction of 2-Deoxy-??-glycosidic Linkages Capitalizing on 2-Deoxyglycopyranosyl Diethyl Phosphites as Glycosyl Donors
Citation Synlett. 1995, 1271
DOI 10.1055/s-1995-5254
PROM-290
Promoter DMTST
Leaving_Group SMe, SEt, SPh
Title A novel promoter for the efficient construction of 1,2-trans linkages in glycoside synthesis, using thioglycosides as glycosyl donors
Citation Carbohydr. Res. 1986, 149, C9
DOI 10.1016/S0008-6215(00)90385-9
PROM-291
Promoter DMTST
Leaving_Group SMe
Title Synthetic Studies on Sialoglycoconjugates. 5: A Facile, Regio and Stereoselective Synthesis of Ganglioside GM4 and Its Position Isomer1
Citation J. Carbohydr. Chem. 1989, 8, 265
DOI 10.1080/07328308908048009
PROM-292
Promoter DMTST
Leaving_Group SMe
Title A facile total synthesis of ganglioside GM1b and its positional analog
Citation Carbohydr. Res. 1991, 211, C1
DOI 10.1016/0008-6215(91)80105-V
PROM-293
Promoter DMTST
Leaving_Group SMe
Title Total synthesis of sialyl Lewis X
Citation Carbohydr. Res. 1991, 209, C1
DOI 10.1016/0008-6215(91)80171-I
PROM-294
Promoter DMTST
Leaving_Group SMe
Title Glycosylation Using Methylthioglycosides of N-Acetylneuraminic Acid and Dimethyl(Methylthio)Sulfonium Triflate
Citation J. Carbohydr. Chem. 1988, 7, 501
DOI 10.1080/07328308808058938
PROM-295
Promoter DMTST
Leaving_Group SMe
Title Synthetic Studies on Sialoglycoconjugates 16: ??-Predominant Glycoside Synthesis of N-Acetylneuraminic Acid With the Primary Hydroxyl Group in Carbohydrates Using Dimethyl(Methylthio)Sulfonium Triflate as a Glycosyl Promoter
Citation J. Carbohydr. Chem. 1990, 9, 393
DOI 10.1080/07328309008543841
PROM-296
Promoter DMTST
Leaving_Group SMe
Title A facile regio- and stereo-selective synthesis of ??-glycosides of N-acetylneuraminic acid
Citation Carbohydr. Res. 1988, 184, C1
DOI 10.1016/0008-6215(88)80035-1
PROM-297
Promoter DMTST
Leaving_Group SMe
Title A facile, regio- and stereo-selective synthesis of ganglioside GM 3
Citation Carbohydr. Res. 1989, 188, 71
DOI 10.1016/0008-6215(89)84060-1
PROM-298
Promoter DMTST
Leaving_Group SEt
Title Chemical Syntheses of Inulin and Levan Structures
Citation J. Org. Chem. 2002, 67, 8457
DOI 10.1021/jo020341q
PROM-299
Promoter DMTST
Leaving_Group SEt
Title Synthesis of d-Fructofuranosides Using Thioglycosides as Glycosyl Donors
Citation Tetrahedron 2004, 60, 1057
DOI 10.1021/jo951641t
PROM-3
Promoter TMSOTf
Leaving_Group 3-Nitro-2-pyridyl (3NPy) glycosides
Title 3-Nitro-2-pyridyl glycoside as donor for chemical glycosylation and its application to chemoenzymatic synthesis of oligosaccharide
Citation Tetrahedron Lett. 1999, 40, 6591
DOI 10.1016/S0040-4039(99)01280-0
PROM-30
Promoter TMSOTf
Leaving_Group -O-P-(OEt)2
Title Direct and Stereoselective Construction of ??-Mannosidic Linkages Capitalizing on 4,6-O-Benzylidene-protected D-Mannopyranosyl Diethyl Phosphite
Citation Heterocycles 2003, 59, 509
DOI 10.3987/COM-02-S80
PROM-300
Promoter DMTST
Leaving_Group S-Ph-pX (X=EDG; H, Me, OMe, NHAc)
Title ?gActive?h and ?glatent?h thioglycosyl donors in oligosaccharide synthesis. Application to the synthesis of ??-sialosides
Citation Tetrahedron Lett. 1992, 33, 6053
DOI 10.1016/S0040-4039(00)60004-7
PROM-301
Promoter DMTST
Leaving_Group isopropenyl, n-pentenyl ?glycoside
Title daburi
Citation daburi
DOI 10.1016/0040-4039(94)88449-8
PROM-302
Promoter DMTST
Leaving_Group -S-C(S)-OEt
Title daburi
Citation daburi
DOI 10.1351/pac199163040519
PROM-303
Promoter DMTST
Leaving_Group -S-C(S)-OEt
Title daburi
Citation daburi
DOI 10.1016/S0040-4020(01)87127-1
PROM-304
Promoter DMTST
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-305
Promoter DMTST
Leaving_Group SEt
Title Effect of Remote Picolinyl and Picoloyl Substituents on the Stereoselectivity of Chemical Glycosylation
Citation J. Am. Chem. Soc. 2012, 134, 20097
DOI 10.1021/ja307355n
PROM-306
Promoter DMTST
Leaving_Group OH
Title A General and Highly Efficient Solid Phase Synthesis of Oligosaccharides. otal Synthesis of a Heptasaccharide Phytoalexin Elicitor (HPE)
Citation J. Am. Chem. Soc. 1997, 119, 449
DOI 10.1021/ja963482g
PROM-307
Promoter DMTST
Leaving_Group ?
Title Synthetic Studies on Sialoglycoconjugates 22: Total Synthesis of Tumor-Associated Ganglioside, Sialyl Lewis X1
Citation J. Carbohydr. Chem. 1991, 10, 549
DOI 10.1080/07328309108543931
PROM-308
Promoter DMTST
Leaving_Group ?
Title Synthetic Studies on Sialoglycoconjugates 25: Reactivity of Glycosyl Promoters in ??-Glycosylation of N-Acetyl-Neuraminic Acid with the Primary and Secondary Hydroxyl Groups in the Suitably Protected Galactose and Lactose Derivatives
Citation J. Carbohydr. Chem. 1991, 10, 493
DOI 10.1080/07328309108543925
PROM-309
Promoter DMTST
Leaving_Group SMe, F
Title Wang Resin-Type Linker Containing a Nitro Group for Polymer Support Oligosaccharide Synthesis: Polymer-Supported Glycosyl Donor
Citation Chem. Pharm. Bull. 2001, 49, 1234
DOI 10.1248/cpb.49.1234
PROM-31
Promoter TMSOTf
Leaving_Group -O-P-(OEt)2
Title Direct and stereoselective synthesis of ??-d-mannosides using 4,6-O-benzylidene-protected mannosyl diethyl phosphite as a donor
Citation Tetrahedron 2005, 61, 10719
DOI 10.1016/j.tet.2005.08.090
PROM-310
Promoter DMTST
Leaving_Group ?
Title Synthesis of colitose-containing oligosaccharide structures found in polysaccharides from Vibrio cholerae O139 synonym Bengal using thioglycoside donors
Citation Carbohydr. Res. 1997, 299, 159
DOI 10.1016/S0008-6215(97)00003-7
PROM-312
Promoter DMTST
Leaving_Group SEt
Title daburi
Citation daburi
DOI 10.1055/s-1997-5767
PROM-313
Promoter DMTST
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1021/ja982232s
PROM-314
Promoter DMTST
Leaving_Group ?
Title Synthetic Studies on Sialoglycoconjugates. 5: A Facile, Regio and Stereoselective Synthesis of Ganglioside GM4 and Its Position Isomer
Citation J. Carbohydr. Chem. 1989, 8, 265
DOI 10.1080/07328308908048009
PROM-315
Promoter DMTST
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0008-6215(99)00080-4
PROM-316
Promoter DMTST
Leaving_Group SEt, SPh, STol, S/O-imidates
Title Hydrogen-Bond-Mediated Aglycone Delivery (HAD): A Highly Stereoselective Synthesis of 1,2-cis ??-D-Glucosides from Common Glycosyl Donors in the Presence of Bromine
Citation Chem._Eur. J. 2015, 21
DOI 10.1002/chem.201406589
PROM-317
Promoter DTBMP
Leaving_Group 2'-caboxybenzyl glycoside
Title Glycosylation with 2??-Carboxybenzyl Glycosides as Glycosyl Donors: Scope and Application to the Synthesis of a Tetrasaccharide
Citation Synlett. 2003, 1311
DOI 10.1055/s-2003-40348
PROM-318
Promoter DTBMP
Leaving_Group PhS(O)-, F
Title daburi
Citation daburi
DOI 10.1021/ja030496v
PROM-319
Promoter SiF4
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(01)80163-5
PROM-32
Promoter TMSOTf
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97191-0
PROM-320
Promoter SiF4
Leaving_Group F
Title Condensation of 1-Fluorofuranoses and Silylated Nucleobases Catalyzed by Tetrafluorosilane
Citation Chem. Lett. 1987, 57
DOI 10.1246/cl.1987.57
PROM-321
Promoter IDCP
Leaving_Group SEt
Title An efficient thioglycoside-mediated formation of ??-glycosidic linkages promoted by iodonium dicollidine perchlorate
Citation Tetrahedron Lett. 1990. 31, 275
DOI 10.1016/S0040-4039(00)94391-0
PROM-322
Promoter IDCP
Leaving_Group SEt
Title Iodonium-Ion Assisted Stereospecific Glycosylation: Synthesis of Oligosaccharides Containing ??(1-4)-Linked L-Fucopyranosyl Units
Citation J. Carbohydr. Chem. 1991, 10, 833
DOI 10.1080/07328309108543953
PROM-323
Promoter IDCP
Leaving_Group SEt
Title Dispiroketals in synthesis (Part 5): A new opportunity for oligosaccharide synthesis using differentially activated glycosyl donors and acceptors
Citation Tetrahedron Lett. 1993, 34, 8523
DOI 10.1016/S0040-4039(00)61375-8
PROM-324
Promoter IDCP
Leaving_Group 4-pentenyl Glycoside
Title Direct elaboration of pent-4-enyl glycosides into disaccharides
Citation J. Chem. Soc., Chem. Commun. 1988, 823
DOI 10.1039/C39880000823
PROM-325
Promoter IDCP
Leaving_Group -S-P(=S)-(OEt)2
Title daburi
Citation daburi
DOI 10.1055/s-1992-26321
PROM-326
Promoter IDCP
Leaving_Group SePh
Title Iodonium ion-mediated glycosidations of phenyl selenoglycosides
Citation Trav. Chim. Pays-Bas 1992, 111, 365
DOI 10.1002/recl.19921110706
PROM-327
Promoter IDCP
Leaving_Group SePh
Title Iodonium-Promoted Glycosylations with Phenyl Selenoglycosides
Citation J. Carbohydr. Chem. 1993, 12, 1091
DOI 10.1080/07328309308020119
PROM-328
Promoter IDCP
Leaving_Group isopropenyl glycoside
Title daburi
Citation daburi
DOI 10.1021/jo960190p
PROM-329
Promoter IDCP
Leaving_Group SEt, dicyclohexylmethyl thioglycosides
Title Chemoselective Glycosylations. 2. Differences in Size of Anomeric Leaving Groups Can Be Exploited in Chemoselective Glycosylations
Citation J. Org. Chem. 1997, 62, 8145
DOI 10.1021/jo971233k
PROM-33
Promoter TMSOTf
Leaving_Group -O-P-(OBn)2
Title .beta.-Sialyl phosphite and phosphoramidite: synthesis and application to the chemoenzymic synthesis of CMP-sialic acid and sialyl oligosaccharides
Citation J. Am. Chem. Soc. 1992, 114, 8748
DOI 10.1021/ja00048a085
PROM-330
Promoter IDCP
Leaving_Group SEt
Title Solvent and Other Effects on the Stereoselectivity of Thioglycoside Glycosidations
Citation Synlett, 1997, 818
DOI 10.1055/s-1997-5762
PROM-331
Promoter IDCP
Leaving_Group Sp-NOPh
Title Use of 4-Nitrophenylthio-_-D-Glycosides in Oligosaccharide Synthesis: A Critical Evaluation
Citation Synlett. 1993, 335
DOI 10.1055/s-1993-22445
PROM-332
Promoter IDCP
Leaving_Group n-pentenyl, SEt
Title Further Insight into ?eMatching?f of Donors and Acceptors via Reciprocal _Donor Acceptor Selectivity (RDAS) Studies
Citation Synlett 2003, 2203
DOI 10.1055/s-2003-42075
PROM-333
Promoter IDCP
Leaving_Group SEt
Title daburi
Citation daburi
DOI daburi
PROM-335
Promoter DAST
Leaving_Group 1-Hydoroxy Sugar
Title A new method for the synthesis of glycosyl fluorides
Citation Tetrahedron Lett. 1985, 26, 3
DOI 10.1016/S0040-4039(00)98450-8
PROM-336
Promoter DAST
Leaving_Group 1-Hydoroxy Sugar
Title A convenient, one-step, high-yield replacement of an anomeric hydroxyl group by a fluorine atom using dast. Preparation of glycosyl fluorides
Citation Tetrahedron Lett. 1985, 26, 5
DOI 10.1016/S0040-4039(00)98451-X
PROM-337
Promoter MeSOTf
Leaving_Group SMe, SEt, SPh
Title Alkyl sulfenyl triflate as activator in the thioglycoside-mediated formation of ??-glycosidic linkages during oligosaccharide synthesis
Citation Carbohydr. Res. 1988, 177, C13
DOI 10.1016/0008-6215(88)85071-7
PROM-338
Promoter NOBF4
Leaving_Group SMe
Title A new method for the synthesis of O-glycosides from S-glycosides
Citation J. Org. Chem. 1987, 52, 4635
DOI 10.1021/jo00229a047
PROM-339
Promoter TrB(C6F5)4 (cat)
Leaving_Group F
Title Trityl Tetrakis(pentafluorophenyl)borate Catalyzed Stereoselective Glycosylation Using Glycopyranosyl Fluoride as a Glycosyl Donor
Citation Chem Lett. 1998, 555
DOI 10.1246/cl.1998.555
PROM-34
Promoter TMSOTf
Leaving_Group -O-P-(OBn)2
Title Synthesis of Sialyl Lewis X Mimetics and Related Structures Using the Glycosyl Phosphite Methodology and Evaluation of E-Selectin Inhibition
Citation J. Am. Chem. Soc. 1996, 118, 6826
DOI 10.1021/ja952265x
PROM-340
Promoter TrB(C6F5)4 (cat)
Leaving_Group OH
Title Trityl Salt Catalyzed Stereoselective Glycosylation of Alcohols with 1-Hydroxyribofuranose
Citation Chem Lett. 1996, 79
DOI 10.1246/cl.1996.79
PROM-341
Promoter TrB(C6F5)4 (cat)
Leaving_Group OH
Title An Efficient Method for Catalytic and Stereoselective Synthesis of 2-Deoxy-??-D-glucopyranosides from 3,4,6,-Tri-O-benzyl-2-deoxy-D-glucopyranose and Several Alcoholic Nucleophiles
Citation Chem Lett. 1997, 969
DOI 10.1246/cl.1997.969
PROM-342
Promoter TrB(C6F5)4
Leaving_Group -S-C(O)-OPh
Title Highly Stereoselective Synthesis of 1,2-trans-Glycosides Using p-Chlorobenzylated Glycosyl Carbonate as Glycosyl Donor
Citation Chem. Lett. 1998. 635
DOI 10.1246/cl.1998.635
PROM-343
Promoter TrB(C6F5)4
Leaving_Group -O-C(O)-OPh
Title The Trityl Tetrakis(pentafluorophenyl)borate Catalyzed Stereoselective Glycosylation Using New Glycosyldonor, 3,4,6-Tri-O-benzyl-2-O-p-toluoyl-??-D-glucopyranosyl Phenylcarbonate
Citation Chem. Lett. 2000. 122
DOI 10.1246/cl.2000.122
PROM-344
Promoter TrB(C6F5)4
Leaving_Group -O-C(O)-OPh(or Me)
Title Highly Stereoselective Synthesis of 1,2-trans-Glycosides Using p-Chlorobenzylated Glycosyl Carbonate as Glycosyl Donor
Citation Chem. Lett. 1998, 635
DOI 10.1246/cl.1998.635
PROM-345
Promoter TrBF4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.79
PROM-346
Promoter TrClO4
Leaving_Group OAc, COCH2Br
Title A FACILE SYNTHESIS OF ??-GLUCOSIDES AND ??-RIBOSIDES FROM THE CORRESPONDING 1-O-ACYL SUGARS AND ALCOHOLS IN THE PRESENCE OF TRITYL PERCHLORATE
Citation Chem. Lett. 1984, 907
DOI 10.1246/cl.1984.907
PROM-347
Promoter TrClO4
Leaving_Group -O=P(=S)-Me2
Title A Convenient 2-Deoxy-??-D-glucopyranosylation Reaction Using Dimethylphosphinothioate Method
Citation Chem Lett. 1990. 849
DOI 10.1246/cl.1990.849
PROM-348
Promoter TrClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.79
PROM-349
Promoter TrClO4
Leaving_Group SCN
Title A new stereospecific method for 1,2-cis-glycosylation
Citation Carbohydr. Res. 1991, 212, 77
DOI 10.1016/0008-6215(91)84047-I
PROM-35
Promoter TMSOTf
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1055/s-1993-22367
PROM-350
Promoter TrClO4
Leaving_Group SCN
Title Synthesis of polysaccharides with 1,2-cis-glycosidic linkages by tritylthiocyanate polycondensation. Stereoregular ??-(1-6)-D-glucan
Citation Tetrahedron Lett. 1992, 33, 381
DOI 10.1016/S0040-4039(00)74137-2
PROM-351
Promoter TrClO4
Leaving_Group ?
Title A convenient synthesis of C-??-d-ribofuranosyl compounds from 1-O-acetyl-2,3,5-tri-O-benzyl-??-d-ribose by the promotion of triphenylmethyl perchlorate
Citation Carbohydr. Res. 1987, 171, 81
DOI 10.1016/S0008-6215(00)90880-2
PROM-353
Promoter TrOTf
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1755
PROM-354
Promoter HB(C6F5)4 or TfOH
Leaving_Group 6-nitro-2- benzothiazolyl glycoside
Title Glycosyl 6-Nitro-2-benzothiazoate. A Highly Efficient Donor for ??-Stereoselective Glycosylation
Citation Chem. Lett. 2003, 32, 340
DOI 10.1246/cl.2003.340
PROM-355
Promoter HB(C6F5)4
Leaving_Group 6-nitro-2- benzothiazolyl glycoside
Title Efficient and Concise Synthesis of ??Man1_4GlcN Linkage of Pentasaccharide Core by Using 6-Nitro-2-benzothiazolyl ??-Mannoside
Citation Chem. Lett. 2005, 34, 702
DOI 10.1246/cl.2005.702
PROM-356
Promoter HB(C6F5)4
Leaving_Group 6-nitro-2- benzothiazolyl glycoside
Title Effective Induction of ??-Selectivity Using ??- or ??-Mannosyl 6-Nitro-2-benzothiazoate in Mannosylation
Citation Heterocycles 2003, 61, 51
DOI 10.3987/COM-03-S29
PROM-357
Promoter TMSB(C6F5)4
Leaving_Group -O-C(=NPh)-CF3
Title Highly ??-Selective Mannosylation towards Man??1-4GlcNAc Synthesis: TMSB(C6F5)4 as a Lewis Acid/Cation Trap Catalyst
Citation Synlett 2005, 2325
DOI 10.1055/s-2005-872678
PROM-358
Promoter BF3
Leaving_Group ?
Title Unsaturated carbohydrates. Part IX. Synthesis of 2,3-dideoxy-??-D-erythro-hex-2-enopyranosides from tri-O-acetyl-D-glucal
Citation J. Chem. Soc. C. 1969, 570
DOI 10.1039/J39690000570
PROM-359
Promoter BF3
Leaving_Group F
Title Coupling of ribofuranosyl fluoride and indoles
Citation J. Chem. Soc. Perkin. Trans 1 1996, 2145
DOI 10.1039/P19960002145
PROM-36
Promoter TMSOTf
Leaving_Group -O-C(=NPh)-CF3
Title First O-Glycosylation of Hydroxamic Acids
Citation J. Org. Chem. 2007, 72, 4262
DOI 10.1021/jo0701839
PROM-360
Promoter BF3
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4020(01)88571-9
PROM-361
Promoter TBAI
Leaving_Group I
Title Efficient, one-pot syntheses of biologically active ??-linked glycolipids
Citation Chem. Commun. 2007, 2336
DOI 10.1039/B702551C
PROM-362
Promoter Me3SiOTf
Leaving_Group -O-C(O)-OPh(or Me)
Title daburi
Citation daburi
DOI 10.1246/cl.1998.635
PROM-363
Promoter Me3SiOTf
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1021/ja0767783
PROM-364
Promoter Me3OBF4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1055/s-1994-22971
PROM-365
Promoter SiCl2(OTf)2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1996.629
PROM-366
Promoter SiCl(OTf)3
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1996.629
PROM-369
Promoter LiClO4
Leaving_Group I
Title O-Glycoside Synthesis with Glycosyl Iodides under Neutral Conditions in 1 M LiClO4 in CH2Cl2
Citation Liebigs Ann. Chem. 1997, 2573
DOI 10.1002/jlac.199719971223
PROM-37
Promoter TMSOTf
Leaving_Group -O-C(=NPh)-CF3
Title Efficient Stereoselective Synthesis of ??-N-Glycosyl Asparagines by N-Glycosylation of Primary Amide Groups
Citation J. Am. Chem. Soc. 2005, 127, 1630
DOI 10.1021/ja0450298
PROM-370
Promoter LiClO4
Leaving_Group F, trichloroimidate
Title Synthesis of glycosides of fucose under neutral conditions in solutions of LiClO4 in organic solvents
Citation Tetrahedron Lett. 1995. 36, 3843
DOI 10.1016/0040-4039(95)00637-R
PROM-371
Promoter LiClO4
Leaving_Group F
Title O-Glycoside Synthesis under Neutral Conditions in Concentrated Solutions of LiClO4 in Organic Solvents Employing Benzyl-Protected Glycosyl Donors
Citation Liebigs Ann. Chem. 1996, 613
DOI 10.1002/jlac.199619960422
PROM-372
Promoter LiClO4
Leaving_Group F
Title O-Glycoside Synthesis under Neutral Conditions in Concentrated Solutions of LiClO4 in Organic Solvents Employing O-Acyl-Protected Glycosyl Donors
Citation Liebigs Ann. Chem. 1996, 621
DOI 10.1002/jlac.199619960423
PROM-373
Promoter LiClO4
Leaving_Group methyl dinitrosalicylate (DISAL)
Title Glucosamine derived DISAL donors for stereoselective glycosylations under neutral conditions
Citation Tetrahedron:Asymmetry 2005, 16, 1439
DOI 10.1016/j.tetasy.2005.02.029
PROM-374
Promoter LiClO4
Leaving_Group -O-P(=O)(OPh)2
Title Activation of glycosyl phosphates by in situ conversion to glycosyl iodides under neutral conditions in concentrated solutions of lithium perchlorate in organic solvents
Citation Tetrahedron Lett. 1996, 37, 3837
DOI 10.1016/0040-4039(96)00729-0
PROM-375
Promoter LiClO4
Leaving_Group -O-P(OEt)2
Title Activation of Glycosyl Phosphites under Neutral Conditions in Solutions of Metal Perchlorates in Organic Solvents
Citation Eur. J. Org. Chem. 1998, 1227
DOI 10.1002/(SICI)1099-0690(199806)1998:6<1227::AID-EJOC1227>3.0.CO;2-4
PROM-376
Promoter LiClO4
Leaving_Group F
Title Synthesis of Fucosyl Saccharides under Neutral Conditions in Solutions of Lithium Perchlorate in Dichloromethane
Citation Chem. Eur. J., 1998, 4, 494
DOI 10.1002/(SICI)1521-3765(19980310)4:3<494::AID-CHEM494>3.0.CO;2-8
PROM-377
Promoter LiClO4
Leaving_Group ?
Title O-Glycoside Syntheses under Neutral Conditions in Concentrated Solutions of LiClO4 in Organic Solvents
Citation Angew. Chem., Int. Ed. 1994, 33, 1944
DOI 10.1002/anie.199419441
PROM-378
Promoter LiClO4
Leaving_Group ?
Title Synthesis of 2-deoxy and 2,6-dideoxy glycosides under neutral conditions in LiClO4/Et2O mixtures
Citation Chem. Commun. 1998, 2759
DOI 10.1039/A807734G
PROM-38
Promoter TMSOTf
Leaving_Group -O-C(=NPh)-CF3
Title Efficient Sialylation with Phenyltrifluoroacetimidates as Leaving Groups
Citation Org. Lett. 2003, 5, 3827
DOI 10.1021/ol0353161
PROM-380
Promoter LiClO4
Leaving_Group ?
Title Synthesis of Deoxy Glycosides Under Neutral Conditions in LiClO4/Solvent Mixtures
Citation Synthesis, 1999, 1411
DOI 10.1055/s-1999-3651
PROM-381
Promoter LiOTf
Leaving_Group trichloroimidate
Title Lithium Triflate as a New Promoter of Glycosylation Under Neutral Conditions
Citation J. Carbohydr. Chem. 1997, 16, 1179
DOI 10.1080/07328309708005745
PROM-382
Promoter Mg(ClO4)2
Leaving_Group -OP(OEt)2
Title daburi
Citation daburi
DOI 10.1002/(SICI)1099-0690(199806)1998:6<1227::AID-EJOC1227>3.0.CO;2-4
PROM-383
Promoter MgO
Leaving_Group I
Title Thermal effect in ??-selective glycosylation reactions using glycosyl iodides
Citation Tetrahedron Lett. 2005, 46, 6727
DOI 10.1016/j.tetlet.2005.07.129
PROM-384
Promoter MgO
Leaving_Group I
Title Unique Reactions of Glycosyl Iodides with Oxa- and Thiocycloalkane Acceptors
Citation Org. Lett. 2004, 6, 973
DOI 10.1021/ol049966w
PROM-385
Promoter Ba(ClO4)2
Leaving_Group -O-P(OEt)2
Title daburi
Citation daburi
DOI 10.1002/(SICI)1099-0690(199806)1998:6<1227::AID-EJOC1227>3.0.CO;2-4
PROM-386
Promoter In
Leaving_Group Br
Title Indium-mediated Stereospecific Glycosylation of Alcohols
Citation Heterocycles 2001, 55, 227
DOI 10.3987/COM-00-9100
PROM-387
Promoter InCl3
Leaving_Group Br
Title Synthesis of glycosides via indium(III) chloride mediated activation of glycosyl halide in neutral condition
Citation Tetrahedron 2001, 57, 7701
DOI 10.1016/S0040-4020(01)00699-8
PROM-388
Promoter InCl3
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-389
Promoter InCl3
Leaving_Group OAc
Title A mild and convenient indium(III) chloride-catalyzed synthesis of thioglycosides
Citation Carbohydr. Res. 2003, 338, 2237
DOI 10.1016/S0008-6215(03)00355-0
PROM-39
Promoter TMSOTf
Leaving_Group OAc
Title ??-selective C-glycosidations: lewis-acid mediated reactions of carbohydrates with silyl ketene acetals
Citation Tetrahedron Lett. 1997, 38, 6815
DOI 10.1016/S0040-4039(97)01602-X
PROM-390
Promoter InBr3
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-391
Promoter InI3
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-392
Promoter InF3
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-393
Promoter In(OTf)3
Leaving_Group -O-C(=NPh)-CF3
Title Efficient Glycosylation Using In(OTf)3 as a Lewis Acid: Activation of N-Phenyltrifluoroacetimidate or Thioglycosides with Halogenated Reagents or PhIO
Citation Chem.Lett. 2014, 43, 956
DOI 10.1246/cl.140167
PROM-396
Promoter AgClO4
Leaving_Group S-Box? (S-benzoxazolyl), S-Benzimidazolyl
Title A study of silver (I) perchlorate as an effective promoter for chemical glycosylation with thioimidates and thioglycosides
Citation Rep. Org. Chem. 2014, 4, 1
DOI 10.2147/ROC.S32147
PROM-397
Promoter AgClO4
Leaving_Group Cl
Title Reaction of glycosyl chlorides with silver perchlorate
Citation Carbohydr. Res. 1970, 15, 329
DOI 10.1016/S0008-6215(00)80449-8
PROM-398
Promoter AgClO4
Leaving_Group -O=P(=S)-Me2
Title New Synthetic Methods and Reagents for Complex Carbohydrates. VIII. Stereoselective ??- and ??-Mannopyranoside Formation from Glycosyl Dimethylphosphinothioates with the C-2 Axial Benzyloxyl Group
Citation Bull. Chem. Soc. Jpn. 1994, 67, 1359
DOI 10.1246/bcsj.67.1359
PROM-399
Promoter AgClO4
Leaving_Group -O=P(=S)-Me2
Title GLUCOSYLATION USING GLUCOPYRANOSYL DIMETHYLPHOSPHINOTHIOATE
Citation Chem Lett. 1985. 297
DOI 10.1246/cl.1985.297
PROM-4
Promoter TMSOTf
Leaving_Group enol ether and imidates
Title Synthesis of ??-O-glycosides using enol ether and imidate derived leaving groups. Emphasis on the use of nitriles as a solvent
Citation Tetrahedron 1991, 47, 9985
DOI 10.1016/S0040-4020(01)96047-8
PROM-40
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OPh)2
Title A rapid and efficient synthesis of 1,2-trans-??-linked glycosides via benzyl- or benzoyl-protected glycopyranosyl phosphates
Citation J. Chem.Soc., Chem. Commun 1989, 685
DOI 10.1039/C39890000685
PROM-400
Promoter AgClO4
Leaving_Group -O-C(S)-N-imidazole
Title Total Synthesis of Avermectin B1a: Synthesis of the Carbohydrate Bis-Oleandrose Fragment and Coupling to the Avermectin B1a Aglycone
Citation Synlett. 1990, 331
DOI 10.1055/s-1990-21081
PROM-401
Promoter AgClO4
Leaving_Group -O-P(=O)-F2
Title A Practical Synthesis of Benzyl ??- and Allyl ??-d-Glucopyranosides Regioselectively Substituted with (CH2)3OH Groups: Stereocontrolled ??-Galactosidation by Cation ??-Interaction
Citation Synthesis 1999, 1625
DOI 10.1055/s-1999-3566
PROM-402
Promoter AgClO4
Leaving_Group ?
Title Stereoselective glycosidations of uronic acids
Citation Tetrahedron Lett. 1980, 21, 1421
DOI 10.1016/S0040-4039(00)92735-7
PROM-403
Promoter AgClO4
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1080/07328309008543823
PROM-404
Promoter AgOTf
Leaving_Group -O-C(O)-S-(2-Py)
Title Synthesis of Gal determinant epitopes, their glycomimetic variants, and trimeric clusters?%5Crelevance to tumor associated antigens and to discordant xenografts
Citation Tetrahedron 2001. 57, 3281
DOI 10.1016/S0040-4020(01)00195-8
PROM-405
Promoter AgOTf
Leaving_Group (1-phenyltetrazol-5-yl)thio droup (ST)
Title A Convenient Synthesis of S-Glycosyl Donors of D-Glucose and O-Glycosylations Involving the New Reagent
Citation Chem. Pharm. Bull. 1990, 38, 636
DOI 10.1248/cpb.38.636
PROM-406
Promoter AgOTf
Leaving_Group S-Box? (S-benzoxazolyl)
Title S-Benzoxazolyl (SBox) Glycosides as Novel, Versatile Glycosyl Donors for Stereoselective 1,2-Cis Glycosylation
Citation Org. Lett. 2003, 5, 455
DOI 10.1021/ol0273452
PROM-407
Promoter AgOTf
Leaving_Group Br
Title Observations on Silver Trifluoromethane Sulfonate-promoted Syntheses of 1,2-trans-Glycosides from Acylated Glycosyl Bromides
Citation Acta Chem. Scand. 1979, 33B, 116
DOI 10.3891/acta.chem.scand.33b-0116
PROM-408
Promoter AgOTf
Leaving_Group SEt
Title A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate
Citation Carbohydr. Res. 2008, 343, 1858
DOI 10.1016/j.carres.2008.03.002
PROM-409
Promoter AgOTf
Leaving_Group Cl
Title C-Glucopyranosyl derivatives from readily available 2,3,4,6-tetra-O-benzyl-??-D-glucopyranosyl chloride
Citation J. Chem. Soc. Chem. Commun. 1987, 101
DOI 10.1039/C39870000101
PROM-41
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OPh)2
Title A highly stereoselective construction of 1,2-trans-??-glycosidic linkages
Citation Tetrahedron 2004, 60, 10711
DOI 10.1016/j.tet.2004.08.076
PROM-410
Promoter AgOTf
Leaving_Group trichloroimidate
Title Silver Triflate. A Mild Alternative Catalyst for Glycosylation Conditions Using Trichloroacetimidates as Glycosyl Donors
Citation J. Carbohydr. Chem. 2003, 22, 385
DOI 10.1081/CAR-120025325
PROM-411
Promoter AgOTf
Leaving_Group SEt
Title Ethyl 2-acetamido-4,6-di-O-benzyl-2,3-N,O-carbonyl-2-deoxy-1-thio-??-D-glycopyranoside as a versatile GlcNAc donor
Citation Chem. Commun. 2005, 3044
DOI 10.1039/B503651H
PROM-412
Promoter AgOTf
Leaving_Group S-2-thiazolinyl
Title Development of an Arming Participating Group for Stereoselective Glycosylation and Chemoselective Oligosaccharide Synthesis
Citation Angew. Chem., Int. Ed. 2005, 44, 7123
DOI 10.1002/anie.200502694
PROM-413
Promoter AgOTf
Leaving_Group S-2-thiazolinyl
Title daburi
Citation daburi
DOI 10.1021/jo801551r
PROM-414
Promoter AgOTf
Leaving_Group -O-P(=S)(OMe)2
Title Preparation of Glycosyl Dimethylthiophosphates and Their Application as Glycosyl Donors
Citation J. Carbohydr. Chem. 1998, 17, 547
DOI 10.1080/07328309808002336
PROM-415
Promoter AgOTf
Leaving_Group trichloroimidate
Title Silver Trifluoromethanesulfonate(Triflate) Activation of Trichloroacetimidates in Glycosylation Reactions
Citation J. Carbohydr. Chem. 1993, 12, 131
DOI 10.1080/07328309308018547
PROM-416
Promoter AgOTf
Leaving_Group isopropenyl, n-pentenyl ?glycoside
Title daburi
Citation daburi
DOI 10.1016/0040-4039(94)88449-8
PROM-417
Promoter AgOTf
Leaving_Group SPy
Title C-glycosidation of pyridyl thioglycosides
Citation Tetrahedron Lett. 1983, 27, 2715
DOI 10.1016/S0040-4039(00)88003-X
PROM-418
Promoter AgOTf
Leaving_Group -S-C(S)-piperidine
Title Glycosyl 1-piperidinecarbodithioates in the synthesis of glycosides
Citation Carbohydr. Res. 1991, 211, 157
DOI 10.1016/0008-6215(91)84154-7
PROM-419
Promoter AgOTf
Leaving_Group -S-C(S)-NEt2
Title Synthesis of glycofuranosides from S-glycofuranosyl dithiocarbonates (xanthates) and dithiocarbamates
Citation Carbohydr. Res. 1996, 295, 235
DOI 10.1016/S0008-6215(96)90148-2
PROM-42
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OPh)2
Title A stereocontrolled construction of 2-azido-2-deoxy-1,2-trans-??-glycosidic linkages utilizing 2-azido-2-deoxyglycopyranosyl diphenyl phosphates
Citation Tetrahedron Lett. 2003, 44, 6453
DOI 10.1016/S0040-4039(03)01557-0
PROM-420
Promoter AgOTf
Leaving_Group I
Title Efficient Synthesis of Man2, Man3, and Man5 Oligosaccharides, Using Mannosyl Iodide Donors
Citation J. Org. Chem. 2005, 70, 8772
DOI 10.1021/jo051360d
PROM-421
Promoter AgOTf
Leaving_Group SR
Title Synthesis and glycosylation of pyrimidin-2-yl 1-thio-??-d-manno- and -??-l-rhamnopyranoside
Citation Carbohydr. Res. 1998, 310, 135
DOI 10.1016/S0008-6215(98)00164-5
PROM-422
Promoter AgOTf
Leaving_Group 1-thioimidoyl
Title Novel glycosylation reactions using glycosyl thioimidates of N-acetylneuraminic acid as sialyl donors
Citation Bioorg. Med. Chem. Lett. 2006, 16, 2618
DOI 10.1016/j.bmcl.2006.02.037
PROM-423
Promoter AgOTf
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(98)00124-5
PROM-424
Promoter AgOTf
Leaving_Group ?
Title Pre-activation based stereoselective glycosylations: Stereochemical control by additives and solvent
Citation Sci. China: Chem. 2011, 54, 66
DOI 10.1007/s11426-010-4186-6
PROM-426
Promoter AgOTf
Leaving_Group Br
Title Neue synthesen von aureols_uretrisacchariden
Citation Carbohydr. Res. 1987,164, 327
DOI 10.1016/0008-6215(87)80139-8
PROM-427
Promoter AgOTf
Leaving_Group ?
Title Synthesis of derivatives of 2-amino-2-deoxy-4-O-(??- and ??-d-galactopyranosyl)-d-glucose
Citation Carbohydr. Res. 1988, 174, 61
DOI 10.1016/0008-6215(88)85081-X
PROM-428
Promoter AgOTf
Leaving_Group ?
Title Synthesis of glycosyltyrosine building blocks for solid-phase glycopeptide assembly: use of aryl tert-butyl ethers as glycosyl acceptors in aromatic glycosylations
Citation J. Chem. Soc., Perkin Trans 1 1994, 3287
DOI 10.1039/P19940003287
PROM-429
Promoter AgOTf
Leaving_Group ?
Title Glycosylation of phenols: preparation of 1,2-cis and 1,2-trans glycosylated tyrosine derivatives to be used in solid-phase glycopeptide synthesis
Citation J. Chem. Soc., Perkin Trans 1 1993, 2119
DOI 10.1039/P19930002119
PROM-43
Promoter TMSOTf
Leaving_Group Dichloro?]cyanoacetimidates
Title Dichloro?]cyanoacetimidates as Glycosyl Donors
Citation J. Carbohydr. Chem. 2007, 26, 223
DOI 10.1080/07328300701410650
PROM-430
Promoter AgOTf
Leaving_Group ?
Title Synthesis of the methyl and 1-octyl glycosides of the P-antigen tetrasaccharide (globotetraose)
Citation Carbohydr. Res. 1985, 144, 231
DOI 10.1016/S0008-6215(00)90671-2
PROM-431
Promoter AgOTf
Leaving_Group Br
Title Synthesis of The Tetradeoxydisaccharide D-C of Aureolic Acids
Citation Liebigs. Ann. Chem. 1983, 462
DOI 10.1002/jlac.198319830312
PROM-432
Promoter AgOTf
Leaving_Group Cl
Title An efficacious C-glucosidation of ??-ketoesters and ketones via enamines
Citation J. Chem. Soc., Chem. Commun. 1988, 57
DOI 10.1039/C39880000057
PROM-433
Promoter AgOTf
Leaving_Group ?
Title Stereoselective template-directed C-glycosidation. Synthesis of bicyclic ketooxetanes via intramolecular cyclization reactions of (2-pyridylthio)glycosidic silyl enol ethers
Citation J. Chem. Soc., Chem. Commun. 1993, 901
DOI 10.1039/C39930000901
PROM-434
Promoter AgOTf
Leaving_Group ?
Title Alternative Syntheses of (l??3)-??-D-Galacto-Oligosaccharides
Citation J. Carbohydr. Chem. 1990, 9, 135
DOI 10.1080/07328309008543823
PROM-435
Promoter AgOTf
Leaving_Group SBox, STaz
Title daburi
Citation daburi
DOI 10.1016/j.tetasy.2004.11.029
PROM-436
Promoter AgOTf
Leaving_Group ?
Title Synthesis of the laminara-oligosaccharide methyl ??-glycosides of dp 3_8
Citation Carbohydr. Res. 1993, 245, 81
DOI 10.1016/0008-6215(93)80061-I
PROM-437
Promoter AgOTf
Leaving_Group Cl
Title Efficient chemical synthesis of methyl ??-glycosides of ??-(1??6)-linked d-galacto-oligosaccharides by a stepwise and a blockwise approach
Citation Carbohydr. Res. 1986, 153, 237
DOI 10.1016/S0008-6215(00)90266-0
PROM-438
Promoter AgOTf
Leaving_Group Cl
Title Synthesis of a series of methyl ??-glycosides of (1??6)-??-d-galacto-oligosaccharides having one residue deoxygenated at position 3
Citation Carbohydr. Res. 1990, 201, 79
DOI 10.1016/0008-6215(90)84226-K
PROM-439
Promoter AgOTf
Leaving_Group SPhMe
Title daburi
Citation daburi
DOI 10.1021/ja015570t
PROM-44
Promoter TMSOTf and more
Leaving_Group glycosylthio heterocycles(SPy,?SQu,?SIm,?STh,?SBth,?SBox,?STr,?SOxd,?SThd,?STe,?SPd,?SPm,?SPz,?SQz,?SBtz,?SQx,?STz)
Title Synthesis and role of glycosylthio heterocycles in carbohydrate chemistry
Citation Tetrahedron, 2006, 62, 2943
DOI 10.1016/j.tet.2005.11.045
PROM-440
Promoter AgOTf
Leaving_Group Br
Title Syntheses of a branched heptasaccharide having phytoalexin-elicitor activity
Citation Carbohydr. Res. 1987, 164, 297
DOI 10.1016/0008-6215(87)80137-4
PROM-441
Promoter AgOTf
Leaving_Group Cl, OP(OEt2), Br, SEt
Title 8-O-Sialylation of Neuraminic Acid
Citation J. Am. Chem. Soc. 1998, 120, 5434
DOI 10.1021/ja9740327
PROM-442
Promoter AgOTf
Leaving_Group Cl, F
Title Total Synthesis of GD3, A Ganglioside?
Citation Chem. Lett. 1996, 337
DOI 10.1246/cl.1996.337
PROM-444
Promoter AgOTf
Leaving_Group 2-PyS, 2-Pym-S
Title The Asymmetric Synthesis of Erythromycin B
Citation J. Am. Chem. Soc. 1997, 119, 3193
DOI 10.1021/ja963575y
PROM-445
Promoter AgOTf-DMSO or tetramethylurea or HMPA(catalytic amount)
Leaving_Group -S-C(S)-NEt2, -S-C(S)-OEt
Title Polar Additives as Cocatalyst in Glycosidation
Citation Synlett. 1997, 661
DOI 10.1055/s-1997-3245
PROM-446
Promoter AgOTf-HMPA(catalyc amount)
Leaving_Group -S-C(S)-NEt2
Title Studies on the synthesis of 1,2-cis pentofuranosides from S-glycofuranosyl dithiocarbamates, dithiocarbonates and phosphorodithioates
Citation Carbohydr. Res. 2001, 330, 141
DOI 10.1016/S0008-6215(00)00220-2
PROM-447
Promoter Ag2CO3
Leaving_Group glycosylthio, glycosyldithio, selenophosphates
Title Highly Stereoselective Synthesis of the 1-O-Acylglycosyl Ester of Diclofenac via Glycosyl Phosphorothioates, -Selenoates and -Dithioates as Glycosyl Donors
Citation Liebigs Ann./ Recueil 1997, 2147
DOI 10.1002/jlac.199719971017
PROM-448
Promoter Ag2O
Leaving_Group trichloroimidate
Title Reaction d'imidates de glucopyranosyle avec l'acetonitrile. Applications synthetiques
Citation Tetrahedron Lett. 1976, 4073
DOI 10.1016/S0040-4039(00)92578-4
PROM-449
Promoter AgB(C6F5)4
Leaving_Group F
Title Catalytic and Stereoselective Glycosylation with Disarmed Glycosyl Fluoride Having Phthaloyl or Dichlorophthaloyl Protected Amino Function Using a 1 : 2 Combination of Stannic Chloride and Silver Tetrakis(pentafluorophenyl)borate
Citation Chem Lett. 2001, 726
DOI 10.1246/cl.2001.726
PROM-45
Promoter TMSOTf
Leaving_Group SPh, SMe
Title Sulfenate esters as glycosyl acceptors: A novel approach to O-glycosides from thioglycosides and sulfenate esters
Citation Tetrahedron Lett. 1987, 28, 4701
DOI 10.1016/S0040-4039(00)96602-4
PROM-451
Promoter AgBF4
Leaving_Group Cl
Title Synthesis of 2-(??-d-glucopyranosyl)benzoic acid by an intramolecular Friedel?%5CCrafts reaction
Citation Carbohydr. Res. 1996, 291, 11
DOI 10.1016/S0008-6215(96)00111-5
PROM-452
Promoter silver tresylate [2,2,2-trifluoroethanesulfonate:Tresylate]
Leaving_Group OH
Title Synthesis of Methyl 3-O-(??-D-mannnopyranosyl)-??-D-mannopyranoside
Citation Bull. Chem. Soc. Jpn. 1986, 59, 1587
DOI 10.1246/bcsj.59.1587
PROM-453
Promoter Hf(OTf)4
Leaving_Group F
Title Hafnium(IV) Tetratriflate as a Glycosyl Fluoride Activation Reagent
Citation J. Org. Chem. 2013, 78,?4568
DOI 10.1021/jo400282x
PROM-454
Promoter ZrCl4
Leaving_Group F
Title Zirconium tetrachloride as a convenient catalyst for the glycosylation of sterols with 2,3,4,6,6??-penta-O-acetyl-5-hydroxymethylgalactosyl fluoride
Citation Tetrahedron:Asymmetry 1997, 8, 1165
DOI 10.1016/S0957-4166(97)00094-3
PROM-455
Promoter ZrCl4
Leaving_Group ?
Title Stereoselective Syntheses of 1,2-trans p-MePh and 2-Pyridyl 1-Thioglycosides Catalyzed by Zirconium(IV) Chloride
Citation Synth. Commun. 1999, 29, 3541
DOI 10.1080/00397919908085987
PROM-456
Promoter Yb(NTf2)3
Leaving_Group F, OAc
Title YTTERBIUM(III) TRIS[BIS(PERFLUORO-BUTYLSULFONYL)AMIDE] AS A LEWIS ACID FOR GLYCOSIDATIONS
Citation Synth. Commun. 2001, 31, 899
DOI 10.1081/SCC-100103325
PROM-457
Promoter Cu(OTf)2
Leaving_Group 1-OH sugar, trichloroimidate, OAc, F
Title daburi
Citation Carbohydr. Res. 2002, 337, 581
DOI
PROM-458
Promoter Cu(OTf)2
Leaving_Group OH
Title Facile Cu(OTf)2-Catalyzed Preparation of Per-O-acetylated Hexopyranoses with Stoichiometric Acetic Anhydride and Sequential One-Pot Anomeric Substitution to Thioglycosides under Solvent-Free Conditions
Citation J. Org. Chem. 2003, 68, 8719
DOI 10.1021/jo030073b
PROM-459
Promoter Cu(OTf)2
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1055/s-1993-22367
PROM-46
Promoter TMSOTf
Leaving_Group TMS
Title Einfache und stereoselektive synthese von ??- und ??-phenylglykosiden
Citation Tetrahedron Lett. 1982, 23, 4661
DOI 10.1016/S0040-4039(00)85681-6
PROM-460
Promoter Cu(OTf)2
Leaving_Group 2-mercaptobenzothiazolyl
Title AN EFFICIENT GLUCOSYLATION OF ALCOHOL USING 1-THIOGLUCOSIDE DERIVATIVE
Citation Chem Lett. 1979, 487
DOI 10.1246/cl.1979.487
PROM-461
Promoter Cu(OTf)2
Leaving_Group S-Box? (S-benzoxazolyl)
Title Revisiting the Armed?|Disarmed Concept:_ The Importance of Anomeric Configuration in the Activation of S-Benzoxazolyl Glycosides
Citation Org. Lett. 2007, 9, 4115
DOI 10.1021/ol701466u
PROM-462
Promoter Cu(OTf)2
Leaving_Group -S-C(S)-OEt
Title daburi
Citation daburi
DOI 10.1351/pac199163040519
PROM-463
Promoter Cu(OTf)2
Leaving_Group -S-C(S)-OEt
Title A novel class of glycosyl donors: Anomeric S-xanthates of 2-azido-2-deoxy-D-galactopyranosyl derivatives
Citation Tetrahedron 1991, 47, 5149
DOI 10.1016/S0040-4020(01)87127-1
PROM-464
Promoter Cu(OTf)2
Leaving_Group 1-thioimidoyl
Title daburi
Citation daburi
DOI 10.1021/jo070741j
PROM-465
Promoter Cu(OTf)2
Leaving_Group OCOPy
Title A new glycosylation reaction based on a ?gremote activation concept?h: glycosyl 2-pyridinecarboxylate as a novel glycosyl donor
Citation Tetrahedron Lett. 1991, 32, 7065
DOI 10.1016/0040-4039(91)85041-3
PROM-466
Promoter Cu(OTf)2
Leaving_Group -S-C(S)-OEt
Title Anomeric S-Xanthates of 2-Azido-2-deoxy-D-galactopyranosyl Derivatives as Efficient Glycosyl Donors
Citation Synlett. 1990, 445
DOI 10.1055/s-1990-34720
PROM-467
Promoter Cu(OTf)2
Leaving_Group 3-methoxypyridines (MOP)
Title daburi
Citation daburi
DOI 10.1021/ja982783i
PROM-468
Promoter CuOTf(C6H6)0.5
Leaving_Group -S-C(S)-NEt2
Title Glycosyl Dithiocarbamates: ??-Selective Couplings without Auxiliary Groups
Citation J. Org. Chem. 2014, 79, 2611
DOI 10.1021/jo500032k
PROM-469
Promoter CuCl2
Leaving_Group ?
Title Copper(II)-Mediated Activation of Sugar Oxazolines: Mild and Efficient Synthesis of ??-Glycosides of N-Acetylglucosamine
Citation Eur. J. Org. Chem. 2002, 1363
DOI 10.1002/1099-0690(200204)2002:8<1363::AID-EJOC1363>3.0.CO;2-#
PROM-47
Promoter TMSOTf
Leaving_Group TMS
Title Coupling reactions of O-(trimethylsilyl) glycosides and 6-O-(tert-butyldiphenylsilyl)-protected galactosides in the presence of trimethylsilyl triflate. A new method of forming .beta.-(1 .fwdarw. 6)-oligosaccharidic linkages
Citation J. Org. Chem. 1989, 54, 6116
DOI 10.1021/jo00287a026
PROM-470
Promoter CuBr2
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/1099-0690(200204)2002:8<1363::AID-EJOC1363>3.0.CO;2-#
PROM-471
Promoter CdCl2
Leaving_Group Cl
Title Naphthalene, Phenanthrene, and Pyrene as DNA Base Analogues: Synthesis, Structure, and Fluorescence in DNA
Citation J. Am. Chem. Soc. 1996, 118, 7671
DOI 10.1021/ja9612763
PROM-472
Promoter AuBr3
Leaving_Group propargyl glycosides
Title Gold-catalyzed glycosidations: unusual cleavage of the interglycosidic bond while studying the armed/disarmed effect of propargyl glycosides
Citation Tetrahedron Lett. 2010, 52, 5269
DOI 10.1016/j.tetlet.2010.07.157
PROM-473
Promoter AuBr3
Leaving_Group OMe
Title Methyl glycosides are identified as glycosyl donors for the synthesis of glycosides, disaccharides and oligosaccharides
Citation Chem. Commun. 2009, 2505
DOI 10.1039/B822526E
PROM-474
Promoter AuCl3
Leaving_Group propargyl glycosides OCH2CCR (R = H, Me)
Title Glycosylation Using Unprotected Alkynyl Donors
Citation J. Org. Chem. 2009, 74, 8417
DOI 10.1021/jo901857x
PROM-475
Promoter AuCl3
Leaving_Group Propargyl Glycosides
Title Propargyl Glycosides as Stable Glycosyl Donors:_ Anomeric Activation and Glycoside Syntheses
Citation J. Am. Chem. Soc. 2006, 128, 9620
DOI 10.1021/ja062425c
PROM-477
Promoter Ph3PAuNTf2
Leaving_Group ortho-alkynylbenzoates
Title An Efficient Approach to the Synthesis of Nucleosides: Au(I)-Catalyzed N-Glycosylation of Pyrimidines and Purines with Glycosyl ortho-Alkynyl Benzoates
Citation Angew. Chem., Int. Ed. 2011, 50, 4933
DOI 10.1002/anie.201100514
PROM-478
Promoter Ph3PAuNTf2
Leaving_Group ortho-alkynylbenzoates
Title Efficient Synthesis of Lupane-Type Saponins via Gold(I)-Catalyzed Glycosylation with Glycosyl ortho-Alkynylbenzoates as Donors
Citation Org. Lett. 2011, 13, 5508
DOI 10.1021/ol202232v
PROM-479
Promoter Ph3PAuNTf2
Leaving_Group ortho-alkynylbenzoates
Title Synthesis of ginsenoside Rh2 and chikusetsusaponin-LT8 via gold(I)-catalyzed glycosylation with a glycosyl ortho-alkynylbenzoate as donor
Citation Tetrahedron Lett. 2011, 52, 3075
DOI 10.1016/j.tetlet.2011.04.003
PROM-48
Promoter TMSOTf
Leaving_Group TBS
Title 2-Deoxy-1-O-silylated-??-hexopyranoses. Useful glycosyl donors and synthetic intermediates.
Citation Tetrahedron Lett. 1991, 32, 2079
DOI 10.1016/S0040-4039(00)71241-X
PROM-480
Promoter Ph3PAuNTf2
Leaving_Group o-cyclopropylethynylbenzoates
Title Synthesis of Kaempferol 3-O-[2????,3????- and 2????,4????-Di-O-(E)-p-coumaroyl]-??-l-rhamnopyranosides
Citation Synlett 2011, 7, 915
DOI 10.1055/s-0030-1259702
PROM-481
Promoter Ph3PAuNTf2
Leaving_Group ortho-hexynylbenzoate
Title Synthesis of ginsenoside Rh2 and chikusetsusaponin-LT8 via gold(I)-catalyzed glycosylation with a glycosyl ortho-alkynylbenzoate as donor
Citation Tetrahedron Lett. 2011, 52, 3075
DOI 10.1016/j.tetlet.2011.04.003
PROM-482
Promoter Ph3PAuNTf2
Leaving_Group ortho-hexynylbenzoates
Title Glycosylation initiated cationic ring-opening polymerization of tetrahydrofuran to prepare neo-glycopolymers
Citation Chem. Commun. 2010, 46, 6060
DOI 10.1039/C0CC00566E
PROM-483
Promoter Ph3PAuNTf2
Leaving_Group ortho-hexynylbenzoates
Title daburi
Citation daburi
DOI 10.1021/ja4064316
PROM-484
Promoter Ph3PAuNTf2
Leaving_Group ortho-hexynylbenzoates
Title daburi
Citation daburi
DOI 10.1021/ja501460j
PROM-485
Promoter Ph3PAuOTf?, ?Ph3PAuNTf2
Leaving_Group ortho-alkynylbenzoates
Title Gold(I)-Catalyzed Glycosylation with Glycosyl ortho-Alkynylbenzoates as Donors: General Scope and Application in the Synthesis of a Cyclic Triterpene Saponin
Citation Chem. Eur. J. 2010, 16, 1871
DOI 10.1002/chem.200902548
PROM-486
Promoter Ph3PAuOTf
Leaving_Group ortho-alkynylbenzoates
Title An efficient glycosylation protocol with glycosyl ortho-alkynylbenzoates as donors under the catalysis of Ph3PAuOTf
Citation Tetrahedron Lett. 2008, 49, 3604
DOI 10.1016/j.tetlet.2008.04.017
PROM-487
Promoter Ph3PAuOTf
Leaving_Group ortho-alkynylbenzoates
Title Mechanistic Insights into the Gold(I)-Catalyzed Activation of Glycosyl ortho-Alkynylbenzoates for Glycosidation
Citation J. Am. Chem. Soc. 2013, 135, 18396
DOI 10.1021/ja4064316
PROM-488
Promoter Ph3PAuOTf
Leaving_Group ortho-alkynylbenzoates
Title Total Synthesis and Structural Revision of TMG-chitotriomycin, a Specific Inhibitor of Insect and Fungal ??-N-Acetylglucosaminidases
Citation J. Am. Chem. Soc. 2009, 131, 12076
DOI 10.1021/ja9055245
PROM-489
Promoter Ph3PAuOTf
Leaving_Group ortho-hexynylbenzoates
Title daburi
Citation daburi
DOI 10.1021/ja501460j
PROM-49
Promoter TMSOTf
Leaving_Group TBS
Title Semisynthetic ??-(iso)rhodomycins: a new glycosylation variant and modification reactions
Citation Carbohydr. Res. 1991, 209, 89
DOI 10.1016/0008-6215(91)80147-F
PROM-490
Promoter Yb(OTf)3
Leaving_Group -C(=NPh)-CF3
Title Efficient activation of glycosyl N-(phenyl)trifluoroacetimidate donors with ytterbium(III) triflate in the glycosylation reaction
Citation Tetrahedron Lett. 2002, 43, 5573
DOI 10.1016/S0040-4039(02)01124-3
PROM-491
Promoter Yb(OTf)3
Leaving_Group -C(=NPh)-CF3
Title Moisture Stable Promoters for Selective ??-Fucosylation Reactions: Synthesis of Antigen Fragments
Citation Synlett 2004, 275
DOI 10.1055/s-2004-815415
PROM-492
Promoter Yb(OTf)3
Leaving_Group -C(=NPh)-CF3
Title Tunable Activation of Glycosyl Trichloro- and (N-phenyl)trifluoro_acetimidates with Ytterbium(III) Triflate: One-Pot Synthesis of _Trisaccharides under Catalytic Conditions
Citation Synlett 2006, 583
DOI 10.1055/s-2006-932484
PROM-493
Promoter Yb(OTf)3
Leaving_Group F
Title A New Glycosidation Procedure Utilizing Rare Earth Salts and Glycosyl Fluorides, with or without the Requirement of Lewis Acids
Citation J. Org. Chem. 1995, 60, 4
DOI 10.1021/jo00106a002
PROM-494
Promoter Yb(OTf)3
Leaving_Group -O-C(=NPh)-CF3
Title Toward Novel Glyconjugates: Efficient Synthesis of Glycosylated 4-Alkylidene--lactams
Citation Eur. J. Org. Chem. 2006, 69
DOI 10.1002/ejoc.200500665
PROM-495
Promoter Yb(OTf)3
Leaving_Group -O-C(=NPh)-CF3
Title Effect of dimethoxyethane in Yb(OTf)3-promoted glycosidations
Citation Tetrahedron Lett. 2004, 45, 4485
DOI 10.1016/j.tetlet.2004.04.046
PROM-496
Promoter Yb(OTf)3
Leaving_Group trichloroimidate
Title Activation of disarmed 2-O-alkoxycarbonylated glycosyl trichloroacetimidates with lanthanide triflates: an efficient approach for the synthesis of 1,2-trans glycosides
Citation Tetrahedron Lett. 2001, 42, 5967
DOI 10.1016/S0040-4039(01)01158-3
PROM-497
Promoter Yb(OTf)3
Leaving_Group OCOCH2OMe
Title Lanthanoid(III) triflates as new glycosylation catalysts. Selective and efficient activation of 1-O-methoxyacetyl sugars
Citation Tetrahedron Lett. 1993, 34, 2791
DOI 10.1016/S0040-4039(00)73563-5
PROM-499
Promoter Yb(OTf)3
Leaving_Group trifluoroacetimidate
Title Versatile Use of Ytterbium(III) Triflate and Acid Washed Molecular Sieves in the Activation of Glycosyl Trifluoroacetimidate Donors. Assemblage of a Biologically Relevant Tetrasaccharide Sequence of Globo H
Citation J. Org. Chem. 2005, 70, 5316
DOI 10.1021/jo050301x
PROM-5
Promoter TMSOTf
Leaving_Group enol ether
Title A new glycosylation method using glycosyl donors substituted by enol ether as a leaving group
Citation Tetrahedron Lett. 1999, 40, 1531
DOI 10.1016/S0040-4039(98)02703-8
PROM-50
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Oxidative Cleavage of Benzyl Esters with Triarylamine Cation Radicals?%5CSelective Deblocking of Protected Carboxy Functions
Citation Angew. Chem., Int. Ed. Engl 1982, 21, 781
DOI 10.1002/anie.198207801
PROM-500
Promoter Tb(OTf)3
Leaving_Group OCOCH2OMe
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)73563-5
PROM-501
Promoter Ho(OTf)3
Leaving_Group OCOCH2OMe
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)73563-5
PROM-502
Promoter Tm(OTf)3
Leaving_Group OCOCH2OMe
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)73563-5
PROM-503
Promoter PhSeOTf
Leaving_Group SMe
Title Benzeneselenenyl triflate as a promoter of thioglycosides : A new method for O-glycosylation using thioglycosides
Citation Tetrahedron Lett. 1988, 29, 1061
DOI 10.1016/0040-4039(88)85335-8
PROM-504
Promoter PhSeOTf
Leaving_Group SMe
Title Benzeneselenenyl triflate as an activator of thioglycosides for glycosylation reactions
Citation Carbohydr. Res. 1990, 202, 165
DOI 10.1016/0008-6215(90)84078-9
PROM-505
Promoter PhSeOTf
Leaving_Group SMe
Title A highly efficient and stereoselective cycloglycosylation. Synthesis of cyclo?????4)-[??-Man-(1??4)]5-??-Man-(1?????, a manno isomer of ??-cyclodextrin
Citation Tetrahedron Lett. 1989, 30, 1273
DOI 10.1016/S0040-4039(00)72734-1
PROM-506
Promoter PhSeOTf
Leaving_Group SePh
Title Substituted azides from selenium-promoted deselenenylation of azido selenides. Glycosylation reactions of protected 2-azido-2-deoxy-1-selenoglycopyranoses
Citation J. Chem.Soc., Chem. Commun 1994, 1883
DOI 10.1039/C39940001883
PROM-507
Promoter PhSeOTf
Leaving_Group ?
Title A highly stereoselective and practical synthesis of cyclomannohexaose, Cyclo{??4)-[??-d-Manp-(1??4)-]5-??-d-Manp-(1??}, a manno isomer of cyclomaltohexaose
Citation Carbohydr. Res. 1990, 192, 131
DOI 10.1016/0008-6215(89)85173-0
PROM-508
Promoter PhSeOTf, thermal condition
Leaving_Group Cl
Title Total synthesis of cyclo-l-rhamnohexaose by a stereoselective thermal glycosylation
Citation Tetrahedron Lett. 1991, 32, 5551
DOI 10.1016/0040-4039(91)80081-G
PROM-509
Promoter Bu3SnH, AIBN
Leaving_Group Br
Title S- and C-glycopeptide derivatives of an LH-RH agonist
Citation Int. J. Peptide Protein Res. 1996, 48, 59
DOI 10.1111/j.1399-3011.1996.tb01107.x
PROM-51
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Glycosylimidate, 13. Anwendung des Trichloracetimidat-Verfahrens auf 2-Azidoglucose- und 2-Azidogalactose-Derivate
Citation Liebigs Ann. Chem. 1984, 2, 1826
DOI 10.1002/jlac.198419841108
PROM-510
Promoter Bu3SnH, AIBN
Leaving_Group Br
Title Reductive Oxa Ring Opening of 7-Oxabicyclo[2.2.1]heptan-2-ones. Synthesis of C-.alpha.-Galactosides of Carbapentopyranoses
Citation J. Org. Chem. 1995, 60, 8351
DOI 10.1021/jo00131a007
PROM-511
Promoter Bu3SnH
Leaving_Group SePh
Title C(5)-Epimerization in Glycopyranosides during the Cyclization of anomeric Radicals: Ease of the intramolecular 1,5-Hydrogen Atom Transfer
Citation Synlett 1994, 330
DOI 10.1055/s-1994-22842
PROM-512
Promoter Bu3SnSnBu3, h??
Leaving_Group Br
Title C-Allylation of 1- and 6-Bromosugars with Allylic Sulfides and Sulfones
Citation J. Org. Chem. 1996, 61, 7463
DOI 10.1021/jo960749l
PROM-513
Promoter SnCl2
Leaving_Group OCOCH2I
Title Tin(II) Chloride Catalyzed Synthesis of Ribofuranosides
Citation Chem. Lett. 1994, 433
DOI 10.1246/cl.1994.433
PROM-514
Promoter SnCl2
Leaving_Group F, S(O)Ph
Title daburi
Citation daburi
DOI 10.1021/ja030496v
PROM-515
Promoter SnCl4
Leaving_Group OAc
Title THE ALPHA AND BETA 1,3,4,6-TETRAACETYL-D-GLUCOPYRANOSES AND THEIR CHLOROACETYL DERIVATIVES
Citation Can. J. Chem. 1953, 31, 528
DOI 10.1139/v53-075
PROM-516
Promoter SnCl4
Leaving_Group OAc
Title Chemistry of the glycosidic linkage.O-glycosylations catalyzed by stannic chloride, in the D-ribofuranose and D-glucopyranose series
Citation Carbohydr. Res. 1977, 59, 261
DOI 10.1016/S0008-6215(00)83314-5
PROM-517
Promoter SnCl4
Leaving_Group ?
Title Glycosides. Part 1. New synthesis of 1,2-trans O-aryl glycosides, via tributyltin phenoxides
Citation J. Chem. Soc., Perkin Trans. 1 1994, 985
DOI 10.1039/P19940000985
PROM-518
Promoter SnCl4
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.5059/yukigoseikyokaishi.53.1045
PROM-519
Promoter SnCl4
Leaving_Group OAc
Title Facile Syntheses of C-Glycosides of Aromatic Compounds
Citation Agric. Biol. Chem. 1972, 36, 1651
DOI 10.1271/bbb1961.36.1651
PROM-52
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Concerning the Origin of the High ??-Selectivity of Glycosidation Reactions of 2-Deoxy-2-iodo-glucopyranosyl Trichloroacetimidates
Citation Org. Lett. 2002, 4, 4523
DOI 10.1021/ol027066e
PROM-521
Promoter SnCl4
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97693-7
PROM-522
Promoter SnCl4
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1002/jhet.5570280526
PROM-523
Promoter SnCl4
Leaving_Group ?
Title Synthesis of methyl- and methoxy-substituted .beta.-D-ribofuranosylnaphthalene derivatives by Lewis acid catalyzed ribofuranosylation
Citation J. Org. Chem. 1991, 56, 3731
DOI 10.1021/jo00011a059
PROM-524
Promoter SnCl4
Leaving_Group ?
Title Cyanosugars?%5CII: Synthesis of hexopyranosyl cyanides by reaction of glycals with trimethylsilyl cyanide
Citation Tetrahedron 1983, 39, 1617
DOI 10.1016/S0040-4020(01)88571-9
PROM-525
Promoter SnCl3(ClO4) (cat)
Leaving_Group OAc
Title Stereoselective Synthesis of O-(2-Azido-2-deoxy-??-D-galactopyranosyl)-L-serine and -L-threonine Derivatives by Using the Catalytic Amount of Active Acidic Species
Citation Chem. Lett. 1993, 581
DOI 10.1246/cl.1993.581
PROM-526
Promoter SnCl3(ClO4)
Leaving_Group OAc
Title Stereoselective Synthesis of 2-Amino-2-deoxy-??-D-glucopyranosides and Galactopyranosides
Citation Chem. Lett. 1992, 21, 1755
DOI 10.1246/cl.1992.1755
PROM-527
Promoter Sn(OTf)2
Leaving_Group trichloroimidate
Title Efficient Methods for Glycosidations with Glycals - A Key Intermediate for the Synthesis of Mucin Core 1-Type O-Glycan
Citation Synlett 2004, 836
DOI 10.1055/s-2004-817790
PROM-528
Promoter Sn(OTf)2 (cat)
Leaving_Group OAc
Title Stereoselective Synthesis of 2-Amino-2-deoxy-??-D-glucopyranosides and Galactopyranosides by Using a Catalytic Amount of Tin(II) Trifluoromethanesulfonate
Citation Chem. Lett. 1992, 1755
DOI 10.1246/cl.1992.1755
PROM-529
Promoter Sn(OTf)2
Leaving_Group trichloroimidate
Title N-Tetrachlorophthaloyl-protected trichloroacetimidate of glucosamine as glycosyl donor in oligosaccharide synthesis
Citation Tetrahedron Lett. 1995, 36, 5343
DOI 10.1016/0040-4039(95)01027-F
PROM-53
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Synthesis of Hex p-(1 ?? 4)-??-d-Glc pNAc-(1 ?? 2)-??-d-Man p-(1 ?? O)(CH2)7CH3 probes for exploration of the substrate specificity of glycosyltransferases: Part I, Hex = ??-d-Gal, 4-deoxy-??-d-Gal, 4-O-methyl-??-d-Gal, 4-deoxy-4-fluoro-??-d-Gal, or ??-d-Glc
Citation Carbohydr. Res. 1996, 291, 63
DOI 10.1016/S0008-6215(96)00154-1
PROM-530
Promoter Sn(OTf)2
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.969
PROM-531
Promoter Sn(OTf)2
Leaving_Group OCOPy
Title daburi
Citation daburi
DOI 10.1016/0040-4039(91)85041-3
PROM-532
Promoter Sn(OTf)2
Leaving_Group trichloroimidate
Title Ionic liquids in oligosaccharide synthesis: towards mucin-type glycan probes
Citation Biochem. Soc. Trans. 2010, 38, 1368
DOI 10.1042/BST0381368
PROM-533
Promoter Sn(OTf)2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1755
PROM-534
Promoter Sn(OTf)2
Leaving_Group -OC(=NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja980588y
PROM-535
Promoter SnCl2(OTf)2
Leaving_Group OAc
Title A New Efficient Method for Stereoselective Synthesis of 2-Deoxy-C-ribofuranosides?
Citation Chem. Lett. 1996, 629
DOI 10.1246/cl.1996.629
PROM-536
Promoter SnCl3(OTf)
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1755
PROM-537
Promoter SnBr4
Leaving_Group OAc, OC(O)CH2Cl
Title daburi
Citation daburi
DOI 10.1021/ja0767783
PROM-539
Promoter tributylstannyllithium
Leaving_Group Cl
Title Stereocontrolled preparation of C-2-deoxy-??- and -??-d-glucopyranosyl compounds from tributyl-(2-deoxy-??- and -??-d-glucopyranosyl)stannanes
Citation Carbohydr. Res. 1987, 171, 289
DOI 10.1016/S0008-6215(00)90893-0
PROM-54
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Stereoselective Synthesis of ??-D-Mannopyranosides with Reactive Mannopyranosyl Donors Possessing a Neighboring Electron-Withdrawing Group
Citation Angew. Chem., Int. Ed. 2002, 41, 2972
DOI 10.1002/1521-3773(20020816)41:16<2972::AID-ANIE2972>3.0.CO;2-4
PROM-540
Promoter Methallyltri-n-butylstannane
Leaving_Group ?
Title Two new methods for the synthesis of C-glycosides
Citation Tetrahedron Lett. 1984, 25, 1867
DOI 10.1016/S0040-4039(01)90062-0
PROM-541
Promoter allyltri-n-butylstannane
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(01)90062-0
PROM-542
Promoter ZnCl2
Leaving_Group Br
Title Alkynylation of mixed acetals with organotin acetylides
Citation J. Am. Chem. Soc. 1988, 110, 2501
DOI 10.1021/ja00216a025
PROM-543
Promoter ZnCl2
Leaving_Group -O-P-(OMe)2
Title Glycosylation Based on Phosphite Chemistry
Citation Synlett. 1993, 115
DOI 10.1055/s-1993-22367
PROM-544
Promoter ZnCl2
Leaving_Group -O-P-(OMe)2
Title Glycosylation using glycosyl phosphite as a glycosyl donor
Citation Tetrahedron 1994, 50, 6523
DOI 10.1016/S0040-4020(01)89683-6
PROM-545
Promoter ZnCl2
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1016/S0008-6215(00)90879-6
PROM-546
Promoter ZnCl2
Leaving_Group OH
Title Preparation of Glycosyl Tetrazoles and Application as Glycosyl Donors
Citation Syntlett 1994, 672
DOI 10.1055/s-1994-22971
PROM-547
Promoter ZnCl2
Leaving_Group Cl
Title daburi
Citation daburi
DOI 10.1055/s-1992-21494
PROM-548
Promoter ZnCl2
Leaving_Group trichloroimidate
Title O-Glycosyl Imidates, 19. _ Reactions of Glycosyl Trichloroacetimidates with Silylated C-Nucleophiles
Citation Liebigs Ann. Chem. 1985, 2403
DOI 10.1002/jlac.198519851211
PROM-549
Promoter ZnCl2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1021/ja980196r
PROM-55
Promoter TMSOTf
Leaving_Group trichloroimidate
Title ??-Directing Effect of Electron-Withdrawing Groups at O-3, O-4, and O-6 Positions and ??-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations
Citation J. Am. Chem. Soc. 2009, 131, 17705
DOI 10.1021/ja907252u
PROM-553
Promoter ZnCl2
Leaving_Group ?
Title Synthesis of 4-methylumbelliferyl 1,2-cis-glycosides
Citation Carbohydr. Res. 1978, 65, 23
DOI 10.1016/S0008-6215(00)84209-3
PROM-554
Promoter ZnCl2
Leaving_Group F, SEt
Title Total Synthesis and Proof of Structure of a Human Breast Tumor (Globo-H) Antigen
Citation J. Am. Chem. Soc. 1996, 118, 11488
DOI 10.1021/ja962048b
PROM-555
Promoter ZnBr2
Leaving_Group -O-C(S)-N-imidazole
Title A Simple, One-Pot, Glycosidation Procedure via (1-Imidazolylcaronyl) Glycosides and Zinc Bromide
Citation Synlett. 1990, 255
DOI 10.1055/s-1990-21053
PROM-556
Promoter ZnBr2
Leaving_Group trichloroimidate
Title Synthesis of tigogenyl ??-O-cellobioside heptaacetate and glycoside tetraacetate via Schmidt's trichloroacetimidate method; some new observatons
Citation Tetrahedron Lett. 1990, 31, 4421
DOI 10.1016/S0040-4039(00)97637-8
PROM-557
Promoter ZnBr2
Leaving_Group PhS(O)2-
Title C-glycoside?synthesis???? Substitution reactions of 2-benzenesulphonyl cyclic ethers with carbon nucleophiles
Citation Tetrahedron Lett. 1989, 45, 4293
DOI 10.1016/S0040-4020(01)81323-5
PROM-558
Promoter ZnBr2
Leaving_Group PhS(O)2-
Title C-glycoside?synthesis???? Direct substitution of 2-benzenesulphonyl cyclic ethers using organozinc reagents
Citation Tetrahedron Lett. 1988, 29, 4869
DOI 10.1016/S0040-4039(00)80630-9
PROM-56
Promoter TMSOTf
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1016/j.tetlet.2004.04.046
PROM-560
Promoter Zn(acac)2
Leaving_Group Cl
Title Zinc Salts Catalyzed Rhamnosylation
Citation Synlett. 1992, 797
DOI 10.1055/s-1992-21494
PROM-561
Promoter Zn(Ac)2
Leaving_Group Cl
Title daburi
Citation daburi
DOI 10.1055/s-1992-21494
PROM-562
Promoter Zn(CN)2
Leaving_Group Cl
Title daburi
Citation daburi
DOI 10.1055/s-1992-21494
PROM-563
Promoter Zn(OTf)2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1755
PROM-564
Promoter ZnO
Leaving_Group ?
Title Dilatatin, the first example of a C-allosylated natural product
Citation Phytochemistry? 1983, 22, 2827
DOI 10.1016/S0031-9422(00)97706-9
PROM-566
Promoter (p-tBuC6H4CO2)2Zn
Leaving_Group Cl
Title ZINC p-tert-BUTYLBENZOATE CATALYZED GLYCOSYLATION WITH GLYCOPYRANOSYL CHLORIDE
Citation Chem. Pharm. Bull. 1993, 41, 784
DOI 10.1248/cpb.41.784
PROM-567
Promoter HgCl2
Leaving_Group SEt, SPh
Title A potentially versatile synthesis of glycosides
Citation Carbohydr. Res. 1973, 27, 55
DOI 10.1016/S0008-6215(00)82424-6
PROM-568
Promoter HgCl2
Leaving_Group SEt
Title A stereoselective synthesis of digitoxin. On cardioactive steroids. XIII
Citation Can.J. Chem. 1984, 62, 1403
DOI 10.1139/v84-238
PROM-569
Promoter HgBr2
Leaving_Group Br
Title daburi
Citation daburi
DOI 10.1016/0008-6215(87)80138-6
PROM-57
Promoter TMSOTf
Leaving_Group -O-P(=NTs)-Ph2
Title AN EFFICIENT CONSTRUCTION OF 1, 2-TRANS-??-GLYCOSIDIC LINKAGES VIA BENZYL-PROTECTED GLYCOPYRANOSYL P, P-DIPHENYL-N-(p-TOLUENESULFONYL)-PHOSPHINIMIDATES
Citation Chem. Pharm. Bull. 1990, 38, 2323
DOI 10.1248/cpb.38.2323
PROM-570
Promoter Hg(OBz)2
Leaving_Group SPh
Title Reinvestigation of the preparation of cholesteryl 2,3,4,6-tetra-O-benzyl-??-D-glucopyranoside
Citation Carbohydr. Res. 1979, 70, 161
DOI 10.1016/S0008-6215(00)83281-4
PROM-571
Promoter Hg(OTf)2
Leaving_Group -OC(O)(CH2)3CC
Title Hg(OTf)2-catalyzed glycosylation using alkynoate as the leaving group
Citation Tetrahedron Lett. 2006, 47, 4729
DOI 10.1016/j.tetlet.2006.04.114
PROM-572
Promoter Hg(CN)2
Leaving_Group Br
Title Synthesis of O-(2-acetamido-2-deoxy-??-d-glucopyranosyl)-(1??3)-O-??-d-galactopyranosyl-(1??4)-2-acetamido-2-deoxy-d- glucopyranose and two related trisaccharides containing the ?glacto-N-biose II?h unit
Citation Carbohydr. Res. 1987, 169, 201
DOI 10.1016/0008-6215(87)80251-3
PROM-573
Promoter Hg(CN)2
Leaving_Group Br, p-NO2PhCOO-
Title Synthesis of a Lividomycin B Analogue, 5-O-[3-O-(2-Amino-2-deoxy-??-D-grlucopyranosyl)-??-D-ribofuranosyl]-3??-deoxyparomamine
Citation Bull. Chem. Soc. Jpn. 1977, 50, 2369
DOI 10.1246/bcsj.50.2369
PROM-574
Promoter Hg(CN)2
Leaving_Group ?
Title Synthesis and characterization of some anomeric pairs of per-O-acetylated aldohexopyranosyl cyanides (per-O-acetylated 2,6-anhydroheptononitriles). On the reaction of per-O-acetylaldohexopyranosyl bromides with mercuric cyanide in nitromethane
Citation Carbohydr. Res. 1984, 132, 61
DOI 10.1016/0008-6215(84)85065-X
PROM-575
Promoter Hg(CN)2
Leaving_Group Br
Title Glycosylated trehalose. Synthesis of the oligosaccharides of the glycolipid-type antigens from Mycobacterium smegmatis
Citation Carbohydr. Res. 1987, 164, 313
DOI 10.1016/0008-6215(87)80138-6
PROM-576
Promoter PhHgOTf
Leaving_Group SPh
Title A reinvestigation of glycosidation reactions using 1-thioglycosides as glycosyl donors and thiophilic cations as promoters
Citation Carbohydr. Res. 1983, 116, 162
DOI 10.1016/S0008-6215(00)90965-0
PROM-577
Promoter Sm(OTf)3
Leaving_Group pyS(O)2-
Title A Glycosylation Protocol Based on Activation of Glycosyl 2-Pyridyl Sulfones with Samarium Triflate
Citation Org. Lett. 2000, 2, 1505
DOI 10.1021/ol005579k
PROM-578
Promoter Sm(OTf)3
Leaving_Group trichloroimidate
Title Efficient activation of armed glycosyl trichloroacetimidates with Sm(OTf)3 in the stereoselective glycosidation of saccharidic acceptors
Citation Tetrahedron Lett. 2000, 41, 9005
DOI 10.1016/S0040-4039(00)01622-1
PROM-579
Promoter SmI2
Leaving_Group pyS(O)2-
Title Diastereocontrolled Synthesis of Carbon Glycosides of N-Acetylneuraminic Acid Wia Glycosyl Samarium(III) Intermediates
Citation J. Am. Chem. Soc. 1997, 119, 1480
DOI 10.1021/ja962703f
PROM-58
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OBu)2
Title Synthesis of 2?f-O-[(4?f?f-O-sorboyl)-??-L-fucopyranosyl]inosine: A Shimofuridin analogue
Citation Synlett. 1996, 313
DOI 10.1055/s-1996-5401
PROM-580
Promoter SmI2
Leaving_Group Cl
Title Synthesis of glycosyl chlorides with acid-labile protecting groups
Citation Tetrahedron Lett. 1996, 37, 4903
DOI 10.1016/0040-4039(96)01006-4
PROM-581
Promoter SmI2
Leaving_Group allylic phosphates
Title Samarium(II)-mediated reaction of allylic phosphate esters with carbonyl compounds: A new method for ?gUmpolung?h of allylic phosphates
Citation J. Organomet. Chem. 1987, 333, 329
DOI 10.1016/S0022-328X(00)99810-3
PROM-582
Promoter SmI2
Leaving_Group allylic phosphates
Title Samarium Diiodide Mediated Coupling of Glycosyl Phosphates with Carbon Radical or Anion Acceptors?%5CSynthesis of C-Glycosides
Citation Angew. Chem., Int. Ed. Engl. 1996, 35, 2671
DOI 10.1002/anie.199626711
PROM-583
Promoter SmI2
Leaving_Group SPh
Title The First Synthesis of Herbicidin B. Stereoselective Construction of the Tricyclic Undecose Moiety by a Conformational Restriction Strategy Using Steric Repulsion between Adjacent Bulky Silyl Protecting Groups on a Pyranose Ring
Citation J. Am. Chem. Soc. 1999, 121, 10270
DOI 10.1021/ja992608h
PROM-584
Promoter SmI2
Leaving_Group SO2Py
Title Stereoselective Synthesis of ??-C-Glucosamines via Anomeric Organosamarium Reagents
Citation Synlett 1998, 1393
DOI 10.1055/s-1998-1944
PROM-585
Promoter SmI2
Leaving_Group glycosyl pyridyl sulfones
Title 1,2-cis-C-glycoside synthesis by samarium diiodide-promoted radical cyclizations
Citation Chem. Eur. J. 1997, 3, 1342
DOI 10.1002/chem.19970030822
PROM-586
Promoter SmI2
Leaving_Group Glycosyl Samarium(III)
Title A Highly Stereoselective Synthesis of 1,2-trans-C-Glycosides via Glycosyl Samarium(III) Compounds
Citation Angew. Chem., Int. Ed. Engl. 1995, 34, 909
DOI 10.1002/anie.199509091
PROM-587
Promoter SmI2
Leaving_Group pyridylsulfone
Title Stereocontrolled synthesis of ??-C-galactosamine derivatives promoted by samarium diiodide: an example of chelation controlled C-glycosylation
Citation Chem. Commun. 1996, 1883
DOI 10.1039/CC9960001883
PROM-588
Promoter TiF4 or SnF4
Leaving_Group F
Title Aufbau von oligosacchariden mit glycosylfluoriden unter lewiss_ure-katalyse
Citation Carbohydr. Res. 1986, 149, 347
DOI 10.1016/S0008-6215(00)90057-0
PROM-589
Promoter TiF4
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97191-0
PROM-59
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OBu)2
Title Oligosaccharide Synthesis with Glycosyl Phosphate and Dithiophosphate Triesters as Glycosylating Agents
Citation J. Am. Chem. Soc. 2001, 123, 9545
DOI 10.1021/ja016227r
PROM-590
Promoter TiCl4
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1021/ja0767783
PROM-591
Promoter TiCl4
Leaving_Group ?
Title The unexpected intramolecular C-arylation of 2-0-benzylated cyclic sugar derivatives: a useful 1,2-cis-C-glycosylation reaction
Citation Tetrahedron Lett. 1985, 26, 2055
DOI 10.1016/S0040-4039(00)94777-4
PROM-592
Promoter TiCl4
Leaving_Group ?
Title Intramolecular C-arylation of benzylated sugars. The unexpected double C-glycosideration of tris-O-m-methoxybenzyl-??-D-ribofuranose derivatives
Citation J. Chem. Soc., Chem. Commun. 1986, 497
DOI 10.1039/C39860000497
PROM-593
Promoter TiCl4
Leaving_Group ?
Title Intramolecular C-arylation of 2,3,5-tri-O-benzyl- and 2,3,5-tri-O-(3-methylbenzyl)-pentofuranose derivatives
Citation Carbohydr. Res. 1987, 171, 211
DOI 10.1016/S0008-6215(00)90888-7
PROM-594
Promoter TiCl4
Leaving_Group ?
Title Multiple and long-range participation of benzyl groups in intramolecular C-arylation reactions of benzylated glycosides
Citation Carbohydr. Res. 1990, 202, 49
DOI 10.1016/0008-6215(90)84070-B
PROM-595
Promoter TiCl4
Leaving_Group OMe
Title Chelation-Controlled Regio- and Stereoselective C-Allylation of Glycosides and Related Cyclic Hemiacetals
Citation Synlett 1991, 702
DOI 10.1055/s-1991-34763
PROM-596
Promoter TiCl2(OTf)2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1996.629
PROM-597
Promoter Tl(NO3)3
Leaving_Group ?
Title C-Glycosylflavonoids. II. The synthesis of 7,4'-Di-O-methylpuerarin (8-C-??-D-Glucopyranosyl-7,4'-dimethoxyisoflavone)
Citation Aust. J. Chem. 1978, 31, 2699
DOI 10.1071/CH9782699
PROM-598
Promoter Me2GaCl, Me2GaOTf
Leaving_Group F
Title Gallium reagents in organic synthesis: Dimethylgallium chloride and triflate as activators in glycosidation using glycopyranosyl fluorides
Citation Tetrahedron Lett. 1990. 31, 2435
DOI 10.1016/S0040-4039(00)97382-9
PROM-599
Promoter [Rh(??)(MeCN)3(triphos)](TfO)3
Leaving_Group OH
Title Catalytic Glycosylation with Rhodium(III)-Triphos Catalysts
Citation Synlett. 2003, 1303
DOI 10.1055/s-2003-40337
PROM-6
Promoter TMSOTf
Leaving_Group COCCl3
Title Studies on Glycosides XIV. Stereoselectivity and Reactivity of New C1 Leaving Group Trichloroacetoxyl in Glycosylation Reaction
Citation Synth. Commun. 1995, 25, 1563
DOI 10.1080/00397919508011769
PROM-60
Promoter TMSOTf
Leaving_Group -O-P(=O)-(OBu)2
Title Synthesis and Use of Glycosyl Phosphates as Glycosyl Donors
Citation Org. Lett. 1999, 1, 211
DOI 10.1021/ol9905452
PROM-600
Promoter FeCl3, TMSOTf, BF3?EEt2O, LiClO4
Leaving_Group methyl dinitrosalicylate (DISAL)
Title DISAL glycosyl donors for efficient glycosylations under acidic conditions: Application to solid-phase oligosaccharide synthesis
Citation J. Chem. Soc., Perkin Trans. 2001, 1, 2175
DOI 10.1039/B105872J
PROM-601
Promoter FeCl3
Leaving_Group OAc
Title Stereoselective ??-glycosidation using FeCl3 as a Lewis acid catalyst
Citation Chem. Commun. 1998, 1729
DOI 10.1039/A804533J
PROM-602
Promoter FeCl3
Leaving_Group OAc
Title The snythesis of disaccharides by the ferric chloride-catalyzed coupling of 2-acylamido-2-deoxy-??-D-glucopyranose 1-acetates to protect sugar acceptors
Citation Carbohydr. Res. 1979, 72, C15
DOI 10.1016/S0008-6215(00)83963-4
PROM-603
Promoter FeCl3
Leaving_Group OAc
Title Synthesis of Ethyl and Phenyl 1-Thio-1,2-trans-D-Glycopyranosides from the Corresponding Per-O-Acetylated Glycopyranoses having a 1,2-trans-Configuration using Anhydrous Ferric Chloride as a Promoter
Citation Acta. Chem. Scand. 1989, 43, 471
DOI 10.3891/acta.chem.scand.43-0471
PROM-604
Promoter FeCl3
Leaving_Group OBz
Title Ferric chloride-molecular sieve-catalyzed formation of a nonreducing disaccharide derivative
Citation Carbohydr. Res. 1990, 207, 138
DOI 10.1016/0008-6215(90)80013-S
PROM-605
Promoter FeCl3
Leaving_Group OH
Title High-Yielding One-Step Conversion of D-Glucose and D-Galactose to the Corresponding ?? and ?? Methyl-D-glucofuranosides and Galactofuranosides
Citation Synth. Commun. 1991, 21, 815
DOI 10.1080/00397919108019762
PROM-607
Promoter La(ClO4)3?EnH2O (cat)
Leaving_Group F
Title Rare earth perchlorate catalyzed glycosidation of glycosyl fluorides with trimethylsilyl ethers
Citation Tetrahedron Lett. 1995. 36, 4443
DOI 10.1016/0040-4039(95)00760-A
PROM-608
Promoter Ni(4-F-PhCN)4(OTf)2
Leaving_Group trichloroimidate
Title Nickel-Catalyzed Stereoselective Formation of ??-2-Deoxy-2-Amino Glycosides
Citation J. Am. Chem. Soc. 2009, 131, 8778
DOI 10.1021/ja903123b
PROM-609
Promoter Ni(4-F-PhCN)4(OTf)2
Leaving_Group trichloroimidate
Title Nickel-Catalyzed Stereoselective Glycosylation with C(2)-N-Substituted Benzylidene D-Glucosamine and Galactosamine Trichloroacetimidates for the Formation of 1,2-cis-2-Amino Glycosides. Applications to the Synthesis of Heparin Disaccharides, GPI Anchor Pseudodisaccharides, and r-GalNAc
Citation J. Am. Chem. Soc. 2010, 132, 14288
DOI 10.1021/ja106682m
PROM-61
Promoter TMSOTf
Leaving_Group -O-P(=NPh)-(OEt)2
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(97)01418-4
PROM-610
Promoter Bi(OTf)3
Leaving_Group -O-C(=NPh)-CF3
Title Remarkably efficient activation of glycosyl trichloro- and (N-phenyl)trifluoroacetimidates with bismuth(III) triflate
Citation Tetrahedron Lett. 2006, 47, 2595
DOI 10.1016/j.tetlet.2006.02.034
PROM-611
Promoter Ph3Bi(OTf)2
Leaving_Group SPr
Title Bismuth(V)-Mediated Thioglycoside Activation
Citation Angew. Chem., Int. Ed. 2013, 52, 8441
DOI 10.1002/anie.201304099
PROM-612
Promoter BiCl3
Leaving_Group -O-P-(OMe)2
Title
Citation
DOI 10.1055/s-1993-22367
PROM-613
Promoter Et3Al
Leaving_Group F
Title Conversion of glycosyl fluorides into C-glycosides using organoaluminum reagents. Stereospecific alkylation at C-6 of a pyranose sugar
Citation Tetrahedron Lett. 1985, 26, 1823
DOI 10.1016/S0040-4039(00)94747-6
PROM-62
Promoter TMSOTf
Leaving_Group -O-P(=NPh)(NiPr2)(OEt)
Title daburi
Citation daburi
DOI 10.3987/COM-96-7466
PROM-621
Promoter Et2AlCl2
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1021/ja0767783
PROM-622
Promoter MoO2Cl2
Leaving_Group OAc
Title Highly Diastereoselective Thioglycosylation of Functionalized Peracetylated Glycosides Catalyzed by MoO2Cl2
Citation Org. Lett. 2006, 8, 5633
DOI 10.1021/ol062375g
PROM-623
Promoter TrSbCl6
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.79
PROM-624
Promoter monomethoxyTrSbCl6
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.79
PROM-625
Promoter lanthanide(III) triflate
Leaving_Group SPh, SOEt
Title A novel approach to the stereoselective synthesis of ??-d-mannopyranosides
Citation Tetrahedron Lett. 2001, 42, 4005
DOI 10.1016/S0040-4039(01)00643-8
PROM-626
Promoter Pd(PhCN)2(OTf)2
Leaving_Group trichloroimidate
Title Palladium-Controlled ??-Selective Glycosylation in the Absence of the C(2)-Ester Participatory Group
Citation J. Org. Chem. 2009, 74, 1650
DOI 10.1021/jo802468p
PROM-627
Promoter Pd(CH3CN)4(BF4)2
Leaving_Group trichloroimidate
Title Cationic Palladium(II)-Catalyzed Stereoselective Glycosylation with Glycosyl Trichloroacetimidates
Citation J. Org. Chem. 2008, 73, 794
DOI 10.1021/jo702436p
PROM-628
Promoter Pd(CH3CN)4(BF4)2
Leaving_Group trichloroimidate
Title Selective Formation of ??-O-Aryl Glycosides in the Absence of the C(2)-Ester Neighboring Group
Citation J. Org. Chem. 2009, 74, 4705
DOI 10.1021/jo9002807
PROM-629
Promoter Pd(ClO4)2
Leaving_Group SPy
Title Total synthesis of erythromycin
Citation J. Am. Chem. Soc. 1981, 103, 3215
DOI 10.1021/ja00401a051
PROM-63
Promoter TMSOTf
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.969
PROM-638
Promoter Pd2(DBA)3
Leaving_Group BocO
Title De Novo Synthesis of Oligosaccharides Using a Palladium-Catalyzed Glycosylation Reaction
Citation J. Am. Chem. Soc. 2004, 126, 3428
DOI 10.1021/ja039400n
PROM-64
Promoter TMSOTf
Leaving_Group SR
Title Stereoselective glycosylation using fully benzylated pyrimidin-2-yl 1-thio-??-d-glycopyranosides
Citation Carbohydr. Res. 1995, 272, 149
DOI 10.1016/0008-6215(95)00031-N
PROM-640
Promoter p-Ts2O
Leaving_Group 2_Deoxy-Sugars
Title A Reagent-Controlled SN2-Glycosylation for the Direct Synthesis of ??-Linked 2-Deoxy-Sugars
Citation J. Am. Chem. Soc., 2014, 136, 5740
DOI 10.1021/ja500410c
PROM-641
Promoter TfOH
Leaving_Group F
Title Trifluoromethanesulfonic Acid (TfOH)-Catalyzed Stereoselective Glycosylation Using Glycosyl Fluoride
Citation Chem Lett. 2000, 696
DOI 10.1246/cl.2000.696
PROM-642
Promoter TfOH
Leaving_Group F
Title 1,2-Cis Selective Glycosylation with Glycosyl Fluoride by Using a Catalytic Amount of Trifluoromethanesulfonic Acid (TfOH) in the Coexistence of Molecular Sieve 5_ (MS5_)
Citation Chem Lett. 2000, 1278
DOI 10.1246/cl.2000.1278
PROM-643
Promoter TfOH
Leaving_Group -O-P-(OEt)2
Title Chemoselective glycosidation strategy based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups: a convergent synthesis of ganglioside GM3
Citation Tetrahedron Lett. 2000, 41, 7691
DOI 10.1016/S0040-4039(00)01343-5
PROM-644
Promoter TfOH
Leaving_Group -O-P-(OBn)2
Title A convenient and highly stereoselective approach for ??-galactosylation performed by galactopyranosyl dibenzyl phosphite with remote participating groups
Citation Tetrahedron Lett. 2002, 43, 7721
DOI 10.1016/S0040-4039(02)01849-X
PROM-645
Promoter TfOH
Leaving_Group -O-C(=N-p-CF3Ph)(S-p-CF3Bn)
Title Catalytic and Stereoselective Glycosylation with a Novel and Efficient Disarmed Glycosyl Donor: Glycosyl p-Trifluoromethylbenzylthio-p-trifluoromethylphenyl Formimidate
Citation
DOI 10.1246/cl.2002.392
PROM-646
Promoter TfOH
Leaving_Group -O-C(=N-p-CF3Ph)(S-p-CF3Bn)
Title Catalytic and Chemoselective Glycosylation between ?e?eArmed?f?f and ?e?eDisarmed?f?f Glycosyl p-Trifluoromethylbenzylthio-p-trifluoromethylphenyl Formimidates
Citation
DOI 10.1246/cl.2002.746
PROM-647
Promoter TfOH
Leaving_Group -O-C(=N-p-CF3Ph)(S-p-CF3Bn)
Title Highly ??-Stereoselective One-pot Sequential Glycosylation Using Glucosyl Thioformimidate Derivatives
Citation
DOI 10.1246/cl.2003.172
PROM-648
Promoter TfOH
Leaving_Group -O-C(=N-p-CF3Ph)(S-p-CF3Bn), trichloroimidate, F
Title daburi
Citation daburi
DOI 10.1246/cl.2003.340
PROM-649
Promoter TfOH
Leaving_Group -O-C(=N-p-CF3Ph)(S-p-CF3Bn)
Title Catalytic and Stereoselective Glycosylation with Glucosyl Thioformimidates
Citation
DOI 10.1246/bcsj.76.1629
PROM-65
Promoter TMSOTf
Leaving_Group trichloroimidate
Title N??-Fmoc-Ser[Ac4-??-d-Gal p-(1 ?? 3)-Ac2-??-d-GalN3 p]-OPfp and N??-Fmoc-Thr[Ac4-??-d-Gal p-(1 ?? 3)-Ac2-??-d-GalN3 p]-OPfp and the application in the solid-phase peptide synthesis of multiply glycosylated mucin peptides with Tn and T antigenic structures
Citation Carbohydr.?Res. 1995, 268, 17
DOI 10.1016/0008-6215(94)00292-N
PROM-650
Promoter TfOH
Leaving_Group PhS(O)-
Title A one step synthesis of the ciclamycin trisaccharide
Citation J. Am. Chem. Soc. 1993, 115, 1580
DOI 10.1021/ja00057a056
PROM-651
Promoter TfOH
Leaving_Group F
Title ?ionic liquid solvent 1-n-Hexyl-3-methylimidazolium?OTf (C6mim[OTf]), 1-(3-cyanopropyl)-3-methylimidazolium?NTf2 (CNC3mim[NTf2])
Citation Tetrahedron Lett. 2004, 45, 7043
DOI 10.1016/j.tetlet.2004.07.128
PROM-652
Promoter TfOH
Leaving_Group trichloroimidate
Title Synthesis of 4-O-(??-L-Rhamnopyranosyl-D-Glucopyranuronic Acid
Citation J. Carbohydr. Chem. 1987, 6, 377
DOI 10.1080/07328308708057927
PROM-653
Promoter TfOH
Leaving_Group trichloroimidate
Title Synthesis of 6-O-??-d-glucopyranosylcyclomaltoheptaose
Citation Carbohydr. Res. 1988, 175, 173
DOI 10.1016/0008-6215(88)84140-5
PROM-654
Promoter TfOH
Leaving_Group OH
Title 6-Nitro-2-benzothiazolyl ??-Glucoside and ??-Mannoside in ??-Selective Glycosylations
Citation Bull. Chem. Soc. Jpn. 2004. 77, 169
DOI 10.1246/bcsj.77.169
PROM-655
Promoter TfOH
Leaving_Group OH
Title Use of Trifluoromethanesulfonic Acid in Fischer Glycosylations
Citation J. Carbohydr. Chem. 1988, 7, 263
DOI 10.1080/07328308808058919
PROM-656
Promoter TfOH
Leaving_Group OH
Title Conditions for modified fischer glycosidations with n-pentenol and other alcohols
Citation Red. Trav. Chim. Pays-Bas 1991, 110, 23
DOI 10.1002/recl.19911100106
PROM-657
Promoter TfOH
Leaving_Group OC(NPh)CF3
Title ??-Rhamnosides from 6-thio mannosides
Citation Chem. Commun. 2012, 48, 2686
DOI 10.1039/C2CC17623H
PROM-658
Promoter TfOH
Leaving_Group -OC(NPh)CF3
Title A General Strategy for the Chemoenzymatic Synthesis of Asymmetrically Branched N-Glycans
Citation Science, 2013, 341, 379
DOI 10.1126/science.1236231
PROM-659
Promoter TfOH
Leaving_Group -OC(=NH)CCl3
Title Total Synthesis of (+)-Neocarzinostatin
Citation J. Am. Chem. Soc. 1998, 120,?5319
DOI 10.1021/ja980588y
PROM-66
Promoter TMSOTf
Leaving_Group OAc
Title Reactions of Partially Acylated Aldohexopyranosides, VIII. A New Synthesis of the Tetradeoxydisaccharide in Avermectins
Citation Liebigs Ann. Chem. 1992, 103
DOI 10.1002/jlac.199219920121
PROM-660
Promoter Tf2O
Leaving_Group F
Title ??-Glucosylation Reactions with 2,3,4,6-Tetra-O-Benzyl-??-D-Glucopyranosyl Fluoride and Triflic Anhydride as Promoter
Citation J. Carbohydr. Chem. 1991, 10, 901
DOI 10.1080/07328309108543958
PROM-661
Promoter Tf2O
Leaving_Group ?
Title Mecanisme de la reaction de glycosylation par reversion acide en presence d'anhydride trifluoromethane sulfonique
Citation Can. J. Chem. 1981, 59, 482
DOI 10.1139/v81-069
PROM-662
Promoter Tf2O
Leaving_Group ?
Title Mechanism of a Chemical Glycosylation Reaction
Citation Acc. Chem. Res. 2010, 43, 1144
DOI 10.1021/ar100035r
PROM-663
Promoter Tf2O
Leaving_Group 2'-caboxybenzyl glycoside
Title Dual Stereoselectivity of 1-(2??-Carboxy)benzyl 2-Deoxyglycosides as Glycosyl Donors in the Direct Construction of 2-Deoxyglycosyl Linkages
Citation Angew. Chem. Int. Ed. 2003, 42, 459
DOI 10.1002/anie.200390139
PROM-664
Promoter Tf2O
Leaving_Group 2'-caboxybenzyl glycoside
Title Acceptor-Dependent Stereoselective Glycosylation:_ 2?e-CB Glycoside-Mediated Direct ??-d-Arabinofuranosylation and Efficient Synthesis of the Octaarabinofuranoside in Mycobacterial Cell Wall
Citation Org. Lett. 2005, 7, 3263
DOI 10.1021/ol0510668
PROM-665
Promoter Tf2O
Leaving_Group F
Title Comparison of catalysts in ??-glucosylation reactions and identification of triflic anhydride as a new reactive promoter
Citation Tetrahedron Lett. 1990. 31, 6863
DOI 10.1016/S0040-4039(00)97191-0
PROM-666
Promoter Tf2O
Leaving_Group S(O)Ph
Title Mannosazide Methyl Uronate Donors, Construction of ??-ManNAcA-Containing Oligosaccharides
Citation J. Org. Chem. 2010, 75, 7990
DOI 10.1021/jo101779v
PROM-667
Promoter Tf2O
Leaving_Group trichloroimidate
Title Triflic Anhydride: An Alternative Promoter in Glycosidations
Citation J. Carbohydr. Chem. 1992, 11, 255
DOI 10.1080/07328309208017992
PROM-668
Promoter Tf2O
Leaving_Group isopropenyl, n-pentenyl ?glycoside
Title daburi
Citation daburi
DOI 10.1016/0040-4039(94)88449-8
PROM-669
Promoter Tf2O
Leaving_Group SR
Title Improved Synthesis of 1?]Benzenesulfinyl Piperidine and Analogs for the Activation of Thioglycosides in Conjunction with Trifluoromethanesulfonic Anhydride
Citation J. Carbohydr. Chem. 2005, 24, 415
DOI 10.1081/CAR-200066978
PROM-67
Promoter TMSOTf
Leaving_Group OAc
Title Synthesis of N-Substituted 1-Amino-2,3-dihydro-1H-imidazole-2-thione-N-nucleosides and S-Glycosylated Derivatives
Citation Nucleosides Nucleotides Nucleic Acids 2003, 22, 299
DOI 10.1081/NCN-120021429
PROM-670
Promoter Tf2O
Leaving_Group ?
Title Direct synthesis of ??-d-Xyl-(1??2)-??-d-Man-(1??4)-??-d-Glc-OME: a trisaccharide component of the Hyriopsis schlegelii glycosphingolipid
Citation Tetrahedron Lett. 1998, 39, 1681
DOI 10.1016/S0040-4039(98)00124-5
PROM-671
Promoter Tf2O
Leaving_Group ?
Title Direct synthesis of ??-mannosides. Synthesis of ??-D-xyl-(1??2)-??-D-man-(1??4)-??-D-Glc-OMe: A trisaccharide component of the Hyriopsis schlegelii glycosphingolipid. Formation of an orthoester from a xylopyranosyl sulfoxide
Citation Tetrahedron. 1999, 55, 1569
DOI 10.1016/S0040-4020(98)01202-2
PROM-672
Promoter Tf2O
Leaving_Group ?
Title Synthesis of glycosyl halides and glycosides via 1-O-sulfonyl derivatives
Citation Carbohydr. Res. 1978, 67, 163
DOI 10.1016/S0008-6215(00)83739-8
PROM-673
Promoter Tf2O
Leaving_Group ?
Title Direct chemical synthesis of ??-mannopyranosides and other glycosides via glycosyl triflates
Citation Tetrahedron 1998, 54, 8321
DOI 10.1016/S0040-4020(98)00426-8
PROM-674
Promoter Tf2O
Leaving_Group ?
Title Synthesis of N-glycosides. Formation of glucosylamine by reaction of 2,3,4,6-tetra-O-benzyl-D-glucopyranose with acetonitrile
Citation J. Org. Chem. 1981, 46, 3158
DOI 10.1021/jo00328a045
PROM-675
Promoter Tf2O
Leaving_Group OH
Title Strained olefin enables triflic anhydride mediated direct dehydrative glycosylation
Citation Org. Biomol. Chem. 2014,12, 9781
DOI 10.1039/C4OB01807A
PROM-676
Promoter Tf2O
Leaving_Group ?
Title Steric control in the polymerization of 1,2-anhydro-3,4,6-tri-O-benzyl-??-d-mannopyranose
Citation Carbohydr. Res. 1985, 135, 195
DOI 10.1016/S0008-6215(00)90771-7
PROM-677
Promoter Tf2O, TfOH
Leaving_Group PhS(O)-
Title Glycosylation of unreactive substrates
Citation J. Am. Chem. Soc. 1989, 111, 6881
DOI 10.1021/ja00199a081
PROM-678
Promoter Tf2O
Leaving_Group PhS(O)-, F
Title Completion of the Synthesis and Analogue Synthesis and Evaluation
Citation J. Am. Chem. Soc. 2003, 125, 15443
DOI 10.1021/ja030496v
PROM-679
Promoter HB(C6F5)4, HClO4, HNTf2 and more
Leaving_Group F, trichloroimidate
Title A Catalytic and Stereoselective Glycosylation with Glucopyranosyl Fluoride by Using Various Protic Acids
Citation Chem Lett. 2001, 426
DOI 10.1246/cl.2001.426
PROM-68
Promoter TMSOTf
Leaving_Group OBz
Title Carbohydrates as chiral auxiliaries: synthesis of 2-hydroxy-??-D-glucopyranosides
Citation Tetrahedron Lett. 1991, 32, 7215
DOI 10.1016/0040-4039(91)80479-P
PROM-680
Promoter TfOH or HClO4
Leaving_Group F
Title Highly -Selective Glycosylation with Glycopyranosyl Fluorides Having Diethylthiocarbamoyl Group
Citation Chem. Lett. 2002, 56
DOI 10.1246/cl.2002.56
PROM-681
Promoter HClO4(cat)
Leaving_Group OAc
Title Perchloric Acid in 1,4-Dioxane and Perfluorooctanesulfonic Acid as Practical Catalysts for the Stereoselective Glycosylation of 1-O-Acetylglycosides
Citation Heterocycles 2000, 52, 1203
DOI 10.3987/COM-99-S123
PROM-682
Promoter PPTS
Leaving_Group OH
Title A Facile Synthesis of 3-Deoxy-??-D-manno-2-octulopyranosides Using Pyridinium p-Toluenesulfonate
Citation Chem. Lett. 1991, 20, 117
DOI 10.1246/cl.1991.117
PROM-683
Promoter PPTS
Leaving_Group trichloroimidate
Title Total synthesis of amphotericin B
Citation J. Am. Chem. Soc. 1987, 109, 2821
DOI 10.1021/ja00243a043
PROM-684
Promoter C8F17SO3H (cat)
Leaving_Group OAc
Title First synthesis of astilbin, biologically active glycosyl flavonoid isolated from Chinese folk medicine
Citation Tetrahedron Lett. 2000, 41, 5537
DOI 10.1016/S0040-4039(00)00826-1
PROM-685
Promoter Nafion-H
Leaving_Group PhS(O)
Title Novel stereocontrolled ??- and ??-glycosidations of mannopyranosyl sulfoxides using environmentally benign heterogeneous solid acids
Citation Tetrahedron Lett. 2001, 42, 4159
DOI 10.1016/S0040-4039(01)00674-8
PROM-686
Promoter H3PO4
Leaving_Group 3-methoxypyridines (MOP)
Title One-Step, Stereocontrolled Synthesis of Glycosyl 1-Phosphates, Uridine-5?e-diphosphogalactose, and Uridine-5?e-diphosphoglucose from Unprotected Glycosyl Donors
Citation J. Am. Chem. Soc. 1998, 120, 13296
DOI 10.1021/ja982783i
PROM-687
Promoter MeONa
Leaving_Group S-Box? (S-benzoxazolyl)
Title S-Benzoxazolyl as a Stable Protecting Moiety and a Potent Anomeric Leaving Group in Oligosaccharide Synthesis
Citation J. Org. Chem. 2007, 72, 6947
DOI 10.1021/jo071191s
PROM-688
Promoter NaH
Leaving_Group OH
Title Stereoselective Synthesis of 2-Deoxy-??-glycosides Using Anomeric O-Alkylation/Arylation
Citation Org. Lett. 2009, 11, 9
DOI 10.1021/ol8022006
PROM-689
Promoter NaH
Leaving_Group OH
Title Ring-Opening of Aziridine-2-Carboxamides with Carbohydrate C1-O-Nucleophiles. Stereoselective Preparation of ??- and ??-O-Glycosyl Serine Conjugates
Citation J. Am. Chem. Soc. 2008, 130, 15228
DOI 10.1021/ja804589j
PROM-69
Promoter TMSOTf
Leaving_Group OCOC6H4-o-CO2Bn(benzyl phthalate)
Title Glycosylation with glycosyl benzyl phthalates as a new type of glycosyl donor
Citation Org. Biomol. Chem. 2004, 2, 2408
DOI 10.1039/B405793G
PROM-690
Promoter KH
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1021/ja804589j
PROM-691
Promoter KOH
Leaving_Group Br
Title Preparation and some reactions of D-glucosyl derivatives of 2-thioxo-1,3,4-oxadiazoles and 2-thioxo-1,3,4-thiadiazoles and their 2-oxo analogues
Citation Carbohydr. Res. 1977, 59, 95
DOI 10.1016/S0008-6215(00)83296-6
PROM-696
Promoter n-BuLi
Leaving_Group nBuSn
Title Stereospecific generation of ??- and ??-glycosyl-lithium reagents from glycosyl-stannanes: a stereocontrolled route to ??- and ??-C-glycosides
Citation Chem. Soc., Chem. Commun. 1985, 894
DOI 10.1039/C39850000894
PROM-698
Promoter Sat. NaHCO3
Leaving_Group OH
Title Single step stereoselective synthesis of unprotected 2,4-dinitrophenyl glycosides
Citation Tetrahedron Lett., 1995, 36, 5627
DOI 10.1016/0040-4039(95)01031-C
PROM-699
Promoter LDA
Leaving_Group ?
Title Synthesis of carbon-bridged N-acetyl-c-lactosamine and derivatives
Citation Liebigs Ann. Chem. 1995, 2113
DOI 10.1002/jlac.1995199512297
PROM-7
Promoter TMSOTf
Leaving_Group COCF3
Title Studies on Glycosides. X. An Alternate Method For Highly Stereoselective Synthesis of Alkyl-??-D-glucopyranosides
Citation Synth. Commun. 1992, 22, 2121
DOI 10.1080/00397919208021347
PROM-70
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Trichloroacetimidates as Glycosyl Donors in Recyclable Ionic Liquids
Citation Synlett 2003, 2297
DOI 10.1055/s-2003-42099
PROM-700
Promoter LDA
Leaving_Group ?
Title C-1 lithiation of C-2 activated glucals
Citation Tetrahedron Lett. 1987, 28, 6591
DOI 10.1016/S0040-4039(00)96921-1
PROM-701
Promoter Sn(OTf)2-collidine
Leaving_Group ?
Title Stannous triplate mediated glycosidations. A sterroselective synthesis of ??-D-glucosides
Citation Tetrahedron Lett. 1985. 26, 1713
DOI 10.1016/S0040-4039(00)98319-9
PROM-702
Promoter Sn(OTf)2-TMU
Leaving_Group Cl
Title Stannous triflate mediated glycosidations. A stereoselective synthesis of 2-amino 2-deoxy-??-D-glucopyranosides directly with the natural N-acetyl protecting group
Citation Tetrahedron Lett. 1987. 28, 5041
DOI 10.1016/S0040-4039(00)96690-5
PROM-703
Promoter Sn(OTf)2-BF3?EEt2O
Leaving_Group -O-P-(OCH2CCl3)2
Title Utility of glycosyl phosphites as glycosyl donors-fructofuranosyl and 2-deoxyhexopyranosyl phosphites in glycoside bond formation
Citation Tetrahedron Lett. 1994, 35, 4763
DOI 10.1016/S0040-4039(00)76961-9
PROM-704
Promoter Sn(OTf)2/TMSCl
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1997.969
PROM-705
Promoter TrCl-ZnCl2
Leaving_Group Br
Title Novel Stereoselective Glycosidation by the Combined Use of Trityl Halide and Lewis Acid
Citation Chem. Pharm. Bull. 1990, 38, 3280
DOI 10.1248/cpb.38.3280
PROM-706
Promoter I2-DDQ
Leaving_Group Cl, Br
Title Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ
Citation Tetrahedron Lett. 1996. 37, 8807
DOI 10.1016/S0040-4039(96)01995-8
PROM-707
Promoter Cu(OTf)2-BTF
Leaving_Group Cl, Br
Title A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride
Citation Carbohydr. Res. 2002, 337, 581
DOI 10.1016/S0008-6215(02)00029-0
PROM-709
Promoter SnCl2-AgClO4
Leaving_Group F
Title AN EFFICIENT METHOD FOR GLUCOSYLATION OF HYDROXY COMPOUNDS USING GLUCOPYRANOSYL FLUORIDE
Citation Chem Lett. 1981, 10, 431
DOI 10.1246/cl.1981.431
PROM-71
Promoter TMSOTf
Leaving_Group trichloroimidate
Title daburi
Citation daburi
DOI 10.1002/jlac.198519851211
PROM-710
Promoter NIS-AgOTf
Leaving_Group SPh
Title Practical Approach for the Stereoselective Introduction of ??-Arabinofuranosides
Citation J. Am. Chem. Soc. 2006, 128, 11948
DOI 10.1021/ja0629817
PROM-711
Promoter NIS-AgOTf
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97609-3
PROM-712
Promoter NIS-AgOTf
Leaving_Group S-Php-O-C8H17
Title Odorless benzenethiols in synthesis of thioglycosides and its application for glycosylation reactions
Citation Bioorg. Med. Chem. Lett. 2006, 16, 5736
DOI 10.1016/j.bmcl.2006.08.095
PROM-713
Promoter NIS-AgOTf
Leaving_Group SEt
Title 2-N-Acetyl-2N,3O-oxazolidinone-Protected Glucosamine Donors
Citation J. Org. Chem. 2008, 73, 7181
DOI 10.1021/jo800971s
PROM-714
Promoter NIS-AgOTf
Leaving_Group S(O)Tol, STol
Title ??-and ??-Arabinofuranosyl Linkages, 2,3-Anhydro Sugars in Glycoside Bond Synthesis
Citation J. Am. Chem. Soc. 2003, 125, 4155
DOI 10.1021/ja029302m
PROM-715
Promoter NIS-AgOTf
Leaving_Group S(O)Tol, STol
Title daburi
Citation daburi
DOI 10.1021/jo061440x
PROM-716
Promoter NIS-AgOTf
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-717
Promoter NIS-AgOTf
Leaving_Group STol, S(O)Tol
Title Stereocontrolled Synthesis of 2,3-Anhydro-??-d-lyxofuranosyl Glycosides
Citation Org. Lett. 2001, 3, 607
DOI 10.1021/ol007008y
PROM-718
Promoter NIS-AgOTf
Leaving_Group STol, S(O)Tol
Title 2,3-Anhydro Sugars in Glycoside Bond Synthesis. Highly Stereoselective Syntheses of Oligosaccharides Containing ??- and ??-Arabinofuranosyl Linkages
Citation J. Am. Chem. Soc. 2003, 125, 4155
DOI 10.1021/ja029302m
PROM-719
Promoter NIS-AgOTf
Leaving_Group STol
Title Ligand Specificity of CS-35, a Monoclonal Antibody That Recognizes Mycobacterial Lipoarabinomannan:_ A Model System for Oligofuranoside?|Protein Recognition
Citation J. Am. Chem. Soc. 2007, 129, 10489
DOI 10.1021/ja0723380
PROM-72
Promoter TMSOTf
Leaving_Group N-Glycosyl Triazoles
Title Glycoside and Saccharide Synthesis Using N-Glycosyl Triazoles as Hydrolytically Stable Glycosyl Donors
Citation Synlett 1990, 251
DOI 10.1055/s-1990-21051
PROM-721
Promoter NIS-AgOTf
Leaving_Group STol, -C(NH)CCl3
Title daburi
Citation daburi
DOI 10.1021/ja072892+
PROM-722
Promoter NIS-AgOTf
Leaving_Group SEt, trichloroacetimidate
Title Synthetic GPI as a candidate anti-toxic vaccine in a model of malaria
Citation Nature 2002, 418, 785
DOI 10.1038/nature00937
PROM-723
Promoter NIS-In(OTf)3
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-724
Promoter NIS-Sn(OTf)2
Leaving_Group 4-pentenyl Glycoside
Title Studies on (??,1??5) and (??,1??6) linked octyl Galf disaccharides as substrates for mycobacterial galactosyltransferase activity
Citation Bioorg. Med. Chem. 2001, 9, 3129
DOI 10.1016/S0968-0896(01)00179-1
PROM-725
Promoter NIS-Sn(OTf)2
Leaving_Group ?
Title A General and Diastereoselective Synthesis of 1,2-cis-Hexofuranosides from 1,2-trans-Thiofuranosyl Donors
Citation Eur. J. Org. Chem. 2000, 1423
DOI 10.1002/(SICI)1099-0690(200004)2000:8<1423::AID-EJOC1423>3.0.CO;2-9
PROM-726
Promoter NIS-LiClO4
Leaving_Group ?
Title Concise Synthesis of 3-O-(2-O-??-d-Glucopyranosyl-6-O-acyl-??-d-glucopyranosyl)-1,2-di-O-acyl-sn-glycerols
Citation Tetrahedron 2000, 56, 8451
DOI 10.1016/S0040-4020(00)00793-6
PROM-727
Promoter NBS-AgOTf
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-728
Promoter NBS-In(OTf)3
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-729
Promoter CuBr2-Bu4NBr
Leaving_Group SMe, SEt
Title An efficient approach to O-glycosides through CuBr2-Bu4NBr mediated activation of glycosides
Citation Carbohydr. Res. 1986, 155, C6
DOI 10.1016/S0008-6215(00)90163-0
PROM-73
Promoter TMSOTf
Leaving_Group OH
Title An imrpoved practical method for synthesis of aryl C-glycosides from unprotected methyl glycosides and 1-hydroxy sugars
Citation J. Chem. Soc., Chem. Commun. 1994, 997
DOI 10.1039/C39940000997
PROM-730
Promoter CuBr2-Bu4NBr
Leaving_Group ?
Title Synthesis of oligosaccharides containing the X-antigenic trisaccharide (??-l-Fucp-(1??3)-[??-d-Galp-(1??4)]-??-d-GlcpNAc) at their nonreducing ends
Citation Carbohydr. Res. 1992, 226, 91
DOI 10.1016/0008-6215(92)84057-Y
PROM-731
Promoter PhSeNPhth-TMSOTf
Leaving_Group SMe, SPh
Title PeSeNPhth-TMSOTf as a Promotor of Thioglycoside
Citation Synlett. 1994, 535
DOI 10.1055/s-1994-22919
PROM-732
Promoter PhSeOTf-TTBP
Leaving_Group pentenoate
Title A Highly Reactive and Stereoselective ??-Mannopyranosylation System: Mannosyl 4-Pentenoate/PhSeOTf
Citation Angew. Chem. Int. Ed. 2006, 45, 7436
DOI 10.1002/anie.200602642
PROM-733
Promoter MgBr2?EEt2O
Leaving_Group PhS(O)2-
Title Preparation of cyclic ether acetals from 2-benzenesulphonylderivatives: a new mild glycosidation procedure
Citation Tetrahedron Lett. 1988, 29, 4873
DOI 10.1016/S0040-4039(00)80631-0
PROM-734
Promoter MgBr2?EEt2O
Leaving_Group PhS(O)2-
Title Use of 2-phenylsulphonyl cyclic ethers in the preparation of tetrahydropyran and tetrahydrofuran acetals and in some glycosidation reactions
Citation Tetrahedron 1991, 47, 1329
DOI 10.1016/S0040-4020(01)86389-4
PROM-735
Promoter PhIO-Mg(ClO4)2
Leaving_Group SMe, SPh
Title daburi
Citation daburi
DOI 10.1055/s-1998-1575
PROM-736
Promoter SO4/ZrO2
Leaving_Group F
Title Novel Stereocontrolled Glycosidations Using a Solid Acid, SO4/ZrO2, for Direct Syntheses of ??- and ??-Mannopyranosides
Citation Synlett. 1998, 643
DOI 10.1055/s-1998-1741
PROM-737
Promoter SO4/ZrO2
Leaving_Group F
Title Novel Stereocontrolled Glycosidations of 2-Deoxyglucopyranosyl Fluoride Using a Heterogeneous Solid Acid, Sulfated Zirconia (SO4/ZrO2)
Citation Synlett. 1999, 813
DOI 10.1055/s-1999-2742
PROM-738
Promoter SO4/ZrO2
Leaving_Group F
Title Stereocontrolled glycosidations using a heterogeneous solid acid, sulfated zirconia, for the direct syntheses of ??- and ??-manno- and 2-deoxyglucopyranosides
Citation Tetrahedron. 2004. 60, 5331
DOI 10.1016/j.tet.2004.04.071
PROM-739
Promoter SO4/ZrO2
Leaving_Group PhS(O)-
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(01)02252-3
PROM-74
Promoter TMSOTf
Leaving_Group OH
Title Aryl and Allyl C-Glycosidation Methods Using Unprotected Sugars
Citation J. Org. Chem. 1998, 63, 2307
DOI 10.1021/jo972146v
PROM-740
Promoter SO4/ZrO2
Leaving_Group F
Title Novel Stereocontrolled Glycosidations Using a Solid Acid, SO4/ZrO2, for Direct Syntheses of ??- and ??-Mannopyranosides
Citation Synlett 1998, 643
DOI 10.1055/s-1998-1741
PROM-741
Promoter SO4/ZrO2
Leaving_Group F
Title Novel Stereocontrolled Glycosidations of 2-Deoxyglucopyranosyl Fluoride Using a Heterogeneous Solid Acid, Sulfated Zirconia (SO4/ZrO2)
Citation Synlett 1999, 813
DOI 10.1055/s-1999-2742
PROM-742
Promoter SO4/ZrO2
Leaving_Group PhS(O)
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(01)00674-8
PROM-743
Promoter Br2-AgOTf
Leaving_Group SEt
Title The in situ activation of thioglycosides with bromine: an improved glycosylation method
Citation J. Org. Chem. 1990, 55, 2860
DOI 10.1021/jo00296a055
PROM-744
Promoter Br2-AgOTf
Leaving_Group SEt
Title An unusual glycosylation product from a partially protected fucosyl donor under silver triflate activation conditions
Citation Org. Biomol. Chem. 2013, 11, 8452.
DOI 10.1039/C3OB42073F
PROM-745
Promoter Br2-Ag2CO3
Leaving_Group ?
Title Syntheses of Isomaltose, Isomaltotetraose, and Isomaltooctaose
Citation Bull. Chem. Soc. Jpn. 1973, 46, 2520
DOI 10.1246/bcsj.46.2520
PROM-746
Promoter IBr-AgOTf
Leaving_Group SPh
Title Study of Interhalogens/Silver Trifluoromethanesulfonate as Promoter Systems for High-Yielding Sialylations
Citation J. Org. Chem. 2002, 67, 7407
DOI 10.1021/jo0262412
PROM-747
Promoter IBr-AgOTf
Leaving_Group SMe
Title Interhalogens (ICl/IBr) and AgOTf in Thioglycoside Activation; Synthesis of Bislactam Analogues of Ganglioside GD3
Citation J. Org. Chem. 2004, 69, 6249
DOI 10.1021/jo049184g
PROM-748
Promoter IBr-AgOTf
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-749
Promoter IBr-In(OTf)3
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-75
Promoter TMSOTf
Leaving_Group ?
Title Nitriles as Solvents in Glycosylation Reactions: Highly Selective ??-Glycoside Synthesis
Citation Synlett. 1990, 694
DOI 10.1055/s-1990-21214
PROM-750
Promoter ICl-AgOTf
Leaving_Group SMe
Title daburi
Citation daburi
DOI 10.1021/jo049184g
PROM-751
Promoter ICl-AgOTf
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-752
Promoter ICl-AgOTf
Leaving_Group SEt, SMe, SPh
Title Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a Convenient Promoter System for O-Glycoside Synthesis
Citation Org. Lett. 2001, 3, 913
DOI 10.1021/ol015547c
PROM-753
Promoter ICl-In(OTf)3
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-754
Promoter PhIO-AgOTf
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-755
Promoter PhIO-In(OTf)3
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-756
Promoter SnCl2-TrClO4
Leaving_Group F
Title STEREOSELECTIVE SYNTHESIS OF 1,2-CIS-GLYCOFURANOSIDES USING GLYCOFURANOSYL FLUORIDES?
Citation Chem Lett. 1983, 935
DOI 10.1246/cl.1983.935
PROM-757
Promoter Sn(OTf)2-DTBP
Leaving_Group SEt, -C(NH)CCl3, F, S(O)Ph
Title daburi
Citation daburi
DOI 10.1021/ja809554x
PROM-758
Promoter (MeO)2P(=S)-S-Br/AgOTf
Leaving_Group STol
Title O,O-Dimethylthiophosphonosulfenyl bromide-silver triflate: a new powerful promoter system for the preactivation of thioglycosides
Citation Org. Biomol. Chem. 2011, 9, 616
DOI 10.1039/C0OB00380H
PROM-759
Promoter TMSOTf_AgClO4
Leaving_Group OH
Title c-Arylglycosylation of unprotected free sugar
Citation J. Chem. Soc., Chem. Commun. 1992, 1641
DOI 10.1039/C39920001641
PROM-76
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Total Synthesis of Eleutherobin and Eleuthosides A and B
Citation J. Am. Chem. Soc. 1998, 120,?8674
DOI 10.1021/ja9810639
PROM-760
Promoter TMSOTf?|AgClO4 or TMSOTf
Leaving_Group OH
Title Aryl and Allyl C-Glycosidation Methods Using Unprotected Sugars
Citation J. Org. Chem. 1998, 63, 2307
DOI 10.1021/jo972146v
PROM-761
Promoter TMSOTf-AgClO4
Leaving_Group OMe
Title Efficient C-arylglycosylation of 1-O-methyl sugar by novel use of TMSOTf-AgClO4 catalyst system
Citation Tetrahedron Lett. 1992, 33, 2175
DOI 10.1016/0040-4039(92)88170-A
PROM-762
Promoter TMSOTf-AgClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1021/jo972146v
PROM-763
Promoter MeOTf, Cu(OTf)2, or Yb(OTf)2
Leaving_Group 3'-methoxy-2'-pyridil glycoside
Title Practical syntheses of B disaccharide and linear B type 2 trisaccharide?%5Cnon-primate epitope markers recognized by human anti-??-Gal antibodies causing hyperacute rejection of xenotransplants
Citation Tetrahedron 2001, 57, 3267
DOI 10.1016/S0040-4020(01)00196-X
PROM-764
Promoter AgOTf, p-TsSCl
Leaving_Group STol
Title Highly Stereoselective Glycosyl-Chloride-Mediated Synthesis of 2-Deoxyglucosides
Citation Chem. - Eur. J. 2013, 19, 846
DOI 10.1002/chem.201203418
PROM-765
Promoter AgOTf-TMSOTf
Leaving_Group ?
Title The stereocontrolled synthesis of 1,2-cis furanosyl nucleosides via a novel anomeric activation
Citation Tetrahedron Lett. 1995, 36, 5865
DOI 10.1016/0040-4039(95)01179-L
PROM-766
Promoter AgPF6-DTBMP
Leaving_Group SPh
Title A Direct and Efficient ??-Selective Glycosylation Protocol for the Kedarcidin Sugar, L-Mycarose: AgPF6 as a Remarkable Activator of 2-Deoxythioglycosides
Citation Angew. Chem. Int. Ed. 2001. 40, 946
DOI 10.1002/1521-3773(20010302)40:5<946::AID-ANIE946>3.0.CO;2-G
PROM-767
Promoter p-NO2PhSCl-AgOTf
Leaving_Group STol
Title On the Reactivity and Selectivity of Galacturonic Acid Lactones
Citation Eur. J. Org. Chem. 2012, 2012, 5729
DOI 10.1002/ejoc.201200717
PROM-768
Promoter p-TolSCl, AgOTf
Leaving_Group STol
Title Superarming Common Glycosyl Donors, 2-O-Benzoyl-3,4,6-tri-O-benzyl Protection
Citation J. Org. Chem. 2010, 75, 1095
DOI 10.1021/jo9021474
PROM-769
Promoter FeCl3-I2
Leaving_Group I
Title daburi
Citation daburi
DOI 10.1021/ol035475k
PROM-77
Promoter TMSOTf
Leaving_Group ?
Title Synthesis of 2'-O-[(4"-O-stearoyl)-??-L-fucopyranosyl]thymidine: A shimofuridin analogue
Citation Bioorg. Med. Chem. Lett. 1997, 7, 2941
DOI 10.1016/S0960-894X(97)10116-0
PROM-770
Promoter CuCl-I2
Leaving_Group I
Title daburi
Citation daburi
DOI 10.1021/ol035475k
PROM-771
Promoter AgOTf-SnCl2
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97191-0
PROM-772
Promoter La(OTf)3-NIS
Leaving_Group SR (R = ?)
Title La(OTf)3: An Efficient Promoter for Thioglycoside Activation in Conjunction with N-Iodosuccinimide
Citation Synlett 2010, 2853
DOI 10.1055/s-0030-1259016
PROM-773
Promoter Cu(OTf)2-NIS
Leaving_Group SEt
Title A new synthesis of the oligosaccharide domain of acarbose
Citation Carbohydr. Res. 2003, 338, 2779
DOI 10.1016/j.carres.2003.09.004
PROM-774
Promoter Cu(OTf)2/cat-TfOH
Leaving_Group S-2-thiazolinyl
Title How the Arming Participating Moieties can Broaden the Scope of Chemoselective Oligosaccharide Synthesis by Allowing the Inverse Armed?|Disarmed Approach
Citation J. Org. Chem. 2008, 73, 8838
DOI 10.1021/jo801551r
PROM-775
Promoter Cu(OTf)2-DMTST
Leaving_Group -S-C(S)-OEt
Title Recent advances in glycosylation reactions
Citation Pure Apple. Chem. 1991, 63, 519
DOI 10.1351/pac199163040519
PROM-776
Promoter Bromodimethylsulfonium Bromide(BDSM)-AgOTf
Leaving_Group SR (R = ?)
Title Bromodimethylsulfonium Bromide-Silver Triflate: A New Powerful Promoter System for the Activation of Thioglycosides
Citation Adv. Synth. Catal. 2008, 350, 1696
DOI 10.1002/adsc.200800190
PROM-777
Promoter MeSiCl3-AgClO4 (cat)
Leaving_Group OAc
Title A Highly Stereoselective Synthesis of ??-Glucosides from Pentaacylglucopyranose and Alkyl Silyl Ether by the Use of a Catalytic Amount of Active Species Generated from Methyltrichlorosilane and Silver Perchlorate
Citation Chem. Lett. 1992, 2105
DOI 10.1246/cl.1992.2105
PROM-778
Promoter NBS, Bi(OTf)3
Leaving_Group SePh, alkyl thio-, phenyl thio-
Title Novel Approaches for the Synthesis and Activation of Thio- and Selenoglycoside Donors
Citation J. Org. Chem. 2007, 72, 6097
DOI 10.1021/jo070670o
PROM-779
Promoter TMSCl-Zn(OTf)2
Leaving_Group OH
Title Glycosidation with 1-Hydroxy Sugars as Glycosyl Donors Promoted by Trimethylsilyl Chloride and Zinc Triflate
Citation Chem. Pharm. Bull. 1994, 42, 1917
DOI 10.1248/cpb.42.1917
PROM-780
Promoter AgF-Ag2CO3
Leaving_Group -S-P(=S)-(O-CH2)2-C-Me2
Title 2-Deoxyglycosyl Phosphorodithioates. A Novel Type of Glycosyl Donor. Efficient Synthesis of 2'-Deoxydisaccharides
Citation J. Carbohydr. Chem. 1991, 10, 107
DOI 10.1080/07328309108543896
PROM-781
Promoter TBPA, (4-BrPh)3NH+SbCl6-
Leaving_Group SePh
Title Tris(4-bromophenyl)aminium hexachloroantimonate-mediated glycosylations of selenoglycosides and thioglycosides. Evidence for single electron transfer?
Citation Carbohydr. Res. 1998, 310, 43
DOI 10.1016/S0008-6215(98)00163-3
PROM-782
Promoter AgOTf-K2CO3
Leaving_Group SePh
Title Phenylselenoglycosides as novel, versatile glycosyl donors. Selective activation over thioglycosides
Citation Tetrahedron Lett. 1991, 32, 4435
DOI 10.1016/0040-4039(91)80005-Q
PROM-783
Promoter MeSO3H-CoBr2
Leaving_Group OH
Title A Stereoselective One-stage ??-Glucosylation with 2,3,4,6-Tetra-O-benzyl-??-D-glucopyranose and a Mixture of Methanesulfonic Acid, Cobalt(II) Bromide, and Tetraethylammonium Perchlorate
Citation Bull. Chem. Soc. Jpn,. 1982. 55, 1543
DOI 10.1246/bcsj.55.1543
PROM-784
Promoter TrB(C6F5)4-LiClO4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.79
PROM-785
Promoter TrB(C6F5)4-LiClO4
Leaving_Group OH
Title A Significant Effect of a Lithium Salt in the Stereocontrolled Synthesis of ??-D-Ribofuranosides
Citation Chem Lett. 1996, 271
DOI 10.1246/cl.1996.271
PROM-786
Promoter TrB(C6F5)4-LiOTf
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.271
PROM-787
Promoter TrB(C6F5)4-LiBF4
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.271
PROM-788
Promoter TrB(C6F5)4-LiNO3 (X: ClO4, I, NTf2)
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.271
PROM-789
Promoter TrB(C6F5)4-LiI
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.271
PROM-790
Promoter TrB(C6F5)4-LiNTf2
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1246/cl.1996.271
PROM-791
Promoter TrB(C6F5)4-NIS(or NBS)
Leaving_Group SEt
Title Stereoselective Glycosylation of Thioglycosides Promoted by Respective Combinations of N-Iodo- or N-Bromosuccinimide and Trityl Tetrakis(pentafluorophenyl)borate. Application to One-Pot Sequential Synthesis of Trisaccharide
Citation Chem Lett. 2000, 124
DOI 10.1246/cl.2000.124
PROM-792
Promoter TrB(C6F5)4-NaIO4
Leaving_Group SMe, SEt
Title An Efficient Method for Catalytic and Stereoselective Glycosylation with Thioglycosides Promoted by Trityl Tetrakis(pentafluorophenyl)borate and odium Periodate
Citation Chem Lett. 1997, 121
DOI 10.1246/cl.1997.121
PROM-793
Promoter MeOCH2CO2H-Yb(OTf)3
Leaving_Group OH
Title
Citation J. Chem. Soc., Chem. Commun. 1993, 1090
DOI 10.1039/C39930001090
PROM-794
Promoter TMSOTf(cat)-Ph2Sn=S
Leaving_Group OTMS
Title Stereoselective Glycosylation Reaction Starting from 1-O-Trimethylsilyl Sugars by Using Diphenyltin Sulfide and a Catalytic Amount of Active Acidic Species
Citation Chem. Lett. 1992, 1041
DOI 10.1246/cl.1992.1041
PROM-795
Promoter InCl3-TMSCl
Leaving_Group -O-C(=NPh)-CF3
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-796
Promoter Me2SiCl2-AgClO4
Leaving_Group -S-C(O)-OPh
Title Stereoselective Synthesis of N-Acetyl-??-neuraminosyl-galactose Disaccharide
Citation Chem. Lett. 1995. 455
DOI 10.1246/cl.1995.455
PROM-797
Promoter MeOSO2F-CaF
Leaving_Group 1,2-cyclic thiocarbonate
Title A NEW METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF ??-XYLOFURANOSIDE
Citation Chem. Lett. 1983, 1733
DOI 10.1246/cl.1983.1733
PROM-798
Promoter CuOAc-DBU
Leaving_Group OH
Title daburi
Citation daburi
DOI 10.1021/ja804589j
PROM-799
Promoter Et2O_ZnCl2
Leaving_Group trichloroacetimidate
Title daburi
Citation daburi
DOI 10.1016/S0008-6215(00)90879-6
PROM-8
Promoter TMSOTf
Leaving_Group trichloroimidate (or C(=NPh)-CF3)
Title Revisit of the phenol O-glycosylation with glycosyl imidates, BF3_OEt2 is a better catalyst than TMSOTf
Citation Carbohydr. Res. 2012, 363, 14
DOI 10.1016/j.carres.2012.09.025
PROM-800
Promoter Et2O_ZnCl2
Leaving_Group trichloroacetimidate
Title O-Glycosyl Imidates, 29. _ Reaction of O-(Glucopyranosyl) Imidates with Electron-Rich Heterocycles. _ Synthesis of C-Glucosides
Citation Liebigs Ann. Chem. 1987, 825
DOI 10.1002/jlac.198719870836
PROM-801
Promoter AgOTf, 2,4,6-trimethylPy
Leaving_Group Br
Title Use of 3-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-??-d-glucopyranosyl)-2,4,6-tri-O-acetyl-??-d-galactopyranosyl bromide as a glycosyl donor: Synthesis of p-nitrophenyl 3-O-(2-acetamido-2-deoxy-??-d-glucopyranosyl)-??-d-galactopyranoside
Citation Carbohydr. Res. 1983, 124, 115
DOI 10.1016/0008-6215(83)88359-1
PROM-802
Promoter Ag2O-Py
Leaving_Group Br
Title Synthesis of Glycosides of Lupane-Type Triterpene Acids
Citation Chem. Nat. Compd. 2003, 39, 575
DOI 10.1023/B:CONC.0000018113.79735.34
PROM-803
Promoter TMSOTf-CaCl2
Leaving_Group 1-thioimidoyl
Title First O-Glycosylation from Unprotected 1-Thioimidoyl Hexofuranosides Assisted by Divalent Cations
Citation J. Org. Chem. 2007, 72, 5743
DOI 10.1021/jo070741j
PROM-804
Promoter p-TolSl- AgOTf
Leaving_Group STol
Title Installation of Electron-Donating Protective Groups, a Strategy for Glycosylating Unreactive Thioglycosyl Acceptors using the Preactivation-Based Glycosylation Method
Citation J. Org. Chem. 2008, 73, 7952
DOI 10.1021/jo801462r
PROM-805
Promoter AgClO4-Lawesson's reagent
Leaving_Group OCOCH2I
Title Catalytic Synthesis of ??-D-Ribofuranosides from D-Ribofuranose and Alcohols
Citation Chem. Lett. 1993, 1941
DOI 10.1246/cl.1993.1941
PROM-806
Promoter [1,2-benzenediolato(2-)-O,O']oxotitanium-TMSOTf
Leaving_Group OTMS
Title Stereoselective Synthesis of 1,2-cis-Arabinofuranosides Using a New Titanium Catalyst
Citation Chem. Lett. 1992, 1401
DOI 10.1246/cl.1992.1401
PROM-807
Promoter [1,2-benzenediolato(2-)-O,O']oxotitanium-TMSOTf
Leaving_Group OTMS
Title daburi
Citation daburi
DOI 10.1246/cl.1992.1041
PROM-809
Promoter Pd2(dba)3-PPh3
Leaving_Group OC(O)Ph
Title De Novo Asymmetric Bio- and Chemocatalytic Synthesis of Saccharides Stereoselective Formal O-Glycoside Bond Formation Using Palladium Catalysis
Citation J. Am. Chem. Soc. 2003, 125, 8714
DOI 10.1021/ja0347538
PROM-81
Promoter TMSOTf
Leaving_Group OC(=NH)CCl3, PTFAI(N-Phenyl trifluoroacetimidates), OFox(3,3-difluoro-3H-indol-2-yl)
Title Regenerative Glycosylation under Nucleophilic Catalysis
Citation J. Am. Chem. Soc. 2014, 136, 921
DOI 10.1021/ja411746a
PROM-810
Promoter Pd2(dba)3-PPh3
Leaving_Group ?
Title De Novo Approach to 2-Deoxy-??-glycosides:_ Asymmetric Syntheses of Digoxose and Digitoxin
Citation J. Org. Chem. 2007, 72, 2485
DOI 10.1021/jo062534+
PROM-811
Promoter Pd(OAc)2-P(OPh)3
Leaving_Group OC(O)Me
Title daburi
Citation daburi
DOI 10.1021/ja0347538
PROM-813
Promoter [Co(dmgH)2py]2-NaBH4
Leaving_Group Br
Title daburi
Citation daburi
DOI 10.1351/pac198860111655
PROM-814
Promoter NiCl2-ligand, NiCl2-Ligand(PyBox)
Leaving_Group Br, Cl
Title A Room Temperature Negishi Cross-Coupling Approach to C-Alkyl Glycosides
Citation J. Am. Chem. Soc. 2007, 129, 1908
DOI 10.1021/ja068950t
PROM-815
Promoter ?⑫?A?R?????g?Q??
Leaving_Group Br, Cl
Title Diastereoselective Ni-Catalyzed Negishi Cross-Coupling Approach to Saturated, Fully Oxygenated C-Alkyl and C-Aryl Glycosides
Citation J. Am. Chem. Soc. 2008, 130, 12177
DOI 10.1021/ja8041564
PROM-82
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Stereoselective synthesis of 2-deoxy-??-glycosides from glycal precursors. 2. Stereochemistry of glycosidation reactions of 2-thiophenyl- and 2-selenophenyl-??-d-gluco-pyranosyl donors
Citation Tetrahedron 1997, 53, 8837
DOI 10.1016/S0040-4020(97)90395-1
PROM-822
Promoter Bu3SnH, AIBN
Leaving_Group Br
Title Stereoselective syntheses with carbohydrate radicals
Citation Pure Appl. Chem. 1988, 60, 1655
DOI 10.1351/pac198860111655
PROM-825
Promoter Cp2HfCl2/AgX (X=OTf, ClO4)
Leaving_Group F
Title Synthesis of Disaccharides by Selective Metallocene Promoted Activation of Glycosyl Fluorides
Citation Synlett 1996, 675
DOI 10.1055/s-1996-5554
PROM-826
Promoter SnCl4, PhOSnBu3
Leaving_Group Br
Title An approach to synthesis of glycosides: enhancement of nucleophilicity of hydroxyl groups by trialkylstannylation
Citation Carbohydr. Res. 1976,?C13
DOI 10.1016/S0008-6215(00)83340-6
PROM-827
Promoter AuBr3, AgOTf
Leaving_Group propargyl glycosides
Title Propargyl/methyl furanosides as potential glycosyl donors
Citation Chem. Commun. 2011, 9906
DOI 10.1039/C1CC13134F
PROM-828
Promoter (4-CF3Ph)3PAuCl, AgOTf
Leaving_Group S(CH2)2CCH
Title Gold-Catalyzed Synthesis of 2-Deoxy Glycosides Using S-But-3-ynyl Thioglycoside Donors
Citation ACS Catal. 2013, 3, 57
DOI 10.1021/cs300670k
PROM-829
Promoter PhSeNPhth-Mg(ClO4)2
Leaving_Group SMe, SPh
Title Mild but Efficient Methods for Stereoselective Glycosylation with Thioglycosides: Activation by[N-Phenylselenophthalimide-Mg(ClO4)2] and [PhIO-Mg(ClO4)2]
Citation Synlett. 1998, 84
DOI 10.1055/s-1998-1575
PROM-83
Promoter TMSOTf
Leaving_Group ?
Title An efficient synthesis of mixed ??-carbonates of acyl-protected sugar and their decarboxylative glycosidation promoted by trimethylsilyl trifluoromethanesulfonate
Citation Tetrahedron Lett. 1999, 40, 4683
DOI 10.1016/S0040-4039(99)00843-6
PROM-830
Promoter SnCl2-AgOTf
Leaving_Group F
Title Total synthesis of ??-cyclodextrin
Citation Carbohydr. Res. 1985, 138, C5
DOI 10.1016/0008-6215(85)85239-3
PROM-831
Promoter SnCl2-AgOTf
Leaving_Group Cl, F
Title daburi
Citation daburi
DOI 10.1246/cl.1996.337
PROM-832
Promoter SnCl2-AgClO4
Leaving_Group F
Title Studies directed toward the total synthesis of polycavernoside A. Enantioselective synthesis of the disaccharide component
Citation Tetrahedron Lett. 1995, 36, 4341
DOI 10.1016/0040-4039(95)00789-F
PROM-833
Promoter SnCl2-AgClO4
Leaving_Group F
Title Enantioselective Total Synthesis of Antifungal Agent Sch 38516
Citation J. Am. Chem. Soc. 1996, 118, 10926
DOI 10.1021/ja9626603
PROM-834
Promoter SnCl2-AgClO4
Leaving_Group F
Title Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1)
Citation J. Am. Chem. Soc. 1997, 119, 10302
DOI 10.1021/ja972191k
PROM-835
Promoter SnCl2-AgClO4
Leaving_Group F
Title Total Synthesis of Formamicin
Citation J. Am. Chem. Soc. 2004, 126, 9307
DOI 10.1021/ja048493l
PROM-836
Promoter SnCl2-AgClO4
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1351/pac199163040555
PROM-837
Promoter SnCl2-AgClO4
Leaving_Group ?
Title Stereocontrolled Total Synthesis of (?|)-Aurisides A and B
Citation Angew. Chem., Int. Ed. 2005, 44, 1130
DOI 10.1002/anie.200462267
PROM-838
Promoter SnCl4-AgClO4 (cat)
Leaving_Group OAc
Title A Highly Stereoselective Synthesis of ??-Glucosides from 1-O-Acetyl Glucose by Use of Tin(IV) Chloride_Silver Perchlorate Catalyst System
Citation Chem. Lett. 1991, 533
DOI 10.1246/cl.1991.533
PROM-839
Promoter SnCl4-AgClO4
Leaving_Group OAc
Title Catalytic Stereoselective Synthesis of 2-Amino-2-Deoxy-??-D-Glucopyranosides and Galactopyranosides
Citation Chem. Lett. 1993. 2145
DOI 10.1246/cl.1993.2145
PROM-84
Promoter TMSOTf
Leaving_Group trichlorocarbamate, trichloroacetate
Title Sequential one-pot glycosylation with glycosyl N-trichloroacetylcarbamate and trichloroacetate including dehydrative approach using 1-hydroxy sugars
Citation Tetrahedron. 2011, 67, 6482
DOI 10.1016/j.tet.2011.06.006
PROM-840
Promoter SnCl4-AgClO4
Leaving_Group -CO2R
Title An ??-Selective Glycosylation via Decarboxylation of Mixed Carbonate Catalyzed by the Combination of Lewis Acid and Silver Perchlorate
Citation Heterocycles 1997, 46, 221
DOI 10.3987/COM-97-S84
PROM-841
Promoter SnCl4-AgClO4
Leaving_Group OAc
Title The trityl group as an alternative in Mukaiyama's glycosylation reaction
Citation Tetrahedron Lett. 1993, 34, 3283
DOI 10.1016/S0040-4039(00)73682-3
PROM-842
Promoter SnCl4-AgClO4
Leaving_Group OCOCH2OC2H4OMe
Title Catalytic Stereoselective Synthesis of ??- or ??-Glucosides Using a Single Glycosyl Donor, 1-O-2??-(2??-Methoxyethoxy)acetyl-Glucopyranose Derivative
Citation Chem. Lett. 1993, 1373
DOI 10.1246/cl.1993.1373
PROM-843
Promoter SnCl4-AgClO4
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.5059/yukigoseikyokaishi.53.1045
PROM-844
Promoter SnCl2-SnCl4 (cat)
Leaving_Group OCOCH2I
Title daburi
Citation daburi
DOI 10.1246/cl.1994.433
PROM-845
Promoter SnCl4-Sn(OTf)2 (cat)
Leaving_Group OAc
Title Stereoselective 1,2-cis Glycosylation Reaction of 1-O-Acetylribose with Silylated Nucleophiles by the Promotion of a New Catalyst System
Citation Chem. Lett. 1989, 145
DOI 10.1246/cl.1989.145
PROM-846
Promoter Sn(OTf)2-LiClO4
Leaving_Group OCOCH2OC2H4OMe
Title An Efficient Method for Catalytic Stereoselective Synthesis of ??-L-Fucopyranosides
Citation Chem. Lett. 1996, 1123
DOI 10.1246/cl.1996.1123
PROM-847
Promoter AgClO4-LiClO4
Leaving_Group OCOCH2I
Title Catalytic Stereoselective Synthesis of ??- or ??-Ribofuranosides by Combined Use of Silver Salts and Lithium Perchlorate or Diphenyltin Sulfide
Citation Chem. Lett. 1993, 781
DOI 10.1246/cl.1993.781
PROM-848
Promoter Ag2CO3-AgClO4
Leaving_Group Br, p-NO2PhCOO-
Title daburi
Citation daburi
DOI 10.1246/bcsj.50.2369
PROM-849
Promoter Ag2CO3-AgClO4
Leaving_Group Br, Cl, SPh
Title Glycopeptides as versatile tools for glycobiology
Citation Glycobiology 2006, 16, 113R
DOI 10.1093/glycob/cwj125
PROM-85
Promoter TMSOTf
Leaving_Group trichloroimidate
Title Synthesis of Biologically Potent ??1??2-Linked Disaccharide Derivatives via Regioselective One-Pot Protection_Glycosylation
Citation Angew. Chem. Int. Ed. 2002, 41, 2360
DOI 10.1002/1521-3773(20020703)41:13<2360::AID-ANIE2360>3.0.CO;2-R
PROM-850
Promoter Ag2CO3-AgClO4
Leaving_Group Cl
Title daburi
Citation daburi
DOI 10.1135/cccc19930159
PROM-851
Promoter GaCl3-AgClO4 (cat)
Leaving_Group OAc
Title The Evaluation of Catalysts Generated from Lewis Acids and Silver Perchlorate in a Highly Stereoselective Glycosylation of 1-O-Acetyl-D-glucose
Citation Chem. Lett. 1991, 985
DOI 10.1246/cl.1991.985
PROM-852
Promoter ZnCl2-AgClO4
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1055/s-1993-22367
PROM-853
Promoter ZnCl2-AgClO4
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1016/S0040-4020(01)89683-6
PROM-854
Promoter Bu2SnCl2, Me2SnCl2, Bu3SnCl, Me3SnCl, and Ph3SnCl with AgClO4
Leaving_Group F
Title ?gDibutyltin diperchlorate?h for activation of glycosyl fluoride
Citation Carbohydr. Res. 1993, 249, 49
DOI 10.1016/0008-6215(93)84059-F
PROM-855
Promoter Cp2MCl2-AgClO4 (M=Zr or Hf)
Leaving_Group F
Title New glycosidation reaction 1: Combinational use of Cp2ZrCl2-AgClO4 for activation of glycosyl fluorides and application to highly ??-selective gylcosidation of D-mycinose
Citation Tetrahedron Lett. 1988. 29, 3567
DOI 10.1016/0040-4039(88)85294-8
PROM-856
Promoter Cp2MCl2-AgClO4 (M=Zr or Hf)
Leaving_Group F
Title Rapid O-Glycosidation of Phenols with Glycosyl Fluoride by Using the Combinational Activator, Cp2HfCl2_AgClO4
Citation Chem. Lett. 1989, 437?@
DOI 10.1246/cl.1989.437
PROM-857
Promoter Cp2MCl2-AgClO4 (M=Zr or Hf)
Leaving_Group OAc
Title Cationic zirconocene- or hafnocene-based Lewis acids in organic synthesis: glycoside_flavonoid analogy
Citation Tetrahedron. 2004, 60, 1365
DOI 10.1016/j.tet.2003.08.076
PROM-858
Promoter Cp2MCl2-AgClO4 (M=Zr or Hf)
Leaving_Group F
Title First total synthesis of mycinamicin IV and VII.: Successful application of new glycosidation reaction
Citation Tetrahedron Lett. 1988. 29, 3575
DOI 10.1016/0040-4039(88)85296-1
PROM-859
Promoter Cp2MCl2-AgX (M=Hf, Zr; X=ClO4, OTf)
Leaving_Group F
Title Stereoselective synthesis of nucleosides by metallocene-promoted activation of glycosyl fluorides
Citation Tetrahedron Lett. 1992, 33, 1093
DOI 10.1016/S0040-4039(00)91869-0
PROM-86
Promoter TMSOTf
Leaving_Group -OC(NH)CCl3
Title A General Strategy for Stereoselective Glycosylations
Citation J. Am. Chem. Soc. 2005, 127, 12090
DOI 10.1021/ja052548h
PROM-860
Promoter Cp2HfCl2-AgClO4
Leaving_Group F
Title New glycosidation reaction 2. preparation of 1-fluoro-d-desosamine derivative and its efficient glycosidation by the use of Cp2HfCl2-AgClO4 as the activator
Citation Tetrahedron Lett. 1988. 29, 3571
DOI 10.1016/0040-4039(88)85295-X
PROM-861
Promoter Cp2HfCl2-AgClO4
Leaving_Group F
Title Isochromane ?gversus?h O-glycoside synthesis. A study of the reaction of 2-alkoxy-2-fluoro-glycosyl fluorides with alcohols
Citation Tetrahedron 1994, 50, 9125
DOI 10.1016/S0040-4020(01)85378-3
PROM-862
Promoter Cp2HfCl2-AgClO4
Leaving_Group F
Title New approach to C-aryl glycosides starting from phenol and glycosyl fluoride. Lewis acid-catalyzed rearrangement of O-glycoside to C-glycoside
Citation Tetrahedron Lett. 1988, 29, 6935
DOI 10.1016/S0040-4039(00)88479-8
PROM-863
Promoter Cp2HfCl2-2AgClO4
Leaving_Group -CO2R
Title daburi
Citation daburi
DOI 10.3987/COM-97-S84
PROM-864
Promoter Cp2HfCl2-AgClO4
Leaving_Group OAc
Title Total Synthesis of the Gilvocarcins
Citation J. Synth. Org. Chem., Jpn. 1995, 53, 1045
DOI 10.5059/yukigoseikyokaishi.53.1045
PROM-865
Promoter Cp2HfCl2-AgClO4
Leaving_Group F
Title daburi
Citation daburi
DOI 10.1055/s-1991-34769
PROM-866
Promoter Cp2HfCl2-AgClO4
Leaving_Group ?
Title First total synthesis of BE-12406 A
Citation Tetrahedron Lett. 1994, 35, 4591
DOI 10.1016/S0040-4039(00)60738-4
PROM-867
Promoter Cp2HfCl2-AgClO4
Leaving_Group ?
Title Improvement in O??C-glycoside rearrangement approach to C-aryl glycosides: Use of 1-O-acetyl sugar as stable but efficient glycosyl donor
Citation Tetrahedron Lett. 1990, 31, 4629
DOI 10.1016/S0040-4039(00)97693-7
PROM-868
Promoter Cp2HfCl2-AgClO4
Leaving_Group ?
Title C-Glycosylation-Cycloaddition Approach to C-Glycosyl Juglones. Versatile Intermediates toward Aryl C-Glycoside Antibiotics?
Citation Chem. Lett. 1995, 677
DOI 10.1246/cl.1995.677
PROM-869
Promoter Cp2HfCl2-AgClO4
Leaving_Group F
Title Synthesis of isochromane derivatives by metallocene-promoted reaction of 2-alkoxy-2-fluoro-glycosyl fluorides with benzyl alcohol
Citation Tetrahedron Lett. 1993, 34, 2361
DOI 10.1016/S0040-4039(00)77614-3
PROM-87
Promoter TMSOTf
Leaving_Group ?
Title Chiral-auxiliary-mediated 1,2-cis-glycosylations for the solid-supported synthesis of a biologically important branched ??-glucan
Citation Nat. Chem. 2010, 2, 552
DOI 10.1038/nchem.663
PROM-870
Promoter Cp2HfCl2-AgOTf
Leaving_Group SMe, F
Title daburi
Citation daburi
DOI 10.1248/cpb.49.1234
PROM-871
Promoter Cp2HfCl2-AgOTf
Leaving_Group F
Title Synthetic study toward vineomycins. Synthesis of c-aryl glycoside sector via Cp2HfCl2?XAgClO4-promoted tactics
Citation Tetrahedron Lett. 1989, 30, 6185
DOI 10.1016/S0040-4039(01)93337-4
PROM-872
Promoter Cp2HfCl2-AgOTf
Leaving_Group F
Title Synthesis of novel oligosaccharides
Citation Pure Apple. Chem. 1991, 63, 555
DOI 10.1351/pac199163040555
PROM-873
Promoter Cp2ZrCl2-AgBF4, Cp2HfCl2-AgOTf
Leaving_Group F
Title Cp2ZrCl2?EAgBF4 in Benzene: A new reagent system for rapid and highly selective ??-mannoside synthesis from tetra-O-benzyl-d-mannosyl fluoride
Citation Tetrahedron Lett. 1989. 30, 6879
DOI 10.1016/S0040-4039(01)93378-7
PROM-874
Promoter Cp2ZrCl2-AgBF4
Leaving_Group F
Title Glycosylating Properties of Ketopyranosyl Donors: Stereospecific Synthesis of Ketodisaccharides
Citation Synlett 1992, 713
DOI 10.1055/s-1992-21464
PROM-875
Promoter Cp2ZrCl2-AgClO4
Leaving_Group PhS(O)-
Title Glycosylation via Cp2ZrCl2/AgClO4-Mediated Activation of Anomeric Sulfoxides
Citation J. Org. Chem. 2001, 66, 7910
DOI 10.1021/jo015952h
PROM-876
Promoter Cp2ZrCl2-AgClO4
Leaving_Group F
Title Cp2ZrCl2-AgClO4: Efficient promoter for the Friedel-Crafts approach to C-aryl glycosides
Citation Tetrahedron Lett. 1989, 30, 833
DOI 10.1016/S0040-4039(01)80628-6
PROM-877
Promoter La(ClO4)3?EnH2O-Sn(OTf)2
Leaving_Group F
Title ??-Selective glycosylation with ??-mannosyl fluorides using tin(II) triflate and lanthanum perchlorate
Citation Tetrahedron Lett. 1996. 37, 7797
DOI 10.1016/0040-4039(96)01781-9
PROM-878
Promoter Bu2SnCl2?%5C2AgClO4
Leaving_Group F
Title ?gDibutyltin diperchlorate?h for activation of glycosyl fluoride
Citation Carbohydr. Res. 1993, 249, 49
DOI 10.1016/0008-6215(93)84059-F
PROM-879
Promoter AgClO4-Ph3Sn=S
Leaving_Group OAc
Title daburi
Citation daburi
DOI 10.1246/cl.1993.781
PROM-88
Promoter TMSOTf
Leaving_Group ?
Title A novel and efficient ionic liquid supported synthesis of oligosaccharides
Citation Tetrahedron Lett. 2006, 47, 3047
DOI 10.1016/j.tetlet.2006.03.002
PROM-880
Promoter AgClO4-Ph3Sn=S
Leaving_Group OCOCH2I
Title daburi
Citation daburi
DOI 10.1246/cl.1993.1941
PROM-881
Promoter LnPtMe3BF4, Cu(OTf)2
Leaving_Group S-2-thiazolinyl
Title Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation
Citation Chem. Commun. 2009, 6379
DOI 10.1039/B903942B
PROM-882
Promoter Pd(MeCN)2Cl2-AgOTf
Leaving_Group SPh, SPy
Title Palladium(II) Promoted O-Glycosylation Involving 1-Thio-2-enosides and 3-Thio-1-enoses
Citation Tetrahedron Lett. 1994, 35, 125
DOI 10.1016/0040-4039(94)88180-4
PROM-883
Promoter PdCl2(dppf)-CuCN
Leaving_Group SnBu3
Title C-Glycosides: Pd/Cu co-catalyzed thiocarboxylation of stannyl glucopyranosides
Citation Tetrahedron Lett. 1995, 36, 5881
DOI 10.1016/0040-4039(95)01183-I
PROM-884
Promoter Zn/ZnCl2
Leaving_Group Br
Title Synthesis of thio- and selenoglycosides by cleavage of dichalconides in the presence of zinc/zinc chloride and reaction with glycosyl bromides
Citation Tetrahedron Lett. 2006, 47, 441
DOI 10.1016/j.tetlet.2005.11.074
PROM-885
Promoter SnCl2-AgB(C6F5)4
Leaving_Group SPh, F
Title daburi
Citation daburi
DOI 10.1021/jo4012464
PROM-886
Promoter SnCl2-AgB(C6H5)4
Leaving_Group F
Title Catalytic and Stereoselective Glycosylation with Disarmed Glycosyl Fluoride by Using a Combination of Stannous(II) Chloride (SnCl2) and Silver Tetrakis(pentafluorophenyl)borate [AgB(C6F5)4] as a Catalyst
Citation Chem. Lett. 2001, 388
DOI 10.1246/cl.2001.388
PROM-887
Promoter SnCl2-AgB(C6H5)4
Leaving_Group F
Title Completely ??-Selective Glycosylation Using 3,6-O-(o-Xylylene)-Bridged Axial-Rich Glucosyl Fluoride
Citation J. Am. Chem. Soc. 2012, 134, 6940
DOI 10.1021/ja301480g
PROM-888
Promoter Hg(CN)2-HgBr2(1:1 mixture)
Leaving_Group ?
Title Synthese eines trisaccharides aus N-acetylneuramins_ure und N-acetyllactosamin
Citation Carbohydr Res 1984, 125, 47
DOI 10.1016/0008-6215(84)85141-1
PROM-889
Promoter Hg(CN)2-HgBr2(1.6:0.5 mixture)
Leaving_Group Cl, OP(OEt2), Br, SEt
Title daburi
Citation daburi
DOI 10.1021/ja9740327
PROM-89
Promoter TMSOTf
Leaving_Group -OP(O)OBu2, -C(NH)CCl3
Title Automated Synthesis of the Tumor-Associated Carbohydrate Antigens Gb-3 and Globo-H:_ Incorporation of ??-Galactosidic Linkages
Citation J. Am. Chem. Soc. 2007, 129, 2770
DOI 10.1021/ja069218x
PROM-890
Promoter Zn_Cu
Leaving_Group ?
Title Reductive cleavage as a route to carbohydrate enolates. Applications to the synthesis of C-linked disaccharides
Citation J. Chem. Soc. Chem. Commun. 1995, 967
DOI 10.1039/C39950000967
PROM-891
Promoter CeCl3_Nal
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1039/C39950000967
PROM-892
Promoter Cu(OTf)2-CuO
Leaving_Group 2-PyS, 2-Pym-S
Title daburi
Citation daburi
DOI 10.1021/ja963575y
PROM-893
Promoter NIS-TMSOTf
Leaving_Group STol
Title Efficient Convergent Synthesis of Bi-, Tri-, and Tetra-antennary Complex Type N-Glycans and Their HIV-1 Antigenicity
Citation J. Am. Chem. Soc. 2013, 135, 15382
DOI 10.1021/ja409097c
PROM-894
Promoter NIS-TMSOTf
Leaving_Group SEt
Title The design and synthesis of a conformationally constrained trisaccharide for probing carbohydrate-protein interactions
Citation Tetrahedron Lett. 1997, 38, 2023
DOI 10.1016/S0040-4039(97)00223-2
PROM-895
Promoter NIS-TMSOTf
Leaving_Group STol
Title Study of the stereoselectivity of 2-azido-2-deoxyglucosyl donors: protecting group effects
Citation Org. Biomol. Chem. 2013, 11, 1879
DOI 10.1039/C3OB26994A
PROM-896
Promoter NIS-TMSOTf
Leaving_Group SEt
Title Thioglycosides Protected as Trans-2,3-Cyclic Carbonates in Chemoselective Glycosylations
Citation Org. Lett. 2001, 3, 4201
DOI 10.1021/ol016869j
PROM-897
Promoter NIS-TMSOTf
Leaving_Group SPh
Title 1,2-cis Alkyl glycosides: straightforward glycosylation from unprotected 1-thioglycosyl donors
Citation Org. Biomol. Chem. 2014, 12, 5182
DOI 10.1039/C4OB00626G
PROM-898
Promoter NIS-TMSOTf
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/ja071955l
PROM-899
Promoter NIS-TMSOTf, DMF
Leaving_Group STol
Title Iterative ??-Glycosylation Strategy for 2-Deoxy- and 2,6-Dideoxysugars
Citation Eur. J. Org. Chem. 2014, 2014, 1827
DOI 10.1002/ejoc.201400006
PROM-9
Promoter TMSOTf
Leaving_Group trichloroimidate
Title C2-Symmetric Lewis Antigen Mimetics Exhibiting the Common Structural Motif
Citation J. Am. Chem. Soc. 1997, 119, 11707
DOI 10.1021/ja972764t
PROM-90
Promoter TMSOTf
Leaving_Group ?
Title Synthesis of 6-Branched Cyclo-(1??3)-glucohexaose and Glucooctaose
Citation Synlett 2004, 2594
DOI 10.1055/s-2004-834811
PROM-900
Promoter NIS-TMSOTf
Leaving_Group azid
Title daburi
Citation daburi
DOI 10.1002/ejoc.200600759
PROM-901
Promoter NIS-TMSOTf
Leaving_Group allyl glycoside
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)73249-7
PROM-902
Promoter NIS-TMSOTf
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-904
Promoter NIS-TMSOTf
Leaving_Group SEt
Title Novel Regioselective Glycosylations for the Convergent and Chemoselective Assembly of Oligosaccharides
Citation Synlett. 1997, 809
DOI 10.1055/s-1997-5767
PROM-905
Promoter NIS-TMSOTf
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(97)00106-8
PROM-906
Promoter NIS-TMSOTf
Leaving_Group Telluruoglycoside
Title Glycosylation with telluroglycosides. Stereoselective construction of ??- and ??-anomers
Citation Tetrahedron Lett. 1998, 39, 7905
DOI 10.1016/S0040-4039(98)01753-5
PROM-907
Promoter NIS-TMSOTf
Leaving_Group SEt
Title Modular Synthesis of Heparan Sulfate Oligosaccharides for Structure?|Activity Relationship Studies
Citation J. Am. Chem. Soc. 2009, 131, 17394
DOI 10.1021/ja907358k
PROM-908
Promoter NIS-TMSOTf
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/ja801669r
PROM-909
Promoter NIS-TMSOTf
Leaving_Group SEt
Title Intramolecular glycoside bond formation ?%5C A rigid spacer concept for the diastereoselective linkage between glycosyl donor and acceptor
Citation Tetrahedron Lett. 1998, 39, 7693
DOI 10.1016/S0040-4039(98)01664-5
PROM-91
Promoter TMSOTf
Leaving_Group ?
Title Synthesis of ??-Arabinose Nucleosides from 6-Substituted Uracils
Citation Liebigs Ann. Chem. 1993, 1
DOI 10.1002/jlac.199319930102
PROM-910
Promoter NIS-TMSOTf
Leaving_Group SEt
Title Intramolecular glycosylation of prearranged glycosides. A novel tool for controlling the reactivity and anomeric selectivity of glycosylations
Citation Tetrahedron Lett. 1995, 36, 1417
DOI 10.1016/0040-4039(95)00010-A
PROM-911
Promoter NIS-TfOH
Leaving_Group SMe, SEt, SPh
Title Iodonium promoted reactions of disarmed thioglycosides
Citation Tetrahedron Lett. 1990. 31, 4313
DOI 10.1016/S0040-4039(00)97609-3
PROM-912
Promoter NIS-TfOH
Leaving_Group SMe
Title Iodonium ion generated in situ from N-iodosuccinimide and trifluoromethanesulphonic acid promotes direct linkage of ?edisarmed?f pent-4-enyl glycosides
Citation J. Chem. Soc. Chem. Commun. 1990, 270
DOI 10.1039/C39900000270
PROM-913
Promoter NIS-TfOH (cat)
Leaving_Group SMe
Title Iodonium ion promoted reactions at the anomeric centre. II An efficient thioglycoside mediated approach toward the formation of 1,2-trans linked glycosides and glycosidic esters
Citation Tetrahedron Lett. 1990, 31, 1331
DOI 10.1016/S0040-4039(00)88799-7
PROM-914
Promoter NIS-TfOH (cat)
Leaving_Group S-Box? (S-benzoxazolyl)
Title Versatile Synthesis and Mechanism of Activation of S-Benzoxazolyl Glycosides
Citation J. Org. Chem. 2007, 72, 6938
DOI 10.1021/jo0711844
PROM-915
Promoter NIS-TfOH
Leaving_Group SEt
Title ??-Arabinofuranosylation Using 5-O-(2-Quinolinecarbonyl) Substituted Ethyl Thioglycoside Donors
Citation Org. Lett. 2013, 15, 3974
DOI 10.1021/ol401755e
PROM-916
Promoter NIS-TfOH
Leaving_Group SEt
Title Trityl ethers in oligosaccharide synthesis: A novel strategy for the convergent assembly of oligosaccharides
Citation Tetrahedron Lett. 1997, 38, 3773
DOI 10.1016/S0040-4039(97)00732-6
PROM-917
Promoter NIS-TfOH
Leaving_Group STol
Title Anomeric Reactivity-Based One-Pot Synthesis of Heparin-Like Oligosaccharides
Citation J. Am. Chem. Soc. 2007, 129, 12795
DOI 10.1021/ja073098r
PROM-918
Promoter NIS-TfOH
Leaving_Group STol
Title C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-??-glycoside formation
Citation Chem. Commun. 2015, 51, 5394
DOI 10.1039/C4CC08465A
PROM-919
Promoter NIS-TfOH
Leaving_Group S-Ph-pX (X=EDG; H, Me, OMe, NHAc)
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)60004-7
PROM-92
Promoter TMSOTf
Leaving_Group ?
Title Synthesis Of Isomaltose Analogues
Citation J. Carbohydr. Chem. 1991, 10, 969
DOI 10.1080/07328309108543966
PROM-920
Promoter NIS-TfOH
Leaving_Group SPh
Title Super Armed?h Glycosyl Donors: Conformational Arming of Thioglycosides by Silylation
Citation J. Am. Chem. Soc. 2007, 129, 9222
DOI 10.1021/ja071955l
PROM-921
Promoter NIS-TfOH
Leaving_Group SEt
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)61375-8
PROM-922
Promoter NIS-TfOH
Leaving_Group SPh
Title Di-tert-butylsilylene (DTBS) group-directed ??-selective galactosylation unaffected by C-2 participating functionalities
Citation Tetrahedron Lett. 2003, 44, 6725
DOI 10.1016/S0040-4039(03)01647-2
PROM-923
Promoter NIS-TfOH
Leaving_Group SPh
Title O-Sialylation with N-Acetyl-5-N,4-O-Carbonyl-Protected Thiosialoside Donors in Dichloromethane:_ Facile and Selective Cleavage of the Oxazolidinone Ring
Citation J. Org. Chem. 2007, 72, 2387
DOI 10.1021/jo062431r
PROM-924
Promoter NIS-TfOH
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1055/s-1993-22367
PROM-925
Promoter NIS-TfOH
Leaving_Group -O-P-(OMe)2
Title daburi
Citation daburi
DOI 10.1016/S0040-4020(01)89683-6
PROM-926
Promoter NIS-TfOH
Leaving_Group 4-pentenyl Glycoside
Title n-Pentenyl glycosides facilitate a stereoselective synthesis of the pentasaccharide core of the protein membrane anchor found in Trypanosoma brucei
Citation J. Am. Chem. Soc. 1989, 111, 8540
DOI 10.1021/ja00204a049
PROM-927
Promoter NIS-TfOH
Leaving_Group STol
Title 2,6-Disubstituted 2-O-Benzoyl groups: A Mechanistic Investigation
Citation J. Carbohydr. Chem. 2010, 29, 236
DOI 10.1080/07328303.2010.508141
PROM-928
Promoter NIS-TfOH
Leaving_Group SePh
Title daburi
Citation daburi
DOI 10.1002/recl.19921110706
PROM-929
Promoter NIS-TfOH
Leaving_Group SePh
Title daburi
Citation daburi
DOI 10.1080/07328309308020119
PROM-93
Promoter TMSOTf
Leaving_Group phosphite and phosphate
Title Synthesis of phosphites and phosphates of neuraminic acid and their glycosyl donor properties ?%5C convenient synthesis of GM3
Citation Glycoconjugate J. 1993, 10, 16
DOI 10.1007/BF00731182
PROM-930
Promoter NIS-TfOH
Leaving_Group isopropenyl, n-pentenyl ?glycoside
Title Glycosyl transfer by isopropenyl glycosides: Trisaccharide synthesis in one pot by selective coupling of isopropenyl and n-pentenyl glycopyranosides
Citation Tetrahedron Lett. 1994, 35, 9145
DOI 10.1016/0040-4039(94)88449-8
PROM-931
Promoter NIS-TfOH
Leaving_Group isopropenyl?glycoside
Title The Chemistry of Isopropenyl Glycopyranosides. Transglycosylations and Other Reactions
Citation J. Org. Chem. 1996, 61, 5024
DOI 10.1021/jo960190p
PROM-932
Promoter NIS-TfOH
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-933
Promoter NIS-TfOH
Leaving_Group SPh
Title Stereoselective Synthesis of Oligo-??-(2,8)-Sialic Acids
Citation J. Am. Chem. Soc. 2006, 128, 7124
DOI 10.1021/ja0613613
PROM-934
Promoter NIS-TfOH
Leaving_Group 2-Allyloxyphenyl glycoside
Title 2-Allyloxyphenyl glycoside as a new and stable type of glycosyl donors
Citation Tetrahedron Lett. 2006, 47, 1621
DOI 10.1016/j.tetlet.2005.12.127
PROM-935
Promoter NIS-TfOH
Leaving_Group SePh
Title Application of Phenyl 1-Selenoglycosides in the Synthesis of a Cell-Wall Tetrameric Fragment of Proteus Vulgaris Strain 5/43
Citation J. Carbohydr. Chem. 1994, 13, 323
DOI 10.1080/07328309408009196
PROM-936
Promoter NIS-TfOH
Leaving_Group SEt
Title Direct Syntheses of ??- Nannopyranosyl Disaccharides from 4,6-O-Benzylidene Derivatives of Ethylthio ??-D-Mannopyranosides Donors
Citation Bull. Korean Chem. Soc. 2000, 21, 562
DOI Nothing
PROM-937
Promoter NIS-TfOH
Leaving_Group SPh, F
Title Conformationally Armed 3,6-Tethered Glycosyl Donors: Synthesis, Conformation, Reactivity, and selectivity
Citation J. Org. Chem. 2013, 78, 7234
DOI 10.1021/jo4012464
PROM-938
Promoter NIS-TfOH
Leaving_Group -S-S-Et
Title Glycosyl Disulfides:_ Novel Glycosylating Reagents with Flexible Aglycon Alteration
Citation J. Org. Chem. 2005, 70, 9740
DOI 10.1021/jo051374j
PROM-939
Promoter NIS-TfOH
Leaving_Group -SC(S)NEt2
Title Block synthesis of oligosaccharides. Part 1: Preparation of furanosyl-1-thiopyranosides
Citation Tetrahedron Lett. 2001, 42, 2221
DOI 10.1016/S0040-4039(01)00116-2
PROM-94
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Solid phase glycosidation of oligonucleotides
Citation Tetrahedron Lett. 1999, 40, 2607
DOI 10.1016/S0040-4039(99)00228-2
PROM-941
Promoter NIS-TfOH
Leaving_Group SPh
Title Solid-Phase Synthesis of Oligosaccharides and On-Resin Quantitative Monitoring Using Gated Decoupling 13C NMR
Citation J. Am. Chem. Soc. 2002, 124, 3591
DOI 10.1021/ja0167396
PROM-942
Promoter NIS-TfOH
Leaving_Group SPh, -C(NH)CCl3, S-2,6-MePh
Title An Efficient Convergent Synthesis of GP1c Ganglioside Epitope
Citation J. Am. Chem. Soc. 2008, 130, 17244
DOI 10.1021/ja807482t
PROM-943
Promoter NIS-TfOH
Leaving_Group ?
Title daburi
Citation daburi
DOI 10.1016/0008-6215(92)84057-Y
PROM-944
Promoter NIS-TfOH
Leaving_Group SBox, STaz
Title Glycosyl thioimidates in a highly convergent one-pot strategy for oligosaccharide synthesis
Citation Tetrahedron: Asymmetry 2005, 16, 433
DOI 10.1016/j.tetasy.2004.11.029
PROM-945
Promoter NIS-TfOH
Leaving_Group ?
Title Synthesis of oligosaccharides containing the X-antigenic trisaccharide (??-l-Fucp-(1??3)-[??-d-Galp-(1??4)]-??-d-GlcpNAc) at their nonreducing ends
Citation Carbohydr. Res. 1992, 226, 91
DOI 10.1016/0008-6215(92)84057-Y
PROM-946
Promoter NIS-TfOH
Leaving_Group ?
Title Synthesis of a Branched Heptose- and Kdo-Containing Common Tetrasaccharide Core Structure of Haemophilus influenzae Lipopolysaccharides via a 1,6-Anhydro-l-glycero-??-d-manno-heptopyranose Intermediate
Citation J. Org. Chem. 1998, 63, 7780
DOI 10.1021/jo9808573
PROM-948
Promoter NIS-TfOH
Leaving_Group STol
Title Programmable One-Pot Oligosaccharide Synthesis
Citation J. Am. Chem. Soc. 1999, 121, 734
DOI 10.1021/ja982232s
PROM-949
Promoter NIS-TfOH
Leaving_Group OC(=NPh)CF3, SPh
Title daburi
Citation daburi
DOI doi.rog/10.3390/molecules19010414
PROM-95
Promoter TMSOTf
Leaving_Group ?
Title Oligosaccharide Synthesis on Controlled-Pore Glass as Solid Phase Material
Citation Synlett. 1998, 171
DOI 10.1055/s-1998-3127
PROM-950
Promoter NIS-TfOH
Leaving_Group ?
Title Active_latent glycosylation strategy toward Lewis X pentasaccharide in a form suitable for neoglycoconjugate syntheses
Citation Carbohydr. Res. 1999, 318, 75
DOI 10.1016/S0008-6215(99)00080-4
PROM-952
Promoter NIS-TfOH
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1021/ja407827n
PROM-953
Promoter NBS-TfOH
Leaving_Group SMe, SPh, SEt
Title An efficient and stereocontrolled synthesis of the nephritogenoside core structure
Citation Tetrahedron Lett. 1991. 32, 6873
DOI 10.1016/0040-4039(91)80430-E
PROM-954
Promoter NBS-TfOH
Leaving_Group -S-C(S)-NEt2
Title Block synthesis of oligosaccharides. Part 1: Preparation of furanosyl-1-thiopyranosides
Citation Tetrahedron Lett. 2001, 42, 2221
DOI 10.1016/S0040-4039(01)00116-2
PROM-955
Promoter NBS-TfOH
Leaving_Group STol
Title daburi
Citation daburi
DOI 10.1246/cl.140167
PROM-956
Promoter NBS-TfOH
Leaving_Group SAda?(1-adamantanylthio)
Title ??-Selective Sialylations at ?|78 ??C in Nitrile Solvents with a 1-Adamantanyl Thiosialoside
Citation J. Org. Chem. 2007, 72, 7794
DOI 10.1021/jo7012912
PROM-957
Promoter NIS-TESOTf
Leaving_Group SEt
Title Total Synthesis of the 2,6-Sialylated Immunoglobulin G Glycopeptide Fragment in Homogeneous Form
Citation J. Am. Chem. Soc. 2009, 131, 16669
DOI 10.1021/ja907136d
PROM-958
Promoter NIS-TESOTf
Leaving_Group -S-S-Me
Title Glycosyldisulfides: a new class of solution and solid phase glycosyl donors
Citation Chem. Commun. 2001, 189
DOI 10.1039/B008734N
PROM-959
Promoter NIS-TESOTf
Leaving_Group 4-pentenyl Glycoside
Title Armed/disarmed effects in glycosyl donors: rationalization and sidetracking
Citation J. Org. Chem. 1990, 55, 6068
DOI 10.1021/jo00312a004
PROM-96
Promoter TMSOTf
Leaving_Group ?
Title Solid-Phase Oligosaccharide Synthesis of a Small Library of N-Glycans
Citation Chem. Eur. J. 2006, 12, 1274
DOI 10.1002/chem.200500707
PROM-960
Promoter NIS-TESOTf
Leaving_Group n-pentenyl
Title n-pentenyl glycosides in the efficient assembly of the blood group substance B tetrasaccharide
Citation Tetrahedron 1992, 48, 4713
DOI 10.1016/S0040-4020(01)81568-4
PROM-961
Promoter NIS-TESOTf
Leaving_Group n-pentenyl franoside
Title n-Pentenyl furanosides: synthesis and glycosidation reactions of some galacto derivatives
Citation Tetrahedron Lett. 1995, 36, 7967
DOI 10.1016/0040-4039(95)01718-W
PROM-962
Promoter NIS-TESOTf
Leaving_Group -S-S-Et
Title daburi
Citation daburi
DOI 10.1021/jo051374j
PROM-963
Promoter NIS-TESOTf
Leaving_Group SMe, F
Title daburi
Citation daburi
DOI 10.1248/cpb.49.1234
PROM-964
Promoter NIS-MeOTf
Leaving_Group ?
Title Synthesis of ??-Mannosides via Prearranged Glycosides
Citation Angew. Chem., Int. Ed. 1998, 37, 3129
DOI 10.1002/(SICI)1521-3773(19981204)37:22<3129::AID-ANIE3129>3.0.CO;2-8
PROM-965
Promoter NIS-BF3?EEt2O
Leaving_Group 4-pentenyl Glycoside
Title Unexpected Role of O-2 ?gProtecting?h Groups of Glycosyl Donors in Mediating Regioselective Glycosidation
Citation J. Am. Chem. Soc. 2002, 124, 3198
DOI 10.1021/ja012383m
PROM-966
Promoter NIS, HClO4_silica
Leaving_Group STol
Title Glycosylation reactions with ?edisarmed?f thioglycoside donors promoted by N-iodosuccinimide and HClO4_silica
Citation Tetrahedron Lett. 2005, 46, 5923
DOI 10.1016/j.tetlet.2005.06.119
PROM-967
Promoter NIS, HClO4-SiO2
Leaving_Group SEt
Title Glycosylation and Pyranose-Furanose Isomerization of Carbohydrates Using HClO4-SiO2: Synthesis of Oligosaccharides Containing Galactofuranose
Citation Synthesis 2007, 683
DOI 10.1055/s-2007-965913
PROM-968
Promoter NIS-Et3SiOTf
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)97609-3
PROM-969
Promoter NIS-IDCT
Leaving_Group SePh
Title Design and synthesis of a trisubstrate analogue for ??(1??3)fucosyltransferase: A potential inhibitor
Citation Tetrahedron. 1995, 51, 8397
DOI 10.1016/0040-4020(95)00451-D
PROM-97
Promoter TMSOTf
Leaving_Group trichloroacetimidate, OP(O)OBu2
Title Automated Solid-Phase Synthesis of Oligosaccharides
Citation Science 2001, 291, 1523? DL(10/26 from ?ʘ_??)
DOI 10.1126/science.1057324
PROM-970
Promoter NBS-Bu4NOTf
Leaving_Group SMe
Title A novel method for activation of thioglycosides, combination of N-bromosuccinimide and triflic acid salts
Citation Tetrahedron Lett. 1993, 34, 2187
DOI 10.1016/S0040-4039(00)60378-7
PROM-971
Promoter NBS-Ph2IOTf
Leaving_Group SMe
Title daburi
Citation daburi
DOI 10.1016/S0040-4039(00)60378-7
PROM-972
Promoter NBS-TMSOTf
Leaving_Group SPh
Title Bromonium ion-promoted glycosidic bond formation and simultaneous bromination of an activated aryl aglycon
Citation Carbohydr. Res. 2002, 337, 31
DOI 10.1016/S0008-6215(01)00276-2
PROM-973
Promoter NBS-TMSOTf
Leaving_Group ?
Title Products from furans. VII. A General Route for the Synthesis of ??-(1,2-cis) and ??-(1,2-trans) Glycoconjugates via 1-O-Acyl and 1-O-Ethoxycarbonyl-2-azido-2,3-dideoxyglycopyranosides
Citation J. Heterocycl. Chem. 1991, 28, 1325
DOI 10.1002/jhet.5570280526
PROM-974
Promoter NBS-QOTf
Leaving_Group SPhMe
Title Chemoenzymatic Synthesis of Sialylated Glycopeptides Derived from Mucins and T-Cell Stimulating Peptides
Citation J. Am. Chem. Soc. 2001, 123, 11117
DOI 10.1021/ja015570t
PROM-975
Promoter PhSOTf-DTBMP
Leaving_Group SEt
Title daburi
Citation daburi
DOI 10.1021/ol016869j
PROM-976
Promoter DMTST-DTBMP
Leaving_Group SEt
Title A Novel ??-Directing Fructofuranosyl Donor Concept. Stereospecific Synthesis of Sucrose
Citation J. Am. Chem. Soc. 2000, 122, 8869
DOI 10.1021/ja001439u
PROM-977
Promoter I2-DTBMP
Leaving_Group SePh
Title Synthesis of carbohydrate derivatives using solid-phase work-up and scavenging techniques
Citation Org. Biomol. Chem. 2003, 1, 2029
DOI 10.1039/B303951J
PROM-979
Promoter BSM-Tf2O
Leaving_Group STol
Title Highly Direct ??-Selective Glycosylations of 3,4-O-Carbonate-Protected 2-Deoxy- and 2,6-Dideoxythioglycosides by Preactivation Protocol
Citation Org. Lett. 2008, 10, 3445
DOI 10.1021/ol801190c
PROM-98
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Rapid Synthesis of a Glycosylphosphatidylinositol-Based Malaria Vaccine Using Automated Solid-Phase Oligosaccharide Synthesis
Citation J. Am. Chem. Soc. 2002, 124, 13434
DOI 10.1021/ja027538k
PROM-980
Promoter BSM-Tf2O
Leaving_Group STol
Title Stereoselectivity investigation on glycosylation of oxazolidinone protected 2-amino-2-deoxy-d-glucose donors based on pre-activation protocol
Citation Tetrahedron, 2008, 64, 4949
DOI 10.1016/j.tet.2008.03.103
PROM-981
Promoter BSM-Tf2O
Leaving_Group STol
Title Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines
Citation Chem. Commun. 2008, 597
DOI 10.1039/B712591G
PROM-982
Promoter BSM-Tf2O
Leaving_Group STol
Title Additive-Controlled Stereoselective Glycosylations of Oxazolidinone-Protected Glucosamine and Galactosamine Thioglycoside Donors Based on Preactivation Protocol
Citation Synlett 2010, 2506
DOI 10.1055/s-0030-1258557
PROM-983
Promoter BSP/Tf2O
Leaving_Group SPh
Title Stereocontrolled Formation of ??-Glucosides and Related Linkages, trans-Fused 2,3-O-Carbonate Group
Citation J. Org. Chem. 2005, 70, 7252
DOI 10.1021/jo0508999
PROM-984
Promoter BSP/Tf2O
Leaving_Group SPh
Title ??-Selective glucosylation, absence of neighboring group, ?3,4-O-bisacetal
Citation Tetrahedron 2007, 63, 5042
DOI 10.1016/j.tet.2007.03.128
PROM-985
Promoter BSP/Tf2O
Leaving_Group SPh
Title A phosphoric ester at the C2 position in glycosyl donors , 1,2-trans selectivity
Citation Angew. Chem., Int. Ed. 2006, 45, 7575
DOI 10.1002/anie.200602699
PROM-986
Promoter BSP/Tf2O
Leaving_Group SPh
Title Iterative Glycosylation of 2-Deoxy-2-aminothioglycosides
Citation Angew. Chem., Int. Ed. 2004, 43, 2145
DOI 10.1002/anie.200353552
PROM-987
Promoter BSP/Tf2O
Leaving_Group SPMP
Title Sulfonium Triflate Mediated Glycosidations of Aryl 2-Azido-2-deoxy-1-thio-D-mannosides
Citation Eur. J. Org. Chem. 2005, 918
DOI 10.1002/ejoc.200400784
PROM-988
Promoter BSP/Tf2O
Leaving_Group SPh, F
Title Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation
Citation Tetrahedron: Asymmetry 2005, 16, 105
DOI 10.1016/j.tetasy.2004.11.032
PROM-989
Promoter BSP/Tf2O
Leaving_Group SPh
Title 4,6-O-Benzylidene-Directed ??-Mannopyranosylation and ??-Glucopyranosylation
Citation J. Org. Chem. 2007, 72, 1681
DOI 10.1021/jo062294y
PROM-99
Promoter TMSOTf
Leaving_Group trichloroacetimidate
Title Hydrophobically Assisted Switching Phase Synthesis:_ The Flexible Combination of Solid-Phase and Solution-Phase Reactions Employed for Oligosaccharide Preparation
Citation J. Am. Chem. Soc. 2005, 127, 7296
DOI 10.1021/ja051737x
PROM-990
Promoter BSP/Tf2O
Leaving_Group SPh
Title Synthesis and Reactivity of 4??-Deoxypentenosyl Disaccharides
Citation J. Org. Chem. 2014, 79, 4878
DOI 10.1021/jo500449h
PROM-991
Promoter BSP/Tf2O
Leaving_Group S(O)Tol, STol
Title On the Use of 3,5-O-Benzylidene and 3,5-O-(Di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and Their Sulfoxides as Glycosyl Donors for the Synthesis of ??-Arabinofuranosides:_ Importance of the Activation Method
Citation J. Org. Chem. 2007, 72, 1553
DOI 10.1021/jo061440x
PROM-992
Promoter BSP/Tf2O
Leaving_Group SPh
Title ?Enhanced Diastereoselectivity in ??-Mannopyranosylation through the Use of Sterically Minimal Propargyl Ether Protecting Groups
Citation J. Org. Chem. 2006, 71, 3064
DOI 10.1021/jo0526789
PROM-993
Promoter BSP/Tf2O
Leaving_Group SPh
Title Chemoselective glycosylations using sulfonium triflate activator systems
Citation Tetrahedron 2004, 60, 1057
DOI 10.1016/j.tet.2003.11.084
PROM-994
Promoter BSP/Tf2O
Leaving_Group SPh
Title On the Influence of the C2?|O2 and C3?|O3 Bonds in 4,6-O-Benzylidene-Directed ??-Mannopyranosylation and ??-Glucopyranosylation
Citation J. Org. Chem. 2006, 71, 8473
DOI 10.1021/jo061417b
PROM-995
Promoter DPS/Tf2O
Leaving_Group SPh
Title daburi
Citation daburi
DOI 10.1016/j.tet.2003.11.084
PROM-996
Promoter BSP/DTBMP
Leaving_Group S(O)Tol, STol
Title daburi
Citation daburi
DOI 10.1021/ja029302m
PROM-997
Promoter BSP/DTBMP
Leaving_Group STol, S(O)Tol
Title daburi
Citation daburi
DOI 10.1021/ja029302m
PROM-998
Promoter Tf2O, DTBMP
Leaving_Group -S(O)Et
Title ??-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method
Citation J. Org. Chem. 1996, 61, 4506
DOI 10.1021/jo9606517
PROM-999
Promoter Tf2O, DTBMP
Leaving_Group -S(O)Et
Title Direct Synthesis of ??-Mannopyranosides by the Sulfoxide Method
Citation J. Org. Chem. 1997, 62, 1198
DOI 10.1021/jo962345z